温差对泉州四至井水氡测值的影响分析

温度变化是影响水氡观测值的主要因素之一.通过1986-2009年泉州台四至井观测数据资料的分析,说明:调整观测室室内温度使其超过采集水样的原始温度,在运输水样过程中对水样采取保温措施,减小取样水温和鼓泡后水温的温差,能够得到更真实、准确的观测值.     

Diffusive equilibrium in thin films provides evidence of suppression of hyporheic exchange and large‐scale nitrate transformation in a groundwater‐fed river

The hyporheic zone of riverbed sediments has the potential to attenuate nitrate from upwelling, polluted groundwater. However, the coarse‐scale (5–10 cm) measurement of nitrogen biogeochemistry in the hyporheic zone can often mask fine‐scale (<1 cm) biogeochemical patterns, especially in near‐surface sediments, leading to incomplete or inaccurate representation of the capacity of the hyporheic zone to transform upwelling NO₃^?. In this study, we utilised diffusive equilibrium in thin‐films samplers to capture high resolution (cm‐scale) vertical concentration profiles of NO₃^?, SO₄^2?, Fe and Mn in the upper 15 cm of armoured and permeable riverbed sediments. The goal was to test whether nitrate attenuation was occurring in a sub‐reach characterised by strong vertical (upwelling) water fluxes. The vertical concentration profiles obtained from diffusive equilibrium in thin‐films samplers indicate considerable cm‐scale variability in NO₃^? (4.4 ± 2.9 mg N/L), SO₄^2? (9.9 ± 3.1 mg/l) and dissolved Fe (1.6 ± 2.1 mg/l) and Mn (0.2 ± 0.2 mg/l). However, the overall trend suggests the absence of substantial net chemical transformations and surface‐subsurface water mixing in the shallow sediments of our sub‐reach under baseflow conditions. The significance of this is that upwelling NO₃^?‐rich groundwater does not appear to be attenuated in the riverbed sediments at <15 cm depth as might occur where hyporheic exchange flows deliver organic matter to the sediments for metabolic processes. It would appear that the chemical patterns observed in the shallow sediments of our sub‐reach are not controlled exclusively by redox processes and/or hyporheic exchange flows. Deeper‐seated groundwater fluxes and hydro‐stratigraphy may be additional important drivers of chemical patterns in the shallow sediments of our study sub‐reach. © 2015 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.     

Water level variations in the Neuse and Pamlico Estuaries,North Carolina due to local and remote forcing

Water level time series records from the Neuse and Pamlico River Estuaries were statistically compared to local and distant wind field data, water level records within the Pamlico Sound and also coastal ocean sites to determine the relative contribution of each time series to water levels in the Neuse and Pamlico Estuaries. The objectives of this study were to examine these time series data using various statistical methods (i.e. autoregressive, empirical orthogonal function analysis (EOF), exploratory data analysis (EDA)) to determine short- and long-time-scale variability, and to develop predictive statistical models that can be used to estimate past water level fluctuations in both the Neuse Estuary (NE) and Pamlico Estuary (PE). Short- and long-time-scale similarities were observed in all time series of estuarine, Pamlico Sound and subtidal coastal ocean water level and wind component data, due to events (nor'easters, fronts and tropical systems) and seasonality. Empirical orthogonal function analyses revealed a strong coastal ocean and wind field contribution to water level in the NE and PE. Approximately 95% of the variation was captured in the first two EOF components for water level data from the NE, sound and coastal ocean, and 70% for the PE, sound and coastal ocean. Spectral density plots revealed strong diurnal signals in both wind and water level data, and a strong cross correlation and coherency between the NE water level and the North/South wind component. There was good agreement between data and predictions using autoregressive statistical models for the NE (R² = 0.92) and PE (R² = 0.76). These methods also revealed significant autoregressive lags for the NE (days 1 and 3) and for the PE (days 1, 2 and 3). Significant departures from predictions are attributed to local meteorological and hydrological events. The autoregressive techniques showed significant predictive improvement over ordinary least squares methods. The results are considered within the context of providing long time-scale hindcast data for the two estuaries, and the importance of these data for multidisciplinary researchers and managers.     

