Study on copper complexing ligand concentrations in several China’s coastal waters

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows: Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer (SSL) in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complexing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China' s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.     

东海浮游翼足类(Pteropods)数量分布的研究

根据1997～2000年东海海域23°30'～33°00'N,118°30'～128°00'E的4个季节海洋调查资料,运用定量、定性方法,探讨了东海浮游翼足类总丰度的平面分布、季节变化及变化的动力学机制.结果表明,东海翼足类总丰度和出现频率有明显的季节变化,均为秋季最高,夏季次之,春季最低;总丰度在各个季节基本上呈东海南部高于北部、外海高于近海的分布趋势;春季的尖笔帽螺(Creseis acicula)、夏季的锥笔帽螺(Creseis virgula)、秋季的蝴蝶螺(Desmopterus papilio)和冬季的马蹄螔螺(Limacina trochiformis)是导致总丰度季节变化的最主要的种类;冬、春和夏3个季节丰度变化及4季总丰度的变化同表层或10m层水温有非常显著的线性相关关系,与底层温度及盐度的相关关系不显著.夏季翼足类高丰度区位于台湾暖流与黑潮暖流的分支处;从夏季到秋季,翼足类随着台湾暖流向北扩展,并在与长江冲淡水,闽浙沿岸水团,黄海水团等交汇处形成高丰度(大于500×10-2个/m3)和较高丰度(250×10-2～500×10-2个/m3)分布区.水温和海流是影响东海翼足类总丰度分布的主要环境因素.     

福建闽南沿海养殖贝类体中砷含量的分布

通过2003~2004年对福建闽南沿海5种养殖贝类体砷含量的调查监测,对养殖贝类体中砷含量的分布进行了探讨.福建闽南沿海5种养殖贝类体总砷含量为0.65×10-6~4.80×10-6,总平均值为2.09×10-6,其中有机砷和无机砷占总砷含量的百分比分别为61.6%~98.2%和2.3%~38.4%,平均值分别为88.8%和11.2%.在相同养殖区,养殖贝类体总砷平均含量的种间分布差异较小.滩涂养殖底栖贝类体内总砷平均含量总体上高于浅海筏式养殖贝类体的平均含量.福建闽南沿海5种养殖贝类体内总砷含量在泉州湾、湄州湾、东山湾和九龙江口高,在诏安湾和围头湾低,在其余各湾相近.5种养殖贝类体内无机砷的污染指数和总平均值分别为0.05~0.76和0.23,总砷的污染指数和总平均值分别为0.06~0.48和0.21,总体符合国家食品卫生质量标准.养殖贝类体中砷含量与体长之间总体成正相关.     

热带印度洋偶极子发生和演变机制的数值研究

对中国科学院大气物理研究所(IAP)大气科学和地球流体力学数值模拟国家重点实验室(LASG)发展的第三代海洋模式(L30T63 OGCM)进行了改进。分析了该模式1959年1月—1998年12月的40a积分结果，以此研究热带印度洋偶极子发生、发展和消亡的物理机制。对数值模拟结果的分析表明，赤道印度洋表面异常东风引起的异常环流结构是偶极子发生、发展的主要动力学原因，其表面异常东风转换为异常西风所引起的异常环流结构调整是偶极子消亡的主要动力学原因；海气界面热通量异常的交换对热带印度洋海表温度距平偶极子模态的形成和演变起着重要的作用；垂直输送作用是热带印度洋次表层海温偶极子模态发生和演变的主要物理机制。     

A probability distribution for depth-limited extreme wave heights in a sea state

A model for the depth-limited distribution of the highest wave in a sea state is presented. The distribution for the extreme wave height is based on a probability density function (pdf) for depth-limited wave height distribution for individual waves [Méndez, F.J., Losada, I.J., Medina, R. 2004. Transformation model of wave height distribution. Coastal Eng, Vol. 50, 97:115.] and considers the correlation between consecutive waves. The model is validated using field data showing a good representation of the extreme wave heights in the surf zone. Some important statistical wave heights are parameterized obtaining useful expressions that can be used in further calculations.     

