江汉平原西部浅层孔隙水水文地球化学特征

为了揭示地下水由江汉平原周缘向中心径流过程中的水质演化和复杂的水文地球化学作用,以江汉平原西部地区为例,通过数理统计、水化学、同位素地球化学、离子比值关系等方法,开展了江汉平原西部边缘地带浅层孔隙地下水的水文地球化学特征研究。结果表明: 平原区孔隙水以HCO₃-Ca·Mg型为主,丘岗区(丘陵和岗地)主要是HCO₃-Ca·Mg型,少量为HCO₃·SO₄-Ca·Mg型,还出现了HCO₃·NO₃-Ca·Mg型水,总溶解固体(total dissolved solids,TDS)升高主要是由于碳酸盐岩的溶解; 浅层孔隙水均来源于大气降水,蒸发作用对该地区孔隙水的影响较小; 方解石、白云石和石膏的溶解主导研究区的水文地球化学过程,也是孔隙水中Ca²⁺、Mg²⁺的主要来源,Na⁺和K⁺的主要来源是阳离子交换吸附。     

山西吕梁山北段中生代构造特征及对成矿的制约

为进一步研究山西吕梁山北段中生代构造特征及对成矿的制约,利用数字化填图方法,在偏关县一带开展1:25万区域地质调查。发现几条中生代大型构造带,查明了这些大型构造带的空间展布、性质、断裂组合及运动学特征; 证实了中生代为该区重要的多金属成矿期,成矿作用尽管与中生代岩浆活动关系密切,但在空间上分布受NE向隐伏构造的制约; 大型挠褶构造是地壳强烈隆升的标志,区内大型构造带多数是在挠褶构造的基础上叠加断层而形成的。该研究对于探讨山西中—新生代构造的演化发展具有重要意义。     

Analysis on the law of occurrence of shallow geothermal energy in Zhoukou City of Henan Province,China

In this paper, through data collection and field investigation, the development and utilization status of shallow geothermal energy in Zhoukou urban area was discussed. Based on the analysis of hydrogeological conditions, rock and soil structure characteristics and field test research, the spatial distribution characteristics of rock and soil in the study area were summarized. The study shows that Zhoukou City is located in the alluvial plain of Huanghuai, and the loose deposits of river alluvial genesis range 0-200 m. These loose deposits and groundwater stored in their pores are the main carriers of shallow geothermal energy. In the central part of the Yinghe River in the middle of the study area, the aquifer thickness is within 200 m, the particle size is coarser, the water-bearing degree and recharge capacity is better. On this basis, the paper uses AHP to evaluate the suitability of shallow geothermal energy development and utilization to guide the rational development and utilization of shallow geothermal energy resources.     

Going green or going away: Environmental regulation,economic geography and firms’ strategies in China’s pollution-intensive industries

The high-growth, resource- and pollution-intensive industrialization model that China has pursued has caused severe environmental pollution and deterioration, particularly in a number of clusters in the coastal regions of East and Southeast China, where the Reform and Opening-up policies first started. The lack of uptake of environmental norms/values, deficit of regulatory enforcement of environmental policies, and insufficient institutional capacity have been compounding factors. As environmental standards were raised by China’s central government, the enforcement of environmental regulation has been compromised more in inland China than in coastal regions, due to China’s “decentralized governance structure” and regional disparity in terms of both economic development and environmental pollution. This paper therefore argues that rising environmental regulations, as well as firm characteristics, regional hub effect and political environment, have all been particularly important in forcing China’s pollution-intensive enterprises to restructure their production, through innovation, upgrading, geographical relocation, outsourcing and plant closure, especially in China’s coastal regions. It contributes to recent studies by developing a heuristic analytical framework that aims to be sensitive to the impacts of environmental regulation, political environment and regional hub effect over firm restructuring, but which does so by stressing these impacts are simultaneously inflected by the nature and attributes of firms. The empirical analysis suggests a roughly inverted “U”-shaped relationship between firm relocation tendency and firm size (or firm capability), resulting from complex interactions between political environment, regional hub effect and environmental regulation.     

太平洋富钴结壳中碲元素的地球化学特征及其富集机制探讨

文章通过对采自太平洋海域不同海山上68个结壳样品中Te元素地球化学特征的研究,探讨了富钴结壳中控制Te元素富集的古海洋氧化还原环境及其富集机制。分析表明,太平洋海域中大多数结壳的w（Te）变化于13.4×10^-6~115.8×10^-6,平均50×10^-6,是海水w（Te）的10⁹倍;结壳中w（Te）与Mn/Fe比值呈正相关,相关系数为0.51;与Fe呈负相关,相关系数为-0.61,显示结壳中Te与Co有类似的地球化学特征。古海水氧化还原环境的改变是控制结壳中Te元素含量变化的重要因素;能反映古海水氧化还原环境的Ce异常与结壳中Te含量基本呈同步变化趋势,Te含量具有随古海水氧化程度减弱而降低的特征。结壳中Te元素的富集主要受控于其内的Mn/Fe比值。Te元素的富集机制除被海水中带微弱正电荷的FeOOH胶体以库伦静电吸附外,还可能与δ-MnO₂表面上以一种表面络合物方式的富集机制有关。Te进入结壳的存在形式及其在不同古海洋环境中的富集机制还有待进一步研究和探讨。     

