基于传统吸附烃概念的烃类检测新技术

烃类是地表油气地球化学勘查地下油气藏的直接指标.目前我国油气化探中常用的酸解烃法检测出的烃类,不应定义为"吸附烃",它是介质吸收的产物,属结合态烃类,应定义为"吸收烃".地表酸解烃异常十分稳定,重现性好,能够很好地证明地质历史上曾经有过的烃类运移过程,但在反映目前深部油气信息方面具有多解性.针对酸解烃法的弱点,依据烃类垂向运移理论和物质吸附作用原理,自行设计开发、研制了一套吸附烃脱气装置,建立了土壤吸附烃提取新技术和检测方法.该方法有利于在近地表获取油气系统的动态信息,强化烃类测量法对其信息源的探测,可以提高地表油气化探预测油气分布的成功率.     

A sub-pixel analysis of urbanization effect on land surface temperature and its interplay with impervious surface and vegetation coverage in Indianapolis,United States

This study developed an analytical procedure based upon a spectral unmixing model for characterizing and quantifying urban landscape changes in Indianapolis, Indiana, the United States, and for examining the environmental impact of such changes on land surface temperatures (LST). Three dates of Landsat TM/ETM+ images, acquired in 1991, 1995, and 2000, respectively, were utilized to document the historical morphological changes in impervious surface and vegetation coverage and to analyze the relationship between these changes and those occurred in LST. Three fraction endmembers, i.e., impervious surface, green vegetation, and shade, were derived with an unconstrained least-squares solution. A hybrid classification procedure, which combined maximum-likelihood and decision-tree algorithms, was developed to classify the fraction images into land use and land cover classes. Correlation analyses were conducted to investigate the changing relationships of LST with impervious surface and vegetation coverage. Results indicate that multi-temporal fraction images were effective for quantifying the dynamics of urban morphology and for deriving a reliable measurement of environmental variables such as vegetation abundance and impervious surface coverage. Urbanization created an evolved inverse relationship between impervious and vegetation coverage, and brought about new LST patterns because of LST's correlations with both impervious and vegetation coverage. Further researches should be directed to refine spectral mixture modeling by stratification, and by the use of multiple endmembers and hyperspectral imagery.     

基于弹性薄板的地表沉陷预计模型

在分析地表沉陷基本规律的基础上,依据弹性薄板理论,建立非充分采动条件下岩层和地表沉陷预计的一类新模型,并推导出地表任意点倾斜、曲率、水平移动以及水平变形的计算公式。该模型充分考虑到地质采矿因素（煤层倾角）及煤层上方各岩层的影响,克服传统预测方法的缺陷,特别是概率积分法关于拐点反对称要求。最后,应用实例证明该方法的应用效果。     

黄土台缘滑坡地表水入渗问题分析

黄土塬区提灌工程保证了农业生产,却造成了地下水位大幅抬升,使得近年来黄土台缘滑坡不断发生。黄土滑坡一个普遍特征就是后缘发育地裂缝以及落水洞,使地表水（灌溉水以及降雨）直接灌入坡体,诱发了大量黄土滑坡。因此,地表水入渗对于黄土滑坡机理研究以及滑坡防治具有重要意义。文章基于对陕西泾阳南塬黄土滑坡的现场调查,对黄土台缘滑坡地表水入渗工程地质问题进行了初步分析,包括：①地表水入渗与落水洞形成机制;②地表水入渗途径及其与黄土滑坡发育过程的关系;③降雨因素对于黄土滑坡的影响程度。     

框架预应力锚杆边坡支护结构的稳定性分析方法及其 应用

以边坡极限平衡理论及框架预应力锚杆边坡支护结构的圆弧滑动破坏模式为基础,在考虑框架、锚杆对土体边坡稳定性影响的情况下,基于圆弧滑动条分法的思想利用积分法建立了内部稳定性安全系数计算模型和最危险滑移面搜索模型。确定滑移面圆心坐标为几何控制参数,推导了安全系数计算模型中各变量与滑移面圆心坐标之间的函数关系式,从而获得了滑移面几何控制参数与内部稳定性安全系数之间的函数关系。利用网格法对框架预应力锚杆支护结构最危险滑移面的圆心坐标进行动态搜索和求解。最后采用Matlab语言编制了框架预应力锚杆边坡支护结构的稳定性分析程序,并结合工程实例进行了验算,讨论了此种方法的适用条件,结果表明该方法简明适用,较传统的经验分析方法更加合理。     

Time-dependent stress change during failure of rocks

The energy balance of a solid subject to fracture has been explored using heat and mass transfer equations with regard to the volumetric and superficial components. In the suggested model, brittle fracture of a cracked solid considered as a heterogeneous two-phase medium is described by an equation analogous to the Griffith’s criterion for propagation of a single crack. The derived equation is used, together with estimates of relative change in specific interface area, to study the respective change of free strain energy and pressure in rocks associated with failure.     

