Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

青藏高原祖尔肯乌拉山地区火山岩Ar-Ar年代学初步研究

对祖尔肯乌拉山地区 4个火山岩样品进行了Ar -Ar年龄测定 ,其坪年龄分别为 (40 91± 1 18)Ma、(41 0 7± 0 80 )Ma、(42 0 0± 1 31)Ma、(39 0 0± 2 0 6 )Ma。它们代表了这些火山岩的形成时代 ,表明本区在古近纪始新世中期发生过大规模的火山活动     

碳酸岩Sr、Nd、Pb 同位素地球化学研究评述

碳酸岩是出露相对较少的幔源岩石，其中Sr与Nd是研究地幔物质组成的主要对象之一。本文统计了世界上主要碳酸岩的锶、钕、铅同位素组成特征；研究显示，碳酸岩源区主要是洋岛玄武岩高U／Pb的HIMU端员和富集端员(EM1或EM2)的混合作用；此外大部分碳酸岩的锶、钕同位素落在大洋玄武岩范围内；这些均表明其成因与地慢柱有密切联系。碳酸岩及与之共生的硅酸岩的同源或独立源区模式部很难充分解释两者同位素组成特征，逭反映碳酸岩的演化模式涉及更复杂的过程。可能是俯冲作用使碳酸岩源区经历不同时间和程度的富集、亏损过程导致地幔源区成分不均一。     

大渡河次级支流斯合沟泥石流特征研究

泥石流作为地质环境较差、的山区的主要自然灾害之一，对它的研究尤其是泥石流规律方面的研究已取得了较大的成绩。但是对于泥石流的研究思路却有待进一步发展和完善，这在很大程度上将对山区的工程建设有很重要的指导意义。论文从工程地质研究思路的角度出发，对位于大渡河支流官料河上某水电站下闸址区的斯合沟泥石流进行了研究。文中采用工程地质分析的方法对大渡河次级支流斯台沟泥石流的形成环境(地层岩性条件、构造条件、地貌条件、气象条件、植被发育及人类活动)、基本特征(泥石流沟的基本特征、泥石流的堆积特征)进行了系统的研究，提出了该泥石流的形成演化过程及其机制模型(初期是堰塞式沟谷型泥石流，后期逐渐转向汇聚式沟谷型泥石流)。并在此基础上对泥石流沟沿岸的岸坡稳定性(可能泥石流的物源)等进行了评价分析。将定性分析和定量分析相结合，对泥石流的活动趋势以及可能泥石流的体积(未来泥石流形成将主要是在面蚀和沟蚀作用下的坡面泥石流。泥石流规模较小，且由于沟谷中下游坡降的进一步减缓，形成的泥石流物质一般将沿途停积．实际进入官料河内的体积很小)做出了较为科学的评价预测。经过这样的系统分析对工程建设中的泥石流防治有着积极的指导意义。     

三峡大坝建成后长江输沙量的减少及其对长江三角洲的影响

三峡大坝建成之后,大量泥沙滞留于库区,出库泥沙量减少,坝下河床冲刷而提供相当数量的泥沙,支流湖泊供沙也发生变化,这将使进入河口地区的泥沙有所减少。三峡大坝以上长江干流和支流建设新的大坝,南水北调、封山育林、退耕还林以及减少水土流失都将进一步减少长江进入河口地区的泥沙。由此估计,三峡大坝建成后的百年内长江输入河口地区的泥沙约为2.0×10⁸～2.5×10⁸t/a;冰后期长江三角洲形成和发育期间的长江年均输沙量为1.84×10⁸～2.28×10⁸t。二者的数值相当接近,然而与近50年的观测(4.33×10⁸t/a)相差甚远,长江流域的气候变化和人类活动可能是造成这一现象的原因。文章着重说明中国和长江上游人口的增长、种植作物的改变可能是水土流失、长江泥沙量增长的主要原因。     

