无色-近无色高温高压合成钻石的谱图特征及其鉴别方法

实验室发现大量小颗粒的无色高温高压(HPHT)合成钻石与天然钻石混杂镶嵌在各种饰品中,前人提出荧光和磷光特征是主要的快速区分特征,然而荧光、磷光特征的差异并不能完全将HPHT合成钻石与天然钻石区分开来。本文将常规的宝石学观察分析与多种高精度谱学测试相结合,对五粒不同的无色-近无色HPHT合成钻石样品进行深入研究。结果表明,五粒钻石在紫外可见吸收光谱无270 nm吸收或是只有极弱的270 nm吸收,随着颜色级别的降低,270 nm吸收越明显。红外光谱测试显示,各粒样品中都含有不等量的硼元素。光致发光光谱测试表明,HPHT合成钻石含有与微量N、Ni、Si等相关的晶格缺陷。超短波紫外光源激发下,所有的HPHT合成钻石都有强磷光,在钻石观察仪下可以观测到清晰的八面体和立方体分区特征。显然,不同的合成钻石的特征略有差异,但综合其荧光及磷光特征以及红外、紫外、光致发光光谱特征,可以准确地将无色HPHT合成钻石与对应的天然钻石区分开来。     

新型GV5000宽频诱导发光测试仪的研制及其应用于筛分无色小颗粒合成钻石和天然钻石

天然钻石中普遍含有聚合氮以及复杂的生长结构,而合成钻石不含氮或含少量单氮并有典型的与合成条件有关的生长结构,利用此类性质可对天然和合成钻石进行区分。但对粒度细小或镶嵌复杂的钻石样品进行检测时,现有仪器由于局限性难以实现有效测量。本文研制了一种新型宝石发光性测试装置——宽频诱导发光测试仪(GV5000),通过对激发光源和滤光片、结构设计和测试方式的研发,实现了可同时观察多个小颗粒样品(最小为0.002 ct)的荧光特征和磷光特征,建立了一种以发光特征差异性作为筛分条件快速、准确筛分无色小颗粒天然钻石和合成钻石的分析方法。应用本方法测试了9015粒样品,并通过红外光谱、光致发光光谱等方法对筛查结果进行验证,表明97%的天然钻石具有蓝白色荧光并无磷光,而合成钻石的发光特征明显区别于天然钻石。本方法避免了样品大小和形状的影响,提高了小颗粒钻石鉴定的准确度和检测效率,对天然钻石的筛查率可达97%,对合成钻石的筛查率可达100%。     

Precise and Accurate Doping of Nanoporous Silica Gel for the Synthesis of Trace Element Microanalytical Reference Materials

This study presents an experimental procedure to fabricate high‐purity silica glass containing a selected element at a specified mass fraction. The procedure was used to prepare glasses doped with trace‐level mass fractions of Ti with the goal of improving analytical confidence when measuring trace elements in quartz. Systematic tests were performed to determine the ideal conditions and procedures for doping nanoporous silica gel with the highest efficiency of dopant recovery. Silica gel was cleaned in concentrated HCl, immersed in a non‐polar doping medium at a controlled pH and doped with precise quantities of ICP‐MS standard solution. Using liquids composed of longer chain molecules as the doping medium diminishes recovery, suggesting that large molecules could obstruct nanopores to inhibit capillary uptake of the dopant. A control experiment using crystalline quartz reinforced the effectiveness of nanoporous silica gel for doping with trace‐level precision. Layered aggregates of silica gel doped with different Ti mass fractions were hot‐pressed to create multi‐layered reference materials that were analysed with multiple techniques at a variety of spatial scales. Analyses at the intra‐grain scale (cathodoluminescence scanning electron microscopy, electron probe microanalysis), at the single grain scale (SIMS), at the sample layer scale (EPMA, laser ablation‐ICP‐MS) and at the bulk scale (ICP‐OES) demonstrated acceptable homogeneity at sample volumes characteristic of most microanalysis techniques and show that nanoporous silica gel holds promise as a highly retentive doping substrate for preparing reference materials for laser‐, electron‐ and ion‐beam microanalysis.     

Linear flow behaviour of matched joints – case study on standard JRC profiles

Roughness on rock joints produces a variable aperture across the joints and increases the flow path length. These conditions should be taken into account for a good approximation from cubic law. In this paper, the concept of local true aperture and tortuosity is applied to assumed joints where surfaces are matched to each other and correspond with standard Joint Roughness Coefficient (JRC) profiles. Furthermore, the hydraulic behaviour of JRC profiles is studied by a new laboratory experiment setup. The analytical approach provides new insights into the effects of roughness on hydraulic properties of rock joints. The results indicate that for a constant mechanical aperture, both the minimum local aperture and hydraulic aperture decrease with increasing JRC. Furthermore, tortuosity and standard deviation of local true aperture increase with JRC increment. The trend obtained between different parameters and JRC shows an obvious fluctuation for JRC lower than 10. On one hand, the results of this study along with a critical review of previous studies demonstrate that JRC profiles cannot present a precise roughness increment when JRC is less than 10. A new laboratory setup was designed to study the flow behaviour of JRC profiles. The results obtained from laboratory experiments under linear flow conditions validate the accuracy of the applied analytical method.     