Estimation of hydraulic permeability considering the micro morphology of rocks of the borehole YAXCOPOIL-1 (Impact crater Chicxulub,Mexico)

Internal surface, formation factor, Nuclear Magnetic Resonance (NMR)-T2 relaxation times and pore radius distributions were measured on representative core samples for the estimation of hydraulic permeability. Permeability is estimated using various versions of the classic Kozeny–Carman-equation (K–C) and a further development of K–C, the fractal PaRiS-model, taking into account the internal surface. In addition to grain and pore size distribution, directly connected to permeability, internal surface reflects the internal structure (“micro morphology”). Lithologies could be grouped with respect to differences in internal surface. Most melt rich impact breccia lithologies exhibit large internal surfaces, while Tertiary post-impact sediments and Cretaceous lithologies in displaced megablocks display smaller internal surfaces. Investigations with scanning electron microscopy confirm the correlation between internal surface and micro morphology. In addition to different versions of K–C, estimations by means of NMR, pore radius distributions and some gas permeability measurements serve for cross-checking and calibration. In general, the different estimations from the independent methods and the measurements are in satisfactory accordance. For Tertiary limestones and Suevites bulk with very high porosities (up to 35%) permeabilites between 10⁻¹⁴ and 10⁻¹⁶ m² are found, whereas in lower Suevite, Cretaceous anhydrites and dolomites, bulk permeabilites are between 10⁻¹⁵ and 10⁻²³ m².     

New basin modelling results from the Polish part of the Central European Basin system: implications for the Late Cretaceous–Early Paleogene structural inversion

Combined subsidence and thermal 1D modelling was performed on six well-sections located in the north-western Mid-Polish Trough/Swell in the eastern part of the Central European Basin system. The modelling allowed constraining quantitatively both the Mesozoic subsidence and the magnitude of the Late Cretaceous–Paleocene inversion and erosion. The latter most probably reached 2,400 m in the Mid-Polish Swell area. The modelled Upper Cretaceous thickness did not exceed 500 m, and probably corresponded to 200–300 m in the swell area as compared with more than 2,000 m in the adjacent non-inverted part of the basin. Such Upper Cretaceous thickness pattern implies early onset of inversion processes, probably in the Late Turonian or Coniacian. Our modelling, coupled with previous results of stratigraphic and seismic studies, demonstrates that the relatively low sedimentation rates in the inverted part of the basin during the Late Cretaceous were the net result of several discrete pulses of non-deposition and/or erosion that were progressively more pronounced towards the trough axis. The last phase of inversion started in the Late Maastrichtian and was responsible for the total amount of erosion, which removed also the reduced Upper Cretaceous deposits. According to our modelling results, a Late Cretaceous heat-flow regime which is similar to the present-day conditions (about 50 mW/m²) was responsible for the observed organic maturity of the Permian-Mesozoic rocks. This conclusion does not affect the possibility of Late Carboniferous–Permian and Late Permian–Early Triassic thermal events.     

Coalification in Carboniferous sediments from the Lötschberg base tunnel

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.     

地面核磁共振模型约束反演含水层参数

导电模型的地面核磁共振感应电动势是含水量的非线性函数.引入模型约束的迭代反演方法求解该非线性问题的反演.在反演过程中,根据理论公式计算迭代过程中灵敏度矩阵,并采用平坦模型和光滑模型两种约束.对均匀半空间、层状导电模型和实际数据进行了反演模拟,结果表明,模型约束迭代反演方法能从地面核磁共振感应电动势获得含水层较为合理的含水量及分布,且该结果可以从作为初始模型的均匀含水量分布反演得到.对无噪音数据,平坦模型和光滑模型约束对反演的含水量分布影响不大;但当数据存在一定的噪音时,平坦模型约束将比光滑模型约束获得更为精确的含水层参数.