Estimating coefficients of volume compressibility from compression of strata and piezometric changes in a multiaquifer system in west Taiwan

This paper estimates the coefficients of volume compressibility from variation in compressible layer thickness and changes in piezometric heads by using detail ground surface surveys and a multilayer monitoring well at a selected site (Shigang) within the Choshui River alluvial fan in west Taiwan. The paper integrates various types of in situ monitoring tools, including leveling surveys, continuous global position system (GPS) stations, multilevel layer compression and groundwater pressure head-monitoring wells, to investigate the situation and progress of the subsidence problem in the region. The results from the cross-analyses of the measured data show that surface settlement caused by the compression of strata is between the depths of 60 and 210 m where the clayey stratum within 120-180 m was most pronounced and contributes up to 53% of the total compression. The results indicate that the clayey stratum is under normal consolidation. The results also reflect the fact that 20% of settlement contribution comes from the sandy stratum within 90-120 m; the elasto-plastic behavior of this sandy stratum is clear. The coefficients of volume compressibility of the clayey and sandy stratum analysed from the stratum's compression records; they were 6.38×10⁻⁸ and 5.71×10⁻⁹ m²/N, respectively. Ultimately, this parameter estimation would permit to control and predict land subsidence based on change in pressure head which are related to groundwater extraction.     

黄河流域天然径流量突变性与周期性特征

突变性和周期性是水文时间序列的两个重要特征。黄河流域面积广阔，各区域水文水资源系统演变规律各不相同，它们的突变和周期变化及其形成的物理机制遍异，因此系统分析各区域水资源突变性和周期性特征及其影响机制具有重要意义。把黄河流域划分为15个区域，计算出各区域1951—1998年的年天然径流量系列。利用Mann-Kendall非参数检验方法检测黄河流域各区域年天然径流量的突变年份，结果表明各区域的突变年份不完全一致，主要在1953—1955年、1979—1983年、1991—1993年等发生了突变，这些突变与北半球气候突变具有一致性，且由于下垫面改变、人类活动等影响而复杂化。利用Morlet小波分析各区域年天然径流量的变化周期，发现主要存在3～4a、7～9a、11a的周期，形成这些周期的物理因子有太阳黑子、海—气相互作用和下垫面因素等。通过分析黄河流域主要产流区不同时段小波系数变化，发现20世纪80年代之后年径流量主要以短周期变化。     

金沙江流域(云南境内)山地灾害危险性评价

云南境内的金沙江流域是斜坡不稳定的敏感区,根据1988-2000年的区域调查和统计,区内发育山地灾害点1697处,其中流域面积大于1km2的泥石流沟808条,体积大于1×104m3的滑坡580处,体积大于1000m3的崩塌309处。用于山地灾害危险性评价的主要敏感因子包括岩土体类型、山坡坡度、降雨、土地利用、地震烈度和人类活动。在对这些因子进行了敏感性评价的基础上,应用GIS对敏感因子集成评价而产生了云南金沙江流域山地灾害危险性评价图。评价结果表明:高危险区面积占全区面积6464km2的8 77%,中危险区占全区总面积的41 51%,低危险区占41 12%,无危险区占8 60%。山地灾害危险性评价图可以帮助规划者或工程师在土地发展规划中选择最佳建设场所,以减轻灾害的影响。     

嘉陵江流域旅游开发

在研究嘉陵江流域旅游资源优势和开发现状的基础上，针对目前该流域旅游发展现状和存在的问题，提出了具体的应对措施，以期能为该流域的旅游开发提供参考。     

美国"阳光带"的崛起对中国西部城市化战略的启示

美国西部开发以城市化为先导，中国西部大开发本质上也是西部城市化。西部大开发战略应以城市为中心组织与落实。本文通过透视美国“阳光带”城市崛起的历史，尤其是产业集群的成功经验，提出中国西部城市化战略实施中应将培育地方产业集群作为推动城市化的重要战略方式和地方重要的公共政策工具。