温度对沸石吸钾量检测的影响研究

沸石具有选择性吸附钾离子的特性,吸钾量是沸石应用中一项重要的物化性能,温度是影响吸钾量测量结果准确度的重要因素。在现有的吸钾量测试方法中,由于对测试温度的规定较为模糊,基本不作设定或只注明室温,而室温随季节变化较大,测试方法的准确度和精密度无法得到保证。为完善吸钾量的测试方法,本文研究了实际温度对沸石吸钾量的影响。结果表明,在试验的温度范围内(11.5~80℃),沸石样品的吸钾量与温度呈稳定且相对固定的负相关,由此提出了吸钾量计算公式:E20=Et+k(t-t20)。根据该定量关系,本文提出吸钾量测试方法中需要明确规定吸钾量的测试温度为20℃;如果是在非20℃的实际温度下测量得到的吸钾量,可根据温度校正系数(k)转换到20℃条件下的吸钾量。这种吸钾量测试方法可在实际室温下进行,操作简单,无需使用控温装置;又能消除因时间和地域差异导致的室温波动的影响,使吸钾量测试结果具有更好的精密度和准确度。     

多年冻土区路基尺度效应对路面结构力学响应的影响

为了研究不同尺度路基融沉作用对路面结构层力学响应的影响,建立了基于热力耦合理论的有限元模型,系统研究不同路基尺度工况下,融沉作用对不同厚度路面、不同材料基层的力学分布规律影响. 结果表明：相同的融沉条件下,整体式路基较分离式及二级路基,变形分别增大45%、64%,应力增大17.5%、21.7%. 高速公路面层由于路基较宽,地基融沉更容易向上传递,进而导致面层底部应力增大,最终造成面层的破坏. 因此,路面设计过程中保证一定的面层厚度,并采用柔性基层减小模量,可有效以降低层底应力水平,并防止基层裂缝向上反射.     

青海省共和-玉树高速公路新建块石路基下的温度状况分析

块石路基是多年冻土区应用最为广泛的多年冻土路基形式. 为了研究多年冻土区修筑高速公路后块石路基的效果,选取青海省新建共和-玉树高速公路3个块石路基监测断面的实测资料,对路基修筑初期多年冻土温度状况进行了分析. 结果表明：路基修筑初期路基中心原天然地表下0.5 m处仍表现出季节变化规律,至原多年冻土上限深度处,温度波动幅度急剧减小. 块石路基的保温效果与年平均地温密切相关,年平均地温越低,对冻土的保护效果越显著. 受阴阳坡效应的影响,左路肩/坡脚温度高于右路肩/坡脚. 左右路肩及中心孔下多年冻土上限都得到不同程度的抬升,抬升幅度主要受路基高度影响,与多年冻土年平均地温没有必然关系.     

基于嫦娥二号微波辐射计数据月球中低纬度亮温异常区地质分析研究

月球表面的微波辐射亮度温度与月表地质结构和月表物质的物理化学特性相关。为了对月球亮温分布异常区域进行地质分析,文章首先计算嫦娥亮温数据的时角,采用克里金插值的方法得到了不同频率不同时刻中低纬度的微波亮温图。结合奇异值分解(SVD)模型分析了月表亮温变化异常,结果表明风暴洋位置和靠近月海东北部的高地区域等存在亮温变化异常,月海区域(除风暴洋外)为3 GHz和37 GHz两个场的总体相关区域。通过对月球火山分布地区的区域亮温变化进行分析,发现这热异常可能是由于月球火山活动造成的。     

Skarn development from limestone adjacent to the Glenrock Granodiorite,Marulan Batholith,New South Wales,Australia

Skarns are developed over two temperature‐time intervals in calcite limestone adjacent to the southern extension of the Glenrock Granodiorite, a pluton of the Marulan Batholith, Southern Highlands, New South Wales. The initial volumetrically‐dominant prograde phase of skarn formation produced a suite comprising bimetasomatic skarn, including pyroxene endoskarn, potassic endoskarn and wollastonite‐bearing exoskarn, together with mineralogically‐zoned vein skarn, massive garnet‐pyroxene skarn and calcite‐vesuvianite skarn. Retrograde replacement is manifested by the development of hydrous silicate minerals, carbonate and cross‐cutting sulphide veinlets.

A genetic model is proposed to account for the development of bimetasomatic skarn in the deposit. Exoskarn geochemistry indicates addition of many components relative to an essentially pure limestone precursor, including Si, Al, Fe, Zr, Zn, S, Mn and Cu, negligible transfer of K, Na and Rb and loss of CO₂. Strontium and Ca loss from the parent limestone is indicated by mass balance calculations at constant volume.

Garnet and pyroxene compositions in the massive garnet‐pyroxene skarn range from Gr₃₀ to Gr₆₆ and Hd₆₁ to Hd₈₇, respectively. Compositions from Gr₆₇ to Gr₉₅ are typical of the vein skarn garnets. Chemical zonation patterns in garnet, pyroxene and vesuvianite are generally characterized by rim Fe depletion relative to cores of grains.

