Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.     

Speciation of adsorbed arsenate on the surface of hydrous iron oxide

Adsorption of arsenate on hydrous iron oxide is an important process controlling geochemical cycling of arsenic in environment as well as the fate of arsenic-bearing mining wastes. The widely accepted view on the mechanism of adsorption is that arsenate is adsorbed via bidentate binuclear inner-sphere complexation. In this study, we characterized the arsenate-hydrous iron oxide sorption solids synthesized at pH=3-8 using Fourier transformed infrared spectroscopy （FTIR） and X-ray diffraction （XRD）. It has been determined that poorly crystalline ferric arsenate developed on the surface of iron oxide when arsenate was sorbed at acidic pH, while at alkaline pH the adsorption of arsenate was via bidentate complexation.     

Permeable Reactive Barrier for the treatment of contaminated surface water in Katedan industrial development area, Hyderabad, India

Permeable Reactive Barrier （PRB） is an emplacement of inert material （s） in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments？ The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute （NGRI）, Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute （NGI）, Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,     

Crustal structure of the Eastern Alps along the TRANSALP profile from wide-angle seismic tomography

The objective of the TRANSALP project is an investigation of the Eastern Alps with regard to their deep structure and dynamic evolution. The core of the project is a 340-km-long seismic profile at 12°E between Munich and Venice. This paper deals with the P-wave velocity distribution as derived from active source travel time tomography. Our database consists of Vibroseis and explosion seismic travel times recorded at up to 100 seismological stations distributed in a 30-km-wide corridor along the profile. In order to derive a velocity and reflector model, we simultaneously inverted refractions and reflections using a derivative of a damped least squares approach for local earthquake tomography. 8000 travel time picks from dense Vibroseis recordings provide the basis for high resolution in the upper crust. Explosion seismic wide-angle reflection travel times constrain both deeper crustal velocities and structure of the crust–mantle boundary with low resolution. In the resulting model, the Adriatic crust shows significantly higher P-wave velocities than the European crust. The European Moho is dipping south at an angle of 7°. The Adriatic Moho dips north with a gentle inclination at shallower depths. This geometry suggests S-directed subduction. Azimuthal variations of the first-break velocities as well as observations of shear wave splitting reveal strong anisotropy in the Tauern Window. We explain this finding by foliations and laminations generated by lateral extrusion. Based on the P-wave model we also localized almost 100 local earthquakes recorded during the 2-month acquisition campaign in 1999. Seismicity patterns in the North seem related to the Inn valley shear zone, and to thrusting of Austroalpine units over European basement. The alignment of deep seismicity in the Trento-Vicenza region with the top of the Adriatic lower crust corroborates the suggestion of a deep thrust fault in the Southern Alps.     

3-D seismic structure of the source area of the 1993 Latur, India, earthquake and its implications for rupture nucleations

The Latur earthquake (M_w 6.1) of 29 September 1993 is a rare stable continental region (SCR) earthquake that occurred on a previously unknown blind fault. In this study, we determined detailed three-dimensional (3-D) P- and S-wave velocity (V_p, V_s) and Poisson's ratio (σ) structures by inverting the first P- and S-wave high-quality arrival time data from 142 aftershocks that were recorded by a network of temporary seismic stations. The source zone of the Latur earthquake shows strong lateral heterogeneities in V_p, V_s and σ structures, extending in a volume of about 90 × 90 × 15 km³. The mainshock occurred within, but near the boundary, of a low-V_p, high-V_s and low-σ zone. This suggests that the structural asperities at the mainshock hypocenter are associated with a partially fluid-saturated fractured rock in a previously unknown source zone with intersecting fault surfaces. This might have triggered the 1993 Latur mainshock and its aftershock sequence. Our results are in good agreement with other geophysical studies that suggest high conductivity and high concentration of radiogenic helium gas beneath the source zone of the Latur earthquake. Our study provides an additional evidence for the presence of fluid related anomaly at the hidden source zone of the Latur earthquake in the SCR and helps us understand the genesis of damaging earthquakes in the SCR of the world.     

