Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.     

内蒙古大青山地区英安岩LA-ICP-MS锆石U-Pb年龄及其构造意义

在内蒙古大青山地区逆冲推覆构造所截切的英安岩中获得锆石~(207)Pb/~(206)Pb表面年龄加权平均值为1870±19Ma,认为英安岩为华北克拉通古元古代末—新元古代一次裂解事件的产物.同时,据安山岩锆石U-Pb年龄谐和度(102)较好的锆石~(206)Pb/~(238)U表面年龄436±4Ma及英安岩锆石U-Pb年龄谐和度(104)较好的锆石~(206)Pb/~(238)U表面年龄153±2Ma和160±2Ma,表明大青山地区逆冲推覆构造存在构造复活或构造追踪现象。这一认识为大青山地区逆冲推覆构造的研究积累了新的资料,提供了新的研究思路。     

VELOCITY–DISCHARGE RELATIONSHIPS DERIVED FROM DYE TRACER EXPERIMENTS IN GLACIAL MELTWATERS: IMPLICATIONS FOR SUBGLACIAL FLOW CONDITIONS

Repeated dye tracer tests were undertaken from individual moulins at Haut Glacier d'Arolla, Switzerland, over a number of diurnal discharge cycles during the summers of 1989–1991. It was hoped to use the concepts of at-a-station hydraulic geometry to infer flow conditions in subglacial channels from the form of the velocity–discharge relationships derived from these tests. The results, however, displayed both clockwise and anticlockwise velocity–discharge hysteresis, in addition to the simple power function relationship assumed in the hydraulic geometry approach. Clockwise hysteresis seems to indicate that a moulin drains into a small tributary channel rather than directly into an arterial channel, and that discharges in the two channels vary out of phase with each other. Anticlockwise hysteresis is accompanied by strong diurnal variations in the value of dispersivity derived from the dye breakthrough curve, and is best explained by hydraulic damming of moulins or sub/englacial passageways. Despite the complex velocity–discharge relationships observed, some indication of subglacial flow conditions may be obtained if tributary channels comprise only a small fraction of the drainage path and power function velocity–discharge relationships are derived from dye injections conducted during periods when the supraglacial discharge entering the moulin and the bulk discharge vary in phase. Analyses based on this premise suggest that both open and closed channel flow occur beneath Haut Glacier d'Arolla, and that flow conditions are highly variable at and between sites.     

对共反射面叠加的进一步探讨

共反射面元（CRS）叠加考虑了反射层的局部特征和第一菲涅耳带内的全部反射,更充分挖掘了多次覆盖数据的潜力.但在地下介质复杂并存在倾斜层时存在反射点分散的情况,从而影响了CRS叠加效果.本文从射线理论出发,在考虑反射层局部特征的情况下,推导了水平地表和起伏地表情况下计算真实反射点分散程度的公式,最终将反射点分散程度定量表达出来.通过对反射点分散程度的控制,从CRS道集中抽取出共反射点（CRP）道集,在CRP道集中而不是在CRS道集中实现叠加,其效果应比传统的CRS叠加效果要好.利用水平地表和起伏地表的模型验证了本文所推导的公式的正确性和有效性.该公式在实际资料处理中的运用尚待进一步研究.     

弯曲射线追踪中Dijkstra算法的改进与实现

文章针对图论中寻找最短路径的Dijkstra算法内存占用量大,效率低的缺点,对该算法进行了改进,修改后的算法计算效率是原来的四倍,内存使用量和图中节点数呈线性关系.在此基础上,用新算法求出了激发点和接收点的最短走时路径,并由激发接收点的旅行时结合联合迭代法对理论模型和实际场地进行了反演.结果表明：和直射线追踪相比,弯曲射线路径能更好地反演出地质体内部的速度场分布.理论模型和实际探测结果证实改进后的算法是有效的.     

地磁台站建设中磁测异常现象分析

地磁台建设磁性跟踪测试工作很重要,通过对跟踪磁测中发现的一个异常现象的分析,计算了不同重量、距离的铁磁性物质对磁房建筑场地磁场的影响,讨论了排除施工现场磁性干扰的一些办法,并得出各种重量铁磁性物质与磁房建筑物的安全距离,还讨论了地磁台部分建筑材料的选择问题。     

二维复杂介质中地震波走时和射线的计算方法及其应用

将Podvin和Lecomte的精确局部格点走时计算方法和Schneider等人的动态规划方法结合起来,可得到一种快速、有效的有限差分波前计算方法。使用该方法对各种类型地震波的走时和射线的计算进行了讨论,并给出了这种有限差分走时计算在叠前深度偏移中的应用实例。     

汞同位素地球化学研究及其在矿床学中的应用进展

汞作为一种重要的成矿元素,广泛分布于不同地质体中,并参与成岩成矿作用.随着质谱技术的飞跃发展,汞同位素地球化学研究取得引人瞩目的进展.汞同位素被广泛地应用于示踪地球表生生物地球化学过程及汞污染等.近年来,汞同位素又被应用于揭示行星的演化过程、识别地质历史时期大火成岩省及示踪矿床成矿物质来源等方面.本文在前人研究的基础上...     

VCT的技术特性和临床价值

本文介绍了Light Speed VCT的技术特性,包括硬件、软件和图像重建的技术进步,以及这些技术进步带来的图像质量上的改进和临床应用.这些先进的临床应用包括5秒心脏成像、胸痛三联诊等.探讨了降低病人剂量的重要性以及实现图像质量和X射线剂量的和谐和同一.