全文获取类型
收费全文 | 1243篇 |
免费 | 140篇 |
国内免费 | 232篇 |
专业分类
测绘学 | 6篇 |
大气科学 | 28篇 |
地球物理 | 358篇 |
地质学 | 736篇 |
海洋学 | 314篇 |
天文学 | 2篇 |
综合类 | 46篇 |
自然地理 | 125篇 |
出版年
2024年 | 9篇 |
2023年 | 27篇 |
2022年 | 32篇 |
2021年 | 33篇 |
2020年 | 39篇 |
2019年 | 47篇 |
2018年 | 44篇 |
2017年 | 49篇 |
2016年 | 59篇 |
2015年 | 53篇 |
2014年 | 68篇 |
2013年 | 70篇 |
2012年 | 51篇 |
2011年 | 79篇 |
2010年 | 51篇 |
2009年 | 96篇 |
2008年 | 114篇 |
2007年 | 82篇 |
2006年 | 80篇 |
2005年 | 66篇 |
2004年 | 67篇 |
2003年 | 41篇 |
2002年 | 42篇 |
2001年 | 47篇 |
2000年 | 49篇 |
1999年 | 35篇 |
1998年 | 42篇 |
1997年 | 32篇 |
1996年 | 20篇 |
1995年 | 13篇 |
1994年 | 13篇 |
1993年 | 16篇 |
1992年 | 11篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1984年 | 9篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1979年 | 1篇 |
排序方式: 共有1615条查询结果,搜索用时 31 毫秒
91.
珠穆朗玛峰地区雪冰中重金属浓度与季节变化 总被引:4,自引:0,他引:4
对2005 年9 月采自珠穆朗玛峰北坡海拔6523 m 的东绒布冰川积累区一批雪坑样品中重金属Ba, Co, Cu, Zn 和Pb 的浓度利用电感耦合等离子体质谱仪进行了测试, 重金属浓度范围分别为(pg/ml); Ba2~227、Co2.8~15.7、Cu 10~120、Zn29~4948、Pb14~142。并利用气体稳 定同位素质谱仪MAT-252 对样品稳定氧同位素比率(δ18O) 进行了测试, 雪坑样品对应的时间为2004 年夏到2005 年秋, δ18O和重金属元素的浓度都存在着季节变化特征。在夏季风期间δ18O 值和重金属元素的浓度都很低,而在非夏季风期间δ18O值和重金属元素浓度升高,反映了不同的水汽来源对重金属浓度季节变化的影响及其环境意义。Co, Cu, Pb, Zn 的地壳富集系数(EFc) 分别为: 3.6、27、33、180, 表明该地区Pb, Cu, Zn 已经受到了人类活动的污染, 其中Zn 受到的污染最大。 相似文献
92.
A. V. Arakel 《Australian Journal of Earth Sciences》2013,60(4):335-369
Sediment at the sediment‐water interface of natural and man‐made waterways forms an integral part of the ecosystem because it is affected by a continuous flux of physical, chemical and biological components between the sediment, interstitial water and the overlying water column. Aquatic sediments contain records of past and present urban and rural runoff, chemical discharges and spills. In recent years sediment quality has received increasing attention following identification of the role of sediment as both a sink for pollutants and as a contaminant source with potential impacts on the quality of receiving waters. Research has indicated that the processes leading to remobilization of contaminated sediments in upstream reaches of a waterway may, through time, exert a significant influence on water quality in the downstream reaches. This, together with the cumulative effects due to contaminant input from point and non‐point source discharges, have dramatic effects on water quality and thus on ecosystem structure and functioning. The problems associated with elevated concentrations of many hazardous organic and inorganic compounds have resulted in the establishment of aquatic sediment quality criteria and management guidelines in many overseas countries, with the objectives being the reduction and elimination of adverse environmental effects and human health risks associated with contaminated sediments. Whereas more than 70% of the Australian population is clustered around the coastal waterways, little is known about the role of sediments as a repository of environmental pollutants and/or as a source of adverse impacts on water quality and the health of our rivers. The paucity of knowledge on the quality of aquatic sediment highlights the need for the development of coherent guidelines for sediment quality assessment and management of contaminated sites, which are consistent with Australian environmental conditions and land use features. A comparative evaluation of sediment quality information from eight coastal rivers along the east coast of Australia, presented in this paper, indicates the possibility for establishing a framework for regional sediment quality assessment. This may be achievable by using textural and compositional attributes of bottom sediments in depositional areas to develop databases on the loading and concentration trends of nutrients and contaminants. Regional variability in sediment quality determinants are shown to reflect the influence of catchment hydrology, lithology and land use on nutrient and contaminant concentration trends. Locally, the loading and partitioning behaviour of sediment‐bound contaminants is largely controlled by the nature and the extent of interactions occurring at the sediment‐water interface within individual depositional units. The concept of ‘Sediment Effect Zone’ is introduced to provide a compartmental approach to the characterization of aquatic sediments and depositional environments in different hydrologic zones. This approach offers a rational basis for follow‐up chemical and biological assessments to establish sediment quality standards and management guidelines. Because of the complex influences of environmental, methodological and statistical factors on defining the sediment variability, the need for implementing proper quality control measures from early stages of design of a sediment quality assessment program is highlighted. 相似文献
