Spatiotemporal variability in hydrochemistry of shallow groundwater in a small pre‐alpine catchment: The importance of landscape elements

Topography and landscape characteristics affect the storage and release of water and, thus, groundwater dynamics and chemistry. Quantification of catchment scale variability in groundwater chemistry and groundwater dynamics may therefore help to delineate different groundwater types and improve our understanding of which parts of the catchment contribute to streamflow. We sampled shallow groundwater from 34 to 47 wells and streamflow at seven locations in a 20‐ha steep mountainous catchment in the Swiss pre‐Alps, during nine baseflow snapshot campaigns. The spatial variability in electrical conductivity, stable water isotopic composition, and major and trace ion concentrations was large and for almost all parameters larger than the temporal variability. Concentrations of copper, zinc, and lead were highest at sites that were relatively dry, whereas concentrations of manganese and iron were highest at sites that had persistent shallow groundwater levels. The major cation and anion concentrations were only weakly correlated to individual topographic or hydrodynamic characteristics. However, we could distinguish four shallow groundwater types based on differences from the catchment average concentrations: riparian zone‐like groundwater, hillslopes and areas with small upslope contributing areas, deeper groundwater, and sites characterized by high magnesium and sulfate concentrations that likely reflect different bedrock material. Baseflow was not an equal mixture of the different groundwater types. For the majority of the campaigns, baseflow chemistry most strongly resembled riparian‐like groundwater for all but one subcatchment. However, the similarity to the hillslope‐type groundwater was larger shortly after snowmelt, reflecting differences in hydrologic connectivity. We expect that similar groundwater types can be found in other catchments with steep hillslopes and wet areas with shallow groundwater levels and recommend sampling of groundwater from all landscape elements to understand groundwater chemistry and groundwater contributions to streamflow.     

Spatio‐temporal variability of the isotopic input signal in a partly forested catchment: Implications for hydrograph separation

The isotopic composition of precipitation (D and ¹⁸O) has been widely used as an input signal in water tracer studies. Whereas much recent effort has been put into developing methodologies to improve our understanding and modelling of hydrological processes (e.g., transit‐time distributions or young water fractions), less attention has been paid to the spatio‐temporal variability of the isotopic composition of precipitation, used as input signal in these studies. Here, we investigated the uncertainty in isotope‐based hydrograph separation due to the spatio‐temporal variability of the isotopic composition of precipitation. The study was carried out in a Mediterranean headwater catchment (0.56 km²). Rainfall and throughfall samples were collected at three locations across this relatively small catchment, and stream water samples were collected at the outlet. Results showed that throughout an event, the spatial variability of the input signal had a higher impact on hydrograph separation results than its temporal variability. However, differences in isotope‐based hydrograph separation determined preevent water due to the spatio‐temporal variability were different between events and ranged between 1 and 14%. Based on catchment‐scale isoscapes, the most representative sampling location could also be identified. This study confirms that even in small headwater catchments, spatio‐temporal variability can be significant. Therefore, it is important to characterize this variability and identify the best sampling strategy to reduce the uncertainty in our understanding of catchment hydrological processes.     

Trends and multi‐annual variability of water temperatures in the river Danube,Serbia

The relationship between air (Ta) and water temperature (Tw) is very important because it shows how the temperature of a water body might respond to future changes in surface Ta. Mean monthly Tw records of three gauging stations (Bezdan, Bogojevo i Veliko Gradi?te) were analysed alongside mean monthly discharge (Q) for the same stations. Additionally, Ta series from two meteorological stations (Sombor and Veliko Gradi?te) were correlated with Tw variations over the period 1950–2012. Locally weighted scatter point smoothing (LOWESS) was used to investigate long‐term trends in the raw data, alongside the Mann–Kendall (MK) trend test. Trend significance was established using Yue–Pilon's pre‐whitening approaches to determine trends in climate data. Also, the rescaled adjusted partial sums (RAPS) method was used to detect dates of possible changes in the time series. Statistically significant warming trends were observed for annual and seasonal minimum and maximum Tw at all investigated sites. The strongest warming was observed at Bogojevo gauging station for seasonal maximum Tw, with +0.05 °C per year on average. RAPS established that the trend began in the 1980s. This behaviour is linked to climate patterns in the North and East Atlantic which determine the amount of heat advected onto mainland Europe. Statistically significant correlations were found for all Tw on an annual basis. Overall, the strongest correlations (p < 0.01) between Tw residuals and the North Atlantic Oscillation (NAO) were recorded for the winter period. These findings suggest possible predictability of Tw over seasonal time‐scales. Copyright © 2016 John Wiley & Sons, Ltd.     

Metals discharged during different flow conditions from a mixed agricultural‐forest catchment (NW Spain)

Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.     

Changes in dissolved organic matter (DOM) amount and composition along nested headwater stream locations during baseflow and stormflow

Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.     

