Group Time Delay in the Reflection of P-Polarized Electromagnetic Plane Waves at a Stratigraphic Interface

The group time delay (GTD) formulae of quasi-total reflection of inhomogeneous P-polarized electromagnetic waves (P-PEW, whose electric field parallels to the plane of incidence), caused by the Goos–Hänchen effect, is derived by the phase shift of the wave. A numerical example where the frequency equals to 1 GHz is given. The curves of calculating results show that there are three discontinuous points at the critical angle of phase shift vector, the critical angle of attenuation vector and 90^○. When the angle of incidence is equal to one of these three angles, the GTD will become infinite, and the electromagnetic wave will propagate along the interface. The GTD will be very large, when the angle of incidence is close to one of these three angles. The results indicate that there is an important relationship between the two critical angles and the conductivity and permittivity of the two strata, and that the GTD has an important relationship with the angle of incidence. These results can be used to determine the lithology of the strata and to delimit the interfaces of strata more effectively. It is suggested that this research may prove useful in electromagnetic logging analysis and, perhaps, in the design of logging instruments.     

山区煤田地震勘探中静校正存在的问题及其改进方法

在山区或地表复杂地区进行地震勘探,采用基于地表一致性假设的静校正将会严重影响勘探效果,该影响主要源于地表一致性假设存在着不合理因素。如较高的低速带、巨厚的低速带、基岩裸露、地形起伏较大等。为分析一致性假设静校正偏差产生的原因及大小．构建一地形起伏、基岩出露的复杂模型,通过正演其射线路径,对比其时距曲线与理论时距曲线的差异,以及二者静校正量误差大小。模型分析证实该差异与偏移距、地震波穿透深度及基准面高程之间存在直接的联系,据此提出了改进方法,如浮动基准面校正及分块静校正等。理论模型和实际地震资料试算表明,使用改进的方法可有效改善地震时间刮面同相轴聚焦效果及连续性。     

New basis for the constitutive modelling of aggregated soils

Natural and compacted soils are usually characterized by aggregation of particles. The mechanical behaviour of these materials depends on soil structure. The oedometric compression tests performed on aggregated samples presented here showed that these materials exhibit a yield limit depending not only on stress history and stress state but also on soil structure. Evidence is provided using the neutron tomography technique. These results revealed that soil structure modification occurs together with plastic deformations. The experimental results are used to propose a new state parameter to quantify the soil structure. Based on pore-scale experimental observations, an evolution law for this parameter is proposed as a function of associated plastic strains. Considering both soil fabric and inter-particle bonding effects, a new yield limit depending on stress state, stress history and soil structure is introduced for the aggregated soils. Accordingly, a new constitutive framework consistent with strain hardening plasticity is proposed to consider soil structure effects in the modelling of aggregated soils.     

(ϖμ/ϖT) P of the lower mantle

We estimate (/T) _P of the lower mantle at seismic frequencies using two distinct approaches by combining ambient laboratory measurements on lower mantle minerals with seismic data. In the first approach, an upper bound is estimated for |(/T) _P | by comparing the shear modulus () profile of PREM with laboratory room-temperature data of extrapolated to high pressures. The second approach employs a seismic tomography constraint ( lnV _S / lnV _P ) _P =1.8–2, which directly relates (/T) _P with (K _S /T) _P . An average (K _S /T) _P can be obtained by comparing the well-established room-temperature compression data for lower mantle minerals with theK _S profile of PREM along several possible adiabats. Both (K _S /T) and (/T) depend on silicon content [or (Mg+Fe)/Sil of the model. For various compositions, the two approaches predict rather distinct (/T) _P vs. (K _S /T) _P curves, which intersect at a composition similar to pyrolite with (/T) _P =–0.02 to –0.035 and (K _S /T) _P =–0.015 to –0.020 GPa/K. The pure perovskite model, on the other hand, yields grossly inconsistent results using the two approaches. We conclude that both vertical and lateral variations in seismic velocities are consistent with variation due to pressure, temperature, and phase transformations of a uniform composition. Additional physical properties of a pyrolite lower mantle are further predicted. Lateral temperature variations are predicted to be about 100–250 K, and the ratio of ( lnp/ lnV _S ) _P around 0.13 and 0.26. All of these parameters increase slightly with depth if the ratio of ( lnV _S / lnV _P ) _P remains constant throughout the lower mantle. These predicted values are in excellent agreement with geodynamic analyses, in which the ratios ( ln / lnV _S ) _P and ( / lnV _S ) _P are free parameters arbitrarily adjusted to fit the tomography and geoid data.     