CP-MS测定饮用水中Fe的方法

通过实验确定了ICP-MS检测饮用水中Fe的质量质量浓度方法。检测方法的检出限(DL)和精密度(RSD)分别达到3.29ng/mL和4.49%(n=12)。     

Hydrological cycle and water balance estimates for the megadune–lake region of the Badain Jaran Desert,China

The hydrology and water balance of megadunes and lakes have been investigated in the Badain Jaran Desert of China. Field observations and analyses of sand layer water content, field capacity, secondary salt content, and grain size reveal 3 types of important natural phenomenon: (a) vegetation bands on the leeward slope of the megadunes reflect the hydrological regime within the sandy vadose zone; (b) seepage, wet sand deposits, and secondary salt deposits indicate the pattern of water movement within the sandy vadose zone; (c) zones of groundwater seeps and descending springs around the lakes reflect the influence of the local topography on the hydrological regime of the megadunes. The seepage exposed on the sloping surface of the megadunes and gravity water contained within the sand layer confirm the occurrence of preferential flow within the vadose zone of the megadunes. Alternating layers of coarse and fine sand create the conditions for the formation of preferential flows. The preferential flows promote movement of water within the sand layer water that leads to deep penetration of water within the megadunes and ultimately to the recharging of groundwater and lake water. Our results indicate that a positive water balance promotes recharge of the megadunes, which depends on the high permeability of the megadune material, the shallow depth of the surface sand layer affected by evaporation, the occurrence of rainfall events exceeding 15 mm, and the sparse vegetation cover. Water balance estimates indicate that the annual water storage of the megadunes is about 7.5 mm, accounting for only 8% of annual precipitation; however, the shallow groundwater per unit area under the megadunes receives only 3.6% of annual precipitation, but it is still able to maintain a dynamic balance of the lake water. From a water budget perspective, the annual water storage in the megadunes is sufficient to serve as a recharge source for lake water, thereby enabling the long‐term persistence of the lakes. Overall, our findings demonstrate that precipitation is a significant component of the hydrological cycle in arid deserts.     

Formation rates of Subantarctic mode water and Antarctic intermediate water within the South Pacific

The formation of Subantarctic Mode Water (SAMW) and Antarctic Intermediate Water (AAIW) significantly contributes to the total uptake and storage of anthropogenic gases, such as CO₂ and chlorofluorocarbons (CFCs), within the world's oceans. SAMW and AAIW formation rates in the South Pacific are quantified based on CFC-12 inventories using hydrographic data from WOCE, CLIVAR, and data collected in the austral winter of 2005. This study documents the first wintertime observations of CFC-11 and CFC-12 saturations with respect to the 2005 atmosphere in the formation region of the southeast Pacific for SAMW and AAIW. SAMW is 94% and 95% saturated for CFC-11 and CFC-12, respectively, and AAIW is 60% saturated for both CFC-11 and CFC-12. SAMW is defined from the Subantarctic Front to the equator between potential densities 26.80-27.06 kg m⁻³, and AAIW is defined from the Polar Front to 20°N between potential densities 27.06-27.40 kg m⁻³. CFC-12 inventories are 16.0×10⁶ moles for SAMW and 8.7×10⁶ moles for AAIW, corresponding to formation rates of 7.3±2.1 Sv for SAMW and 5.8±1.7 Sv for AAIW circulating within the South Pacific. Inter-ocean transports of SAMW from the South Pacific to the South Atlantic are estimated to be 4.4±0.6 Sv. Thus, the total formation of SAMW in the South Pacific is approximately 11.7±2.2 Sv. These formation rates represent the average formation rates over the major period of CFC input, from 1970 to 2005. The CFC-12 inventory maps provide direct evidence for two areas of formation of SAMW, one in the southeast Pacific and one in the central Pacific. Furthermore, eddies in the central Pacific containing high CFC concentrations may contribute to SAMW and to a lesser extent AAIW formation. These CFC-derived rates provide a baseline with which to compare past and future formation rates of SAMW and AAIW.     