93.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引:1,自引:0,他引:1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
94.
Raw and retorted spent oil shales from Kentucky, as well as soil and overburden materials, were subjected to laboratory and field leaching tests. Standard batch leaching tests grossly undervalue the amount of dissolved ions as measured in the field, being too brief to enable slow reactions of the mineral matrix, such as hydrolysis and oxidation of sulfides or reactions of acidic leachates with soluble components of the clays. Laboratory column tests, devised to closely simulate natural leaching processes, achieved concentration levels and elemental release patterns similar to those found in field tests. The column tests provide a reliable means to assess the leachability of metals in these materials. 相似文献
95.
Lesley A. Warren Ann P. Zimmermann 《Aquatic Sciences - Research Across Boundaries》1994,56(4):348-362
We examined particle size distributions of suspended particulate matter (SPM); physical and environmental influences on the observed distributions; and relationships between particle size and geochemical partitioning of metals, over the fall and winter period in a small urban river (Don River, Toronto, Ontario, Canada). For this dataset, the majority of particles (80%) in suspension were less than 10 µm in size. In addition, while total SPM concentrations showed a positive trend with increasing discharge (Q); the proportions of particles found within given size classes were independent of both SPM concentration and Q. Temperature was the only measured environmental variable related to the particle concentrations within size classes. As water temperature increased, the concentration of particles in the smallest size class (1–4 µm) decreased, while the concentration of silt and/or algae sized particles (10–50 µm) increased. Increasing water temperatures may promote bacterial attachment to particles and their subsequent flocculation into larger sized particles. Decreasing concentrations of leachable (most labile) Cd, Zn and Mn were associated with increasing concentrations of the largest particles (70–150 µm) in suspension. In contrast, higher reducible (oxides) associated concentrations of Cd, Zn and Mn occurred with increasing concentrations of smaller particles (1–10 µm) in suspension. Both of these trends are speculated to reflect the importance of particle surface area for metal sorption reactions. 相似文献
96.
D. A. Burney R. V. DeCandido L. P. Burney F. N. Kostel-Hughes T. W. Stafford Jr. H. F. James 《Journal of Paleolimnology》1995,13(3):209-217
A sediment core from a high-elevation bog on Maui in the Hawaiian Islands contains evidence for drier conditions between 9.4–5.8 kyr BP, followed by a wetter interval between 5.8–2.2 kyr BP, and a variable late Holocene. These precipitation changes may be a reflection of vertical displacements of the upper boundary of the mid-Pacific Trade Wind Inversion (TWI) cloud layer. Fires, probably volcanically ignited, occurred in the forests prior to human arrival. Polynesian activity in this high-elevation, remote site was apparently limited, with no pollen, charcoal, or sedimentological evidence for local anthropogenic disturbance. After European contact, grass fires increased and introduced plant species invaded the site. Values for Cd, Cu, Pb, and Zn in sediments throughout the Holocene indicate low trace-metal deposition from atmospheric particulates at the site, even in the twentieth century.This paper is one of a series of papers guest edited by Dr. Mark Brenner on tropical paleolimnology 相似文献
97.
