GBW10010a大米标准物质复(研)制及数据特征

随着我国对生态文明建设的重视,自然资源综合调查势在必行,对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展,自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试,需要以生物标准物质作为生物成分测试量值比对和溯源的基础,因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一,其食品安全日益受到重视,对大米中的化学成分进行准确的分析测试具有重要的现实意义,因而对大米标准物质的需求量尤为突出,但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求,开展了GBW10010a大米成分分析标准物质的复（研）制工作,包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠,符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素,包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn,其中的39项元素给出了标准值及不确定度,包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn;15项元素提供参考值,包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较,GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降,其中Cd、Cu、Zn降幅较大,分别下降约39%、43%、38.7%,一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项,新增定值元素Ag、Nb（Nb给出参考值）,并且各项元素不确定度范围整体上有所缩小,如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素,表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素,适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。     

基于标准化降水指数的内蒙古地区干旱时空变化特征

利用内蒙古及周边地区70个气象站1951~2014年降水数据,采用标准化降水指数等方法,对内蒙古近64年气候干旱时空变化进行分析。结果表明:研究区近64年来除西部年际、春、秋、冬季,中部春、秋季及东部春、冬季气候趋于湿润外,其他均趋于干旱。中、东部年际、植(作)物生长期SPI在2001年和1990年左右发生突变,东部突变后趋于干旱并在2006年左右又发生明显转折后趋于湿润。西部在1960s干旱严重,中、东部在1990s至2000s干旱严重。西部年际SPI由西北向东南、东部由南向北干旱趋势速率呈阶梯状下降,中部干旱趋势速率较西、东部快;植(作)物生长期SPI空间变化与年际一致,但西、中部干旱趋势明显的区域有所扩大。     

CFG桩复合地基承载力及桩身完整性检测试验实例分析

本文介绍CFG桩复合地基的特点及在我省的应用,利用反射波法检测桩身完整性,采用静载荷试验确定CFG桩复合地基承载力。     

Conversion relationship of rainfall-soil moisture-groundwater in Quaternary thick cohesive soil in Jianghan Plain,Hubei Province,China

The scientific field test site of rainfall-soil moisture-groundwater conversion in Dabie Mountain Area–Jianghan Plain is located in the northern region of the Jianghan Plain, the transition zone between the Dabie Mountain Area and Jianghan Plain. It’s a great field test site to study the material and energy exchange among rainfall, soil moisture, and groundwater of the Earth ’s critical zone in subtropical monsoon climate plain areas. This paper analyzed the connection between rainfall and volume water content (VWC) of soil at different depths of several soil profiles, and the dynamic feature of groundwater was discussed, which reveals the rainfall infiltration recharge of Quaternary Upper Pleistocene strata. The results show that the Quaternary Upper Pleistocene aquifer groundwater accepts a little direct rainfall recharge, while the lateral recharge is the main supplement source. There were 75 effective rainfall events among 120 rainfall events during the monitoring period, with an accumulated amount of 672.9 mm, and the percentages of effective rainfall amount and duration time were 62.50% and 91.56%, respectively. The max evaporation depth at the upper part in Quaternary cohesive soil was no less than 1.4 m. The soil profile was divided into four zones: (1) The sensitive zone of rainfall infiltration within 1.4 m, where the material and energy exchange frequently near the interface between atmosphere and soil; (2) the buffer zone of rainfall infiltration between 1.4 m and 3.5 m; (3) the migration zone of rainfall infiltration between 3.5 m and 5.0 m; and (4) the rainfall infiltration and groundwater level co-influenced zone below 5.0 m. The results revealed the reaction of soil moisture and groundwater to rainfall in the area covered by cohesive soil under humid climate in Earth ’s critical zone, which is of great theoretical and practical significance for groundwater resources evaluation and development, groundwater environmental protection, ecological environmental improvement, drought disaster prevention, and flood disaster prevention in subtropical monsoon climate plain areas.     

土工三轴试验方法-静动耦合试验

尝试了一种新的土工三轴试验方法,即在一个试样同时得到与土体静动变形和强度特性相关的各种参数。文中讨论了采用耦合试验方法时应变循环大小对静力变形和强度特性的影响;并通过与常规试验结果的比较,给出了等效弹性模量、等效阻尼比和动永久应变等动力变形参数的试验结果。试验结果表明：采用耦合试验复杂加载方式,能够更深入地研究土体的静、动变形和强度特性,尤其在复杂应力条件下的动力变形特性方面。     

基坑测斜观测数据误差分析方法研究

测斜是基坑监测的必要项目,针对测斜观测数据存在各种误差影响因素的情况,该文通过间接观测值探讨了伺服加速度计式测斜仪观测数据误差分析的统计检验方法,以期具有实际应用价值。     