阶段性干旱胁迫对小麦光合生理特性及产量结构的影响

在人工遮雨的条件下,采用盆栽的种植方式探究"皖麦68"营养生长期(返青期—开花期)及生殖生长期(开花期—成熟期)轻度干旱胁迫(土壤相对含水量为55%±5%)及复水(土壤相对含水量为70%±5%)对其光合生理特性及产量结构的影响。结果表明:返青期至成熟期充分供水(CK)的小麦旗叶光合参数和产量最高。开花至成熟期复水(DN)的小麦叶片在复水后光合能力迅速恢复,表现出了超补偿效应:光合速率(16.43μmol/(m~2·s))甚至超过了CK(15.01μmol/(m~2·s));采用非直角双曲线模型拟合小麦旗叶的光响应曲线,其中DN的曲角θ最大;DN产量较CK略有降低但千粒重为34.51 g,高于CK(34.44 g)。开花至成熟期轻度干旱(ND)及全生育期轻度干旱(DD)的小麦光合特征参数与产量均显著降低。DD产量最低、品质最差,但其收获指数I_H高于CK、仅次于DN。在小麦返青期—开花期进行水分管理适量减少灌溉,开花期—成熟期复水能够提升籽粒的干物质积累量,获得较高的产量及品质。     

The environmental planning and management approach towards the development and management of the Osun natural spring project,Ibadan, Nigeria

There is a general shortage of potable water in Nigeria, partly through the lack of natural provision and partly because of rapid urban growth that has largely been unplanned. The paper describes the recent redevelopment of a public water facility in a run-down area of Ibadan which is part of the Sustainable Ibadan Project. Despite funding from national and international bodies, the development is strongly based at community level. The local inhabitants feel they have control over their own water supply through their representatives on the various planning and managing committees. This aims to reduce vandalism and to increase pride and involvement in the community. The project is a pilot for other projects around Ibadan, some of which have begun and others are being planned. This paper describes the administrative structures and management principles that have been employed. It forcefully advocates community-based planning and management which respects both the environment and the water-users, and involves a major “bottom-up” element. This revised version was published online in July 2006 with corrections to the Cover Date.     

南海北部海区水团的判别分析

将判别分析应用于南海北部海区的水团分析。划分为八个水团:沿岸冲淡水团(F),近岸混合水团(M),暖表层水团(WS),表层水团(S),表—次层混合水团(SU),次层水团(U),次—中层混合水团(UI)和中层水团(I)。给出了各水团在四季代表月的Bayes多组判别的系数和参数。用资料检验判别的成效.冬季和春季可达95.90％以上,夏季为94.80％,秋季是全年最低值,为92.72％。讨论了造成错判的原因,并与Fisher判别作了比较。当测值维数较低时,建议选用Bayes判别。对八个水团以及各水团两两之间差异的显著性进行了检验,证实在每个季节中各水团之间的差异,都在高度置信水平(α=0.01)上具有显著性。因而,划分为八个水团是有实际意义的,其判别式的系数和参数,可用于实际的判别和预报。     

特低渗透砂岩储层水驱油CT成像技术研究

通过水驱油岩心的CT成像技术,动态、定量、可视化地研究了特低渗透砂岩储层水驱油岩心的微观孔隙结构、含水饱和度分布、吸水能力及微观孔隙结构对驱油效率的影响.研究表明,实验岩心的CT值分布在1819~1961之间,与标准的Berea砂岩相比高出15%左右,属于典型的特低渗透砂岩储层.储层微观孔隙结构是影响油水分布的主要因素.特低渗透砂岩储层开发要高度重视无水采收率.储层致密和微裂缝发育的不均一性是特低渗透砂岩油田驱油效率低的根本原因.