98.
The early diagenetic environment of intertidal sandy sediments (sands) and muddy sediments (muds) is described and compared from two cores taken from an unpolluted part of the Manukau Harbour, New Zealand. Extraction techniques characterized the form of the trace elements (Fe, Mn, S, C, Pb, Zn, Cu) at different depths in the sediment. Dissolved forms of Fe, Mn, and S were measured in interstitial water. Nonresidual metal concentrations, humic acid, FeS, and FeS2 are an order of magnitude higher in the muds than in the sands because of dilution by unreactive sand particles. Muds contain a larger proportion of metals in the mobile fractions; exchangeable (Mn), carbonate (Mn, Fe, Zn), and easily-reducible oxide (Fe, Mn, Zn, Pb). This is due to greater surface area (for Mn adsorption); the favorable conditions for MnCO3, FeCO3, and FeS precipitation; and higher concentrations of easily reducible iron oxide and humic acid. Therefore, compared to the sands, muds are more important as reservoirs for toxic metals, both in terms of quantity and availability. At either site there was very little difference between the forms of Zn, Pb or Cu identified by sequential extraction as sediments changed from oxic to anoxic conditions. One reason for this is that the amounts and proportions of some of the important components that bind metals, viz., amorphous iron hydrous oxides, humic acids, and FeS2, do not change much. Other components that do change with redox conditions, for example, manganese phases and FeS, are only minor components of the sediment. Redox conditions, then, have relatively little effect on trace-metal partitioning in the sediment matrix of these unpolluted sediments. 相似文献
99.
North End Lake is a polluted and eutrophic freshwater system located in Port Elizabeth, South Africa. Since the lake is expected
to be used for recreational/tourist purposes by 2010, a rehabilitation program will have to be designed. For this reason,
we retrieved a sediment core from the central region of the lake to decipher the effect of historical human impacts on the
water body. Pre-disturbance paleolimnological inferences indicate that the lake was likely mesotrophic. After ∼1831, when
sheep farming activities were undertaken in the catchment, increases in trophic state and changes in sediment composition
were observed. After ∼1937, increases in trace metal levels, organic matter, spheroidal carbonaceous particles (SCP) and changes
in sediment composition were recorded. The system became eutrophic as indicated by the dominance of the diatom Actinocyclus normanii, a cosmopolitan species often observed in systems where water quality has been dramatically degraded. The conditions worsened
after 1986 because of the construction of a storm-water retention system, which intentionally channeled storm-water runoff
into the lake. Because of this, extremely high values of fecal coliforms (i.e. 2 × 106 every 100 ml) have been measured in the water column. The paleolimnological information identified the sharp increase in
organic content in the uppermost section of the core, and this could be correlated to the operation of the storm-water retention
system. Therefore, as an immediate management measure, we suggest that the storm-water retention system should either no longer
be utilized, or the storm-water runoff should be treated before disposal into the lake. In addition, an effective sewage system
has to be constructed. 相似文献
100.
Marc Rütschlin Johannes H. Cloete Iain M. Mason Keith D. Palmer 《Journal of Applied Geophysics》2007,62(4):354-360
A new measurement technique enables the complex dielectric properties of the geological strata comprising the UG1–UG2 (Upper Group 1–Upper Group 2) unit of the Bushveld Complex in South Africa to be determined with unprecedented detail at radio frequencies (RF). Results of non-destructive laboratory measurements of representative diamond drill core samples from the UG1–UG2 unit are presented at 25 MHz. These data establish that the UG1 and UG2 chromitite layers are embedded in rock strata (norite, pyroxenite and anorthosite) which are translucent in the HF spectral band, whereas the chromitite layers themselves exhibit significant velocity contrast, making them good radar reflectors. The data presented here is useful for calibration of the radar system, and for predicting the range and resolution performance of borehole radars operating in both the hanging and footwalls of the economically important platiniferous UG2 reef. 相似文献