云南者桑金矿床载金矿物标型特征研究

者桑金矿床处在滇黔桂“金三角”构造带中,该矿床的形成经历了沉积成岩期、热液成矿期及表生氧化期,黄铁矿及毒砂为矿床的重要载金矿物。通过岩相学特征、标型矿物研究,发现热液成矿Ⅰ阶段中主要载金矿物为毒砂,热液成矿Ⅱ阶段为金矿化最主要阶段,主要载金矿物为黄铁矿。黄铁矿呈胶状、细粒状、破碎状;毒砂呈粗粒板柱状,维氏硬度偏低为其载金标型。晶胞参数测试表明,黄铁矿a值在5.4300~5.4325 Å之间,成矿Ⅰ阶段至成矿Ⅱ阶段a值逐渐变大。载金毒砂明显富S、Co亏As,导致b、c、β均低于理论值。各成矿阶段的黄铁矿及毒砂中主量、微量元素及硫同位素组成呈现一定变化规律,成矿物质主要来自于富含有机质的围岩。者桑金矿床为中低温热液矿床。     

新疆库车盆地钾盐科探1井含盐系地球化学特征及找钾指示

在盐湖沉积演化过程中,钾盐矿物在盐类沉积的中晚期阶段才开始析出。因此,研究含盐系盐类的沉积地球化学特征,不仅可以从侧面获取岩盐的沉积物源和成盐古卤水蒸发浓缩程度等地球化学信息,而且更能揭示古盐湖钾盐富集趋势。文章通过对库车盆地钾盐科探1井钻取的岩芯样品进行高精度采样测试,得出岩盐中Mg×103/Cl、K×103/Cl、Li×103/Cl与K+、Mg2+、Li+、Ca2+、Cl-含量的垂向变化规律。并与库车盆地其他钻孔中的岩盐含钾性进行对比,同时,依据钻井剖面岩性特征,与潜江凹陷和大汶口凹陷含盐系剖面进行对比,论述研究区成盐的地球化学特征,对其钾盐成矿前景进行分析和评价。     

云南普洱大平掌铜多金属矿床成矿特征与成矿模式

[摘 要] 大平掌铜多金属矿属火山喷流沉积矿床,发育V1和V2两类矿体,其中,V1矿体为块状硫化物矿体,V2矿体为细脉浸染状矿体,二者构成VHMS型矿床所具有的“上层-下脉”及“上黑-下黄”的空间矿化结构。本文通过研究区域地质背景、成矿地质特征、结合矿区演化特点,建立大平掌铜矿成矿模式,对分析原特提斯期的铜多金属成矿作用及其类型,提升“三江”成矿带典型矿床研究水平,认识思茅盆地早古生代基底中的优势成矿类型、找矿潜力和找矿思路等,有重要的启示作用。     

山西平顺西安里铁矿成矿流体特征及演化

[摘 要]对西安里铁矿床蚀变矿物（透辉石、石榴子石、绿帘石和方解石）流体包裹体进行了岩相学、均一温度、盐度和H-O同位素组成分析研究,结果表明：透辉石中流体包裹体均一温度为515℃～622℃,盐度（w（NaCl））为48～75;石榴子石均一温度为475℃～525℃,w（NaCl）均小于26wt%NaCl;绿帘石均一温度为390～440℃,盐度主要分布在40 wt%NaCl左右;方解石均一温度为141～4066oC,w（NaCl）为6.74～21.11;石榴石、透辉石的δD_SMOW值介于-106‰～-86‰,δ¹⁸O_SMOW值介于6.7～8.7‰,δ¹⁸O_H2O值介于2.7‰～8.7‰。磁铁矿δ¹⁸O_H2O值介于2.6‰～6.2‰。综合分析认为：热液主要来源于岩体,在上升过程中萃取了围岩中Na和Cl,Na的加入使大量Fe析出并与Cl结合进行迁移,流体物理化学特征具有显著的变化,导致Fe质析出形成西安里铁矿床。     

黑龙江争光金矿床隐爆角砾岩特征及其地质意义

黑龙江争光金矿床位于大兴安岭东北缘的多宝山矿集区,矿体主要呈脉状产于燕山期闪长岩体与中奥陶统多宝山组的内外接触带上,受断裂构造控制明显。在野外地质调查过程中,发现了3个隐爆角砾岩体（J-1、J-2、J-3）,角砾岩体从中心向外侧有较显著的岩石类型分带,中心为热液隐爆角砾岩,向外角砾增大,逐渐过渡为震碎角砾岩。根据胶结物的不同和穿插关系可将其分为四期,最早期为硅质胶结,中期为绿泥石胶结,其次为矿质胶结,最后为灰黑色安山质胶结,其中第二期和第三期隐爆作用与矿化关系密切。通过对隐爆角砾岩地质特征的研究,结果表明在Ⅱ号矿带绿泥石胶结隐爆角砾岩体深部具有寻找与矿质胶结隐爆角砾岩有关金铜矿化体的潜力,这对争光金矿床深部及外围找矿具有一定的指导意义。