SOME NEW UNDERSTANDINGS OF LAND-SURFACE PROCESSES IN ARID AREA FROM THE HEIFE*

The survey for the HEIFE(Atmosphere-Land Surface Processes Experiment at Heihe River Basin,Western China) is given in the paper.The following basic subjects for land-surface processes in arid areas are studied:(1) the general characteristics of the energy budget on ground surface in arid areas;(2) the parameterization of the land surface processes;(3) the interaction between oasis and its desert circumstances,a special phenomenon in arid areas.The analysis shows that the sensible heat flux in the surface energy budget is in the majority,and the latent heat flux may be neglected.The influence of atmospheric stratification stability on the turbulent transfer of energy and substance must be considered in parameterization of land surface processes in arid areas.The "cold island effect" phenomenon in oasis and the "humidity inversion" phenomenon in desert near oasis are the result of the interaction between them.The results would improve the understanding of land surface processes in arid areas.     

Energy balance of simple elastodynamic sources

Complete relations are derived for energy and energy flux of elastic waves generated by an isotropic and double-couple source in a perfectly elastic, homogeneous, isotropic, and unbounded medium. In the energy balance of elastodynamic sources near-field waves play an essential role, transforming static energy into wave energy, andvice versa. For explosive and dislocation sources, the sources surface radiates a positive wave energy that is partially distributed to the medium transforming into static energy. For implosive and antidislocation sources, the source surface generates elastic waves, but it does not necessarily imply that it also radiates a positive wave energy. The energy transported by waves can originate in gradual transformation of the static-to-wave energy during propagation of waves through a stressed medium.On leave from Geophysical Institute, Czech Academy of Sciences, Boní II/1401, 41 31, Praha 4 Czech Republic     

Earthquake rupture complexity due to dynamic nucleation and interaction of subsidiary faults

We numerically study the dynamic interaction of propagating cracks. It is assumed that propagating cracks can nucleate and drive subsidiary cracks because of shear strain enhancement near the propagating crack tips. The critical strain fracture criterion is assumed in the analysis. Intense interaction is expected to occur among the cracks. All the cracks are assumed to be parallel and antiplane strain deformation is assumed in the computation.In the interaction of two non-coplanar cracks, a strain shadow is formed in the neighborhood of each crack because of the strain release by the introduction of the crack. The growth of each crack is accelerated when the propagating tips of each crack are outside of the strain shadow of the other crack. In general, the crack tips enter the strain shadow, and the crack tips decelerate. The calculation shows that only one of the two cracks can continue to grow, and the other's growth is decelerated and arrested. If we can assume that the suite of cracks interact in a pairwise manner only, then this may suggest that only a limited number of cracks can continue to grow during the final stage of the rupture process. Hence the crack interaction causes complexity in dynamic earthquake faulting. The concepts of barrier and asperity have been employed by many researchers for the interpretation of complex seismic wave data. However, the physical realities of such concepts are obscure. Our calculations show that dynamic crack interactions can produce barriers and asperities in some cases; the crack tip deceleration or arrest due to the interactions among non-coplanar cracks can be interpreted as being due to a barrier. The dynamic coalescence among the coplanar cracks can be regarded as an asperity.Umeda found a localized area that strongly radiates high-frequency seismic waves in the epicentral areas of some large shallow earthquakes. He defined this as an earthquake bright spot. Our analysis implies that only a limited number of cracks continue to grow when many interactive cracks nucleate, and that all other cracks stop extending soon after nucleation. Hence, if the nucleation and termination of several cracks occur in a localized area, it will be observed seismologically as an earthquake bright spot. This is because it is theoretically known that the sudden termination of crack growth and dynamic crack coalescence efficiently emits high-frequency elastic waves.     

The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.