Horizontal spatial and temporal distribution patterns of nearshore larval fish assemblages at a temperate rocky shore

There have been no previous studies of the composition of nearshore larval fish assemblages along the coast of Portugal. We aimed to describe the composition and horizontal distribution patterns of larval fish assemblages and their temporal dynamics near a rocky reef at depths shallower than 13 m (inshore) and at two miles (3.70 km) from shore (offshore), as well as along transects perpendicular to the shoreline, from the reef to 10 miles offshore (18.52 km). Samples were taken using 5 min sub-surface trawls at the rocky shore of the Arrábida Marine Park (W Portugal). A total of 1021 larvae were collected, belonging to 61 taxa inshore and to 29 taxa offshore. Along transects, 626 larvae of 52 taxa were collected. Most larvae belonged to coastal species associated with rocky reefs. Total larval abundance and diversity were higher from May to July, which is consistent with the spawning activity of adults. Diversity and total larval abundance decreased significantly with increasing distance from shore, both in the inshore/offshore comparison and in the transects, where this decrease was evident at a very small spatial scale (within the first mile from the reef). Species assemblages differed in the pattern of distribution, with most species clearly associated to the extreme nearshore. The distribution patterns obtained were independent of the spawning mode of species. Results are discussed in the light of the possible physical mechanisms that can potentially act at the Arrábida Marine Park to facilitate larvae retention and the role of larval behaviour.     

Southern elephant seal trajectories, fronts and eddies in the Brazil/Malvinas Confluence

This study describes the association between transient, mesoscale hydrographic features along the axis of the Brazil–Malvinas Confluence, in the SW Atlantic, and the foraging behavior of 2–3-year-old (focal) juvenile southern elephant seals, Mirounga leonina, from Península Valdés, Argentina. Departing from the dominant pattern of foraging on predictable bathymetric fronts on the Patagonian shelf and slope, three females out of 12 satellite-tracked juveniles remained at the edge of young warm-core eddies and near the outer core of cold-core eddies, coinciding with the most productive areas of these temperature fronts. Seal trajectories along high-temperature gradients were always consistent with the speed and direction of surface currents inferred from the temperature distribution and confirmed by surface drifters. Movements of foraging seals were compared with those of surface drifters, coinciding in time and space and yielding independent and consistent data on regional water circulation parameters. The diving pattern recorded for one focal seal yielded shallower dives and a loose diel pattern in the eddy, and a marked diurnal cycle compatible with foraging on vertically migrating prey in the cold waters of the Malvinas Current. Pre-reproductive females that use the mesoscale fronts of the Argentine Basin as an alternative foraging area would benefit from lower competition with more experienced seals and with other top predators that reproduce along the coast of Patagonia.     

Aliasing due to sampling of the Adriatic temperature, salinity and density in space

High-resolution underway temperature and conductivity measurements collected by R/V Knorr during winter and spring 2003 are used to characterize errors associated with spatial aliasing in the northern and central Adriatic Sea. During winter, 99th percentile temperature, salinity and density errors were 0.62 °C, 0.25 and 0.12 kg/m³ (0.25 °C, 0.10 and 0.05 kg/m³) for sampling at 10 km (5 km) horizontal resolution, respectively. The corresponding values in spring were 1.31 °C, 0.50 and 0.40 kg/m³ (0.93 °C, 0.25 and 0.22 kg/m³) for the 10 km (5 km) sample spacing, respectively. The largest errors were associated with energetic regions over the shallow, western Adriatic, in front of the Po River mouth and off the tip of the Istrian peninsula. The deeper eastern basin exhibited smaller errors. The variability of errors in time and space reflected the variability of small-scale density features, characterized by wavelengths as small as 2 km in winter and 1 km in spring and being more pronounced in the western and northern parts of the Adriatic. As these results indicate that errors associated with undersampling can be considerable, they should be taken into account while planning future CTD measurements in the region.     

黄海、渤海底层温度数值预报方法的研究

根据文献［ｌ］建立的底层温度（ＴＨ）与其水柱垂向平均温度（）的经验关系，结合流体动力学方程和（垂向平均）热传导方程，发展了以水气温差和风速为已知量的底层温度二维数值预报模式。该模式避开了海面热量和动量输入在垂直水柱中分配的复杂物理过程而直接报出底层水温场，具有较好的实用性；此外，从试报结果看，效果令人满意。