CTD海上剖面测量性能综合评定方法研究

随着国产温盐深剖面仪（Conductivity-Temperature-Depth profiler,CTD） 测量性能的不断提高,其使用范围和规模也逐步扩大,需要规范CTD 海上剖面测量性能评定方法。在威海附近海域开展基于锚泊式平台CTD 海上比对试验,通过改变同架比对CTD 数量、引入相关系数和平均差数据处理方法研究海上比对试验效果,提出以精准度和灵敏度为目标层的CTD 海上剖面测量性能评价指标体系,实现了对被测CTD 海上剖面测量性能相对全面的评价,准确量化了被测CTD 在实际海洋环境中的剖面测量性能,为国产CTD 海上剖面测量性能的优化提供依据。     

Identification of modal parameters of a 600-m-high skyscraper from field vibration tests

Accurate prediction of the dynamic responses of a high-rise building subjected to dynamic loads such as earthquake and wind excitations requires the information of its structural dynamic properties such as modal parameters including natural frequencies and damping ratios. This paper presents the identification results of the modal parameters based on field vibration tests on a 600-m high skyscraper. A set of tests, including ambient vibration test (AVT) and free vibration test (FVT), were conducted on the skyscraper to identify its modal parameters. Firstly, this paper presents and discusses the modal parameters of the skyscraper assessed by several identification methods applied to the AVT measurements. These methods include the wavelet transform (WT) method, the stochastic subspace identification (SSI) method, and the random decrement technique (RDT). Secondly, an active mass damper (AMD) system with total mass 1000 tons equipped into the skyscraper was used to excite the building for estimation of the modal parameters by FVT. Thirdly, this paper presents observations on the structural dynamic behavior of the skyscraper with the operation of the AMD system during a typhoon event. The field measurement results show that the AMD system functioned efficiently for suppression of the wind-induced vibrations of the skyscraper during the typhoon. This paper aims to further understand the structural dynamic properties of super-tall buildings and provide useful information for structural design and vibration control of future skyscrapers.     

Seismic fracture evaluation of diaphragm joints in welded beam-to-box column moment connections

Steel box columns are widely used in steel building structures in Taiwan due to their dual strong axes. To transfer the beam-end moment to the column, diaphragm plates of the same thickness and elevations as the beam flanges are usually welded inside the box column. The electro-slag welding (ESW) process is widely used to connect the diaphragms to the column flanges in Taiwan because of its convenience and efficiency. However, ESW may increase the hardness of the welds and heat-affected zones (HAZs), while reducing the Charpy-V notch strength in the HAZ. This situation can cause premature fracture of the diaphragm-to-column flange welds before a large plastic rotation is developed in the beam-to-box column joints. To quantify the critical eccentricity and the effectiveness of fracture prediction, this study uses fracture prediction models and finite element model (FEM) analysis to correlate the test results. In this study, two beam-to-box column connection subassembly tests are conducted with different loading protocols and ESW chamber shapes. To implement a fracture prediction model, the material parameters are established from circumferential notched tensile tests and FEM analysis. Test results indicate that the fracture instances can be predicted on the basis of the cumulative plastic deformation in the HAZs. Analytical results indicate that fracture instances and locations are sensitive to the relative locations of the ESW joints and beam flange. Tests also confirm that the possible fracture of the diaphragm-to-column flange joints can be mitigated by enlarging the chamber of the ESW joint.     

Response of a scale-model pile group for a jacket foundation of an offshore wind turbine in liquefiable ground during shaking table tests

To investigate the seismic response of a pile group during liquefaction, shaking table tests on a 1/25 scale model of a 2 × 2 pile group were conducted, which were pilot tests of a test project of a scale-model offshore wind turbine with jacket foundation. A large laminar shear box was utilized as the soil container to prepare a liquefiable sandy ground specimen. The pile group model comprising four slender aluminum piles with their pile heads connected by a rigid frame was designed with similitude considerations focusing on soil–pile interaction. The input motions were 2-Hz sinusoids with various acceleration amplitudes. The excess pore water pressure generation indicated that the upper half of the ground specimen reached initial liquefaction under the 50-gal-amplitude excitation, whereas in the 75-gal-amplitude test, almost entire ground was liquefied. Accelerations in soil, on the movable frames composing the laminar boundary of the shear box, and along the pile showed limited difference at the same elevation before liquefaction. After liquefaction, the soil and the movable-frame accelerations that represented the ground response considerably reduced, whereas both the movable frames and the piles exhibited high-frequency jitters other than 2-Hz sinusoid, and meantime, remarkable phase difference between the responses of the pile group and the ground was observed, all probably due to the substantial degradation of liquefied soil. Axial strains along the pile implied its double-curvature bending behavior, and the accordingly calculated moment declined significantly after liquefaction. These observations demonstrated the interaction between soil and piles during liquefaction.