Understanding the relative impacts of natural processes and human activities on the hydrology of the Central Rift Valley lakes,East Africa

Significant changes have been observed in the hydrology of Central Rift Valley (CRV) lakes in Ethiopia, East Africa as a result of both natural processes and human activities during the past three decades. This study applied an integrated approach (remote sensing, hydrologic modelling, and statistical analysis) to understand the relative effects of natural processes and human activities over a sparsely gauged CRV basin. Lake storage estimates were calculated from a hydrologic model constructed without inputs from human impacts such as water abstraction and compared with satellite‐based (observed) lake storage measurements to characterize the magnitude of human‐induced impacts. A non‐parametric Mann–Kendall test was used to detect the presence of climatic trends (e.g. a decreasing or increasing trends in precipitation), while the Standard Precipitation Index (SPI) analysis was used to assess the long‐term, inter‐annual climate variability within the basin. Results indicate human activities (e.g. abstraction) significantly contributed to the changes in the hydrology of the lakes, while no statistically significant climatic trend was seen in the basin, however inter‐annual natural climate variability, extreme dryness, and prolonged drought has negatively affected the lakes. The relative contributions of natural and human‐induced impacts on the lakes were quantified and evaluated by comparing hydrographs of the CRV lakes. Lake Abiyata has lost ~6.5 m in total lake height between 1985 and 2006, 70% (~4.5 m) of the loss has been attributed to human‐induced causes, whereas the remaining 30% is related to natural climate variability. The relative impact analysis utilized in this study could potentially be used to better plan and create effective water‐management practices in the basin and demonstrates the utility of this integrated methodology for similar studies assessing the relative natural and human‐induced impacts on lakes in data sparse areas. Copyright © 2015 John Wiley & Sons, Ltd.     

The impact of rural land management changes on soil hydraulic properties and runoff processes: results from experimental plots in upland UK

To develop an evidence base to help predict the impacts of land management change on flood generation, four experimental sites were established on improved grassland used for sheep grazing at the Pontbren catchment in upland Wales, UK. At each site, three plots were established where surface runoff was measured, supplemented by measurements of soil infiltration rates and soil and vegetation physical properties. Following baseline monitoring, treatments were applied to two of the plots: exclusion of sheep (ungrazed) and exclusion of sheep and planting with native broadleaf tree species (tree planted), with the third plot acting as a control (grazed pasture). Due to a particularly dry summer that occurred pre‐treatment, the soil hydrological responses were initially impacted by the effects of the climate on soil structure. Nevertheless, treatments did have a clear influence on soil hydrological response. On average, post‐treatment runoff volumes were reduced by 48% and 78% in ungrazed and tree‐planted plots relative to the control, although all results varied greatly over the sites. Five years following treatment application, near‐surface soil bulk density was reduced and median soil infiltration rates were 67 times greater in plots planted with trees compared to grazed pasture. The results illustrate the potential use of upland land management for ameliorating local‐scale flood generation but emphasise the need for long‐term monitoring to more clearly separate the effects of land management from those of climatic variability. Copyright © 2013 John Wiley & Sons, Ltd.     

Potential food deserts and food oases in a post-communist city: Access,quality, variability and price of food in Bratislava-Petržalka

Delimitation tools and definitions of food deserts have not been internationally unified so far. Such comprehension ambiguity may lead to variability in research methods as well as to terminology mismatch in the research. In general, assessment of accessibility of selected (large-scale) food stores network in a region is considered as a suitable tool to identify the food deserts, but this is certainly not the only approach. In our paper some other approaches (such as measuring quality, variability and food price) are assessed together with supermarkets and hypermarkets accessibility examination. Results gained by analyses based on various methodological approaches are then compared and confronted, which simultaneously allows us to compare the individual approaches. For our case study purposes, the largest housing estate in Slovakia's capital city was selected.     

中国大陆降水时空变异规律——Ⅲ. 趋势变化原因

中国大陆现代降水表现出若干长期变化特征,对现代降水趋势性变化的原因,目前还没有很好了解。结合多种资料分析以及前人研究成果,对中国大陆近几十年降水变化趋势的原因进行了探讨,得到以下初步认识:① 现代降水量变化趋势具有明显的地域性差异,全国平均没有表现出显著增加或减少的长期变化,但强降水事件频率和降水量出现明显增多,而小雨事件特别是痕量降水事件显著减少。② 再分析资料表明,最近几十年全国水汽净收支量在一定程度上增加了,实际观测资料显示近地面和对流层中下层空气比湿或大气可降水量出现较明显上升趋势。③ 代用资料序列分析显示,全国大部地区近几十年降水变化仍处于晚近历史时期正常自然波动范围内;近百年观测的降水量序列也表明,黄淮海地区降水具有多重时间尺度相互叠加作用特点,低频自然气候变异的影响信号有清晰表现。④ 人类活动引起的大气中温室气体浓度增加对全国或东部季风区现代降水变化影响的信号,目前仍难以识别;区域性近地面风速减弱导致的雨量观测系统偏差以及大范围气溶胶浓度增加,可能是东部季风区大多数台站观测到的强降水事件频率增加和小雨频率显著减少的两个重要原因。⑤ 主要与城市化影响相关的地面观测资料系统偏差,可以部分解释现有分析表明的短历时强降水事件频率和累计降水量增加现象,同时也很可能是城市台站小雨和痕量降水事件频率明显下降的另一重要原因。