基于模糊综合评判的海洋溢油污染评估模型研究

在分析总结相关研究成果的基础上,利用模糊综合评估方法,对溢油污染程度相关影响因素进行深入分析研究,对溢油污染程度评估指标体系进行改进和完善,提出溢油量和离岸距离两个影响因子新的隶属度函数,构建新的海域敏感区隶属度子集表并计算各指标的权重。最后,应用此模型对2002年渤海绥中36-1油田中心平台溢油事故进行评估,结果显示污染程度评估等级有明显提高,以期为海洋溢油污染评估提供科学依据,并通过提高污染评估等级引起人们对海洋环境的重视。     

六边形格网的快速傅里叶变换

全球离散格网系统是支持多源地球空间数据融合处理的新型数据模型,傅里叶变换是联系其空域与频域的纽带,对以格网系统为框架的遥感图像的增强具有重要意义。根据三孔六边形格网剖分方案,设计了一种规则六边形格网单元组合结构,并将该结构空间域的二维离散傅里叶变换转化为可以用蝶形算法加速的标准一维变换。采用遥感影像进行实验验证,结果表明本文提出的快速傅里叶变换算法正确、高效,其复杂度为N log2N。随着数据量增大,效率以指数函数形式提高。     

合成孔径雷达反演黄海海面风场

基于后向散射系数反演高空间分辨率海面风场,采用谱方法确定风向,并利用CMOD4模式函数反演风速。以ERS-2 SAR黄海区域图像为例,反演海面风场,并将反演结果同QuikSCAT散射计对比,比较吻合,证明该方法在黄海区域的可行性。     

The Kefalonia Transform Zone (offshore Western Greece) with special emphasis to its prolongation towards the Ionian Abyssal Plain

Information concerning two seismic lines, the first located northwest of the Lefkada Island and the second from the deep Ionian basin to the gulf of Patras, is used to trace the Kefalonia Transform Zone (KTZ) and to explore its relation with the sedimentary sequences and the deeper geologic structures in the study area. In addition, sea bottom topography and fault plane solutions are combined in order to explore the prolongation of the KTZ into the Ionian Abyssal Plain (IoAP) and to describe its properties. The boundary between the subduction of the eastern Mediterranean oceanic crust under the overriding continental crust and the KTZ is well constrained by the seismic data in association with seismicity and regional stress field. The southern prolongation of the KTZ is located in the IoAP towards the direction between Kefalonia and Zakynthos Islands at depth greater than 15 km. The southern part of the KTZ exhibits a strike–slip motion with a thrust component according to fault plane solutions of moderate and strong earthquakes. The seismic section mostly confirms the existence of the thrust component and gives information about the tectonic status east and west of the KTZ.     

Determination of source parameters of small earthquakes in the east part of Guandong and south part of Fujian Province

Determination of source parameters of small earthquakes from amplitude ratios of and is studied in this paper when the distribution of the regional seismic network is skew to the earthquakes. The distribution of stations of the seismic network was to one side of the 17 earthquakes chosen from among 39 earthquakes in the east part of Guangdong and south part of Fujiang Province. The distribution of stations was classified into three types according to their relative positions with respect to the chosen earthquakes and the experiments of artificial data were done. Excellent results were also presented in various unfavourable conditions by using the method. As to the 39 small earthquakes recorded by the network in east Guangdong and south Fujian Province from 1982 to 1986, the results can be summarized as follows: Most of the fault planes of the earthquakes apear to be steep. Most of the principal compression stressesP and tensile stressesT are nearly horizontal, concentrating in the WNW-ESE direction. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinia,13, 420–429, 1991.     

A method for estimating earthquake occurrence probability using first- and multiple-order Markov chain models

It is valuable in earthquake prediction to determine the occurrence probability of major earthquakes by making use of data obtained from precursory phenomena up to the time of the evaluation. In this study, the time evolution of the state determined by earthquakes and precursory phenomena was modelled using Markov chains. Various probabilities suitable for earthquake prediction were derived from the transition probability of the Markov chain with a chosen length of memory time. As an example, earthquake sequence records for northern China, which covered a period of about two thousand years, were examined and the results were also obtained from modern scientific observations of the radon anomaly which covered a period of about 10 years.Assuming moderate-sized earthquakes of two magnitude ranges 4 3/4 M 5 3/4, 6 M 6 3/4 as precursors to large earthquakes of a magnitude range, 7 M 8 1/2, transition probabilities were calculated for a time interval from 2 to 40 yr. The results showed that the precursory time of moderate-sized earthquakes is mainly distributed in a time span of around several years and that the earthquake occurrence probability is considerably large when the precursory earthquakes occur successively. Furthermore, it was shown that a larger moderate-sized earthquake (4 3/4 M 5 3/4) is a more effective precursor than an entire moderate-sized earthquake (4 3/4 M 6 3/4).Second, a multiple precursor case was tried by means of simulation based on the radon anomaly data obtained during a limited observation period. Simultaneous occurrence of two precursors makes the earthquake occurrence probability increase by 1.5–2.0 for a reasonable choice of a mean recurrence interval of the radon anomaly compared with the case where only a moderate-sized earthquake was treated as the precursor. However, the probability is much the same if the average recurrence interval of the radon anomaly is the same through time, including the preparatory period before the earthquake.