Prograde skarn probably formed at T = 500–580°C; P < 220 MPa. The massive garnet‐pyroxene skarn evolved under conditions of log fO₂ = ‐18.9 to ‐22.9 (assuming a constant fCO₂ of 20 MPa) within the fS₂ stability field of pyrrhotite. Retrograde skarn formed at T < 400°C, possibly under conditions of X_H2O < 0.01.

Vesuvianite plus wollastonite assemblages, present in exoskarn, probably attest to very water‐rich conditions. The marble wall rocks, isolated from the source of skarn‐forming fluids, probably evolved under conditions of minimum X_co2 >0.2. Low temperature CO₂ ‐rich fluid inclusions and prehnite (stable at X_co2 <0.01), present in the marble and skarn, respectively, suggest that substantial differences in X_co2: X_H2O were maintained during cooling.

Observed mineralogical and chemical zonation within the skarn reflects the complex interaction of T, P, fO₂, Xco₂ and other chemical variables such as a_SiO2 and a_Al2O3 throughout the skarn system. No single variable can account adequately for the mineralogical diversity observed in the skarn deposit.     

High‐ to ultrahigh‐temperature metamorphism in the lower crust: An example resulting from Hikurangi Plateau collision and slab rollback in New Zealand

Lower crustal xenoliths erupted from an intraplate diatreme reveal that a portion of the New Zealand Gondwana margin experienced high‐temperature (HT) to ultrahigh‐temperature (UHT) granulite facies metamorphism just after flat slab subduction ceased at c. 110–105 Ma. P–T calculations for garnet–orthopyroxene‐bearing felsic granulite xenoliths indicate equilibration at ~815 to 910°C and 0.7 to 0.8 GPa, with garnet‐bearing mafic granulite xenoliths yielding at least 900°C. Supporting evidence for the attainment of HT and UHT conditions in felsic granulite comes from re‐integration of exsolution in feldspar (~900–950°C at 0.8 GPa), Ti‐in‐zircon thermometry on Y‐depleted overgrowths on detrital zircon grains (932°C ± 24°C at aTiO₂ = 0.8 ± 0.2), and correlation of observed assemblages and mineral compositions with thermodynamic modelling results (≥850°C at 0.7 to 0.8 GPa). The thin zircon overgrowths, which were mainly targeted by drilling through the cores of grains, yield a U–Pb pooled age of 91.7 ± 2.0 Ma. The cause of Late Cretaceous HT‐UHT metamorphism on the Zealandia Gondwana margin is attributed to collision and partial subduction of the buoyant oceanic Hikurangi Plateau in the Early Cretaceous. The halt of subduction caused the fore‐running shallowly dipping slab to rollback towards the trench position and permitted the upper mantle to rapidly increase the geothermal gradient through the base of the extending (former) accretionary prism. This sequence of events provides a mechanism for achieving regional HT–UHT conditions in the lower crust with little or no sign of this event at the surface.     

锆石裂变径迹(ZFT)年代学:进展与应用

裂变径迹技术是解决各种与时间-温度相关的地质问题的一种低温年代学手段.与磷灰石相比,锆石裂变径迹具有较高的封闭温度和退火区间,有其特定的地质意义和应用.自20世纪90年代以来,开展了大量锆石裂变径迹退火的研究,包括退火特性、径迹测量、退火模型,以及来自露头和钻孔样品的退火研究.首先介绍了锆石裂变径迹的分析程序、测量标准...     

多年冻土区典型地面浅层地温对降水的响应

在大气-地面-冻土之间存在复杂的水热变化过程,降水是青藏高原地区主要的水分补给来源,在浅层形成水热变化的不连续层。通过对北麓河地区降水和工程路面(沥青路面、砂砾路面)、天然地面(高寒草原、高寒草甸)浅层(0~80cm)温度数据的原位监测,分析在不同降水量和不同时段浅层的温度变化,结果表明:北麓河地区年降水量逐年增加,增加速率为22.9mma-1。降雨主要集中在5~9月。白天地温对降水的响应比夜间强烈。工程路面夜间的温度变化大于天然地面。在相同降水条件下, 10:00~15:30时段的温度变化量大于16:00~18:00时段。随着降雨量的增加,温度下降幅度增大。砂砾、高寒草原、高寒草甸地面地温对降水的响应深度范围为0~30cm。受路面结构中隔水层的影响,沥青路面为0~20cm,且5cm深度温度的变化幅度大于地表。为进一步研究不同地面类型不同水热传输模式层结的划分提供数据基础。     

Estimation of runoff distribution within river systems: Application to the Lena Basin (Siberia)

A channel account approach is proposed to estimate longitudinal changes in runoff along large river systems. This new method provides a quantitative basis for describing the fluvial transport of suspended particulate material and dissolved substances. This method includes an evaluation of basic elements of water balance in separate sections of the river network and subsequent correction of channel accounting equations for the entire system using a maximum likelihood principle. To calculate water discharges of tributaries that have no hydrological information, structural analysis of river network is performed. This approach provides less error in comparison with traditional methods of estimating lateral inflow. The method is used to trace water discharge with increasing distance along the Lena river basin and to evaluate the contribution of geologically and lithologically uneven sub-basins in water discharge formation during a summer low water period.