The Tornquist Zone, a north east inclining lithospheric transition at the south western margin of the Baltic Shield: Revealed through a nonlinear teleseismic tomographic inversion

From July 1996 to August 1997 the TOR project operated 130 seismographs in North Germany, Denmark and South Sweden, with the aim of collecting signals from local, regional and teleseismic earthquakes. This data set is particularly interesting since the seismic antenna crosses the most significant geological boundary in Europe, the Tornquist Zone, which in the northern part is the border between the Baltic Shield and the younger European lithosphere. Previous studies have shown significant physical changes in the crust and upper mantle across this transition zone, including two independent teleseismic tomographic studies of the TOR data set. But these two studies disagree on the orientation of the slope of the transition. Both studies used an iterative linearized inversion method. We will in this work Preprint submitted to Elsevier Science 27 July 2005 present an inversion based on Bayesian statistics, where the solution space is examined in order to study a very large number of tomographic solutions and to examine the solution uniqueness and uncertainty. The method is applied to measurements of 3345 relative teleseismic P-phase travel times from 48 teleseismic earthquakes with good azimuthal coverage with respect to the great circle arc of the TOR array. We find the lithospheric transition to be a north east inclination of around 30° to 45° off vertical.     

Deep structure of the Nojima Fault, southwest Japan, estimated from borehole observations of fault-zone trapped waves

To estimate the deep structure of the southern part of the Nojima Fault, southwest Japan without the influence of near-surface structures, we analyzed the Love-wave-type fault-zone trapped waves (LTWs) recorded by a borehole seismometer at 1800 m depth. We examined the polarization, dispersion, and dominant frequency of the wavetrain following the direct S-wave in each seismogram to identify the LTW. We selected eight candidates for typical LTWs from 462 records. Because the duration of the LTW increases with hypocentral distance, we infer that the low velocity fault-zone of the Nojima Fault continues towards the seismogenic depth. In addition, since the duration of the LTW increases nonlinearly with hypocentral distance, we infer that the S-wave velocity of the fault-zone increases with depth. The location of events showing the LTW indicates that the fault-zone dips to the southeast at 75° and continues to a depth of approximately 10 km. We assumed a uniform low-velocity waveguide to estimate the average structure of the fault-zone. We estimated the average width, S-wave velocity, and Q_s of the fault-zone by comparing an analytical solution of the LTW with measured data. The average width, S-wave velocity, and Q_s of the fault-zone are 150 to 290 m, 2.5 to 3.2 km/s, and 40 to 90, respectively. Hence the fault-zone structure with a larger width and smaller velocity reduction than the fault-zone model estimated by previous surface observation is more suitable to represent the average fault-zone structure of the Nojima fault. The present study also indicated that the shallow layers and/or a shallow fault-zone structure drastically changes the characteristics of the LTW recorded at the surface, and therefore cause a discrepancy in the fault-zone model between the borehole observation and surface observation.     

冲击凿岩钎杆的瞬态动力学分析

以ANSYS为平台，按照真实工作状态对凿岩钎杆进行了瞬态动力学分析，并对不同活塞形状下分析结果数据进行了比较，为冲击凿岩系统设计提供了理论依据。     

大变形有限元法分析边坡稳定性

边坡稳定性分析的重要任务是确定边坡潜在滑面的位置及相应的安全系数,鉴于坡体位移可在现场监测中直接得到,提出边坡潜在滑面确定的位移判据,采用大变形有限元首先计算出边坡的位移场,然后在开挖面的不同高度作塑性区内的水平位移参考线,依次连接参考线上的位移突变点即得到边坡失稳的潜在滑面位置,分析滑面上的应力以及岩体抗剪强度即得到边坡的整体安全系数。     

用于湿地气候效应模拟的三江平原下垫面数据获取

三江平原是我国沼泽湿地的重要分布区。在20世纪的后50 a中,三江平原在经过几次大规模的开荒后,其下垫面发生了明显的阶段性变化,湿地大面积消失,农田面积不断增加。为了认识20世纪下半叶不同时期三江平原湿地的气候效应,拟采用第三代区域气候模式(RegCM3)来开展研究。而目前被广泛用于RegCM3的GL-CC数据,所反映的研究区下垫面几乎不存在沼泽湿地,这与事实严重不符,所以必须获取三江平原有沼泽湿地存在的真实的下垫面数据,才能得到可靠的湿地气候效应的模拟结果。分别选择了4期(1954年、1985年、1996年和2000年)有阶段代表性的航片、TM影像数据为主要数据源,利用ERDAS8.7和Arcview3.2等软件,首先得到4期研究区的土地利用数据,然后通过土地利用数据类型向模式数据类型的转换,从4期研究区土地利用数据中提取出了三江平原下垫面的模式数据。经过误差分析,认为获取的4期三江平原下垫面模式数据准确的反映出研究区几个时期的湿地下垫面实况,可以作为三江平原湿地气候效应模拟的基础数据。