基坑潜水疏干的简化计算在昊华水泥厂中的应用

以流线、流面、汇点的概念为基础,对稳定流双井干扰和直线隔水边界附近涌水量理论公式进行对比分析,提出了二个虚拟界面,其中虚拟界面Ⅰ,运用流线、流面的性质,流线方程等给出证明;虚拟界面Ⅱ则通过半无限条形降落漏斗的分析,应用元流和总流的能量方程得到流量为零,流线为零的平面。在同样条件下,条形无限涌水量是半无限潜含水层涌水量的二倍。应用总流能量方程对三种情况水头损失的分析,解释了这种关系存在的合理性,得出虚拟界面Ⅱ,并以此得出该界面内的最大残余水头计算公式。将基坑降水运用虚拟界面简化为扇形,条形半无限含水层,从而实现单井预测,该方法应用到昊华水泥厂基坑降水中,预测效果理想。     

Multi-Scale Texture Modeling

Patterns of crystallographic preferred orientation are referred to as texture. The specific subject of texture analysis is the experimental determination and interpretation of the statistical distribution of orientations of crystals within a specimen of polycrystalline material, which could be metals or rocks. The objective is to relate an observed pattern of preferred orientation to its generating processes and vice versa. In geosciences, texture of minerals in rocks is used to infer constraints on their tectono-metamorphic history. Since most physical properties of crystals, such as elastic moduli, the coefficients of thermal expansion, or chemical resistance to etching depends on crystal symmetry and orientation, the presence of texture imparts directional properties to the polycrystalline material. A major issue of mathematical texture analysis is the resolution of the inverse problem to determine a reasonable orientation density function on SO(3) from measured pole intensities on , which relates to the inverse of the totally geodesic Radon transform. This communication introduces a wavelet approach into mathematical texture analysis. Wavelets on the two-dimensional sphere and on the rotational group SO(3) are discussed, and an algorithms for a wavelet decomposition on both domains following the ideas of Ta-Hsin Li is given. The relationship of these wavelets on both domains with respect to the totally geodesic Radon transform is investigated. In particular, it is shown that the Radon transform of these wavelets on SO(3) are again wavelets on . A novel algorithm for the inversion of experimental pole intensities to an orientation density function based on this relationship is developed.     

山区煤田地震勘探中静校正存在的问题及其改进方法

在山区或地表复杂地区进行地震勘探,采用基于地表一致性假设的静校正将会严重影响勘探效果,该影响主要源于地表一致性假设存在着不合理因素。如较高的低速带、巨厚的低速带、基岩裸露、地形起伏较大等。为分析一致性假设静校正偏差产生的原因及大小．构建一地形起伏、基岩出露的复杂模型,通过正演其射线路径,对比其时距曲线与理论时距曲线的差异,以及二者静校正量误差大小。模型分析证实该差异与偏移距、地震波穿透深度及基准面高程之间存在直接的联系,据此提出了改进方法,如浮动基准面校正及分块静校正等。理论模型和实际地震资料试算表明,使用改进的方法可有效改善地震时间刮面同相轴聚焦效果及连续性。     

SOME NEW UNDERSTANDINGS OF LAND-SURFACE PROCESSES IN ARID AREA FROM THE HEIFE*

The survey for the HEIFE(Atmosphere-Land Surface Processes Experiment at Heihe River Basin,Western China) is given in the paper.The following basic subjects for land-surface processes in arid areas are studied:(1) the general characteristics of the energy budget on ground surface in arid areas;(2) the parameterization of the land surface processes;(3) the interaction between oasis and its desert circumstances,a special phenomenon in arid areas.The analysis shows that the sensible heat flux in the surface energy budget is in the majority,and the latent heat flux may be neglected.The influence of atmospheric stratification stability on the turbulent transfer of energy and substance must be considered in parameterization of land surface processes in arid areas.The "cold island effect" phenomenon in oasis and the "humidity inversion" phenomenon in desert near oasis are the result of the interaction between them.The results would improve the understanding of land surface processes in arid areas.     

地震综合效应场函数及其在地震预报中的应用──（一）地震综合效应场函数及其计算方法

在系统地分析了目前各种测震学地震预报方法科学思路的基础上,认为测震学地震预报方法基本上可以分为两大类。一类是以已经发生的一些地震作为未来可能发生的地震的“因”,即由于已经发生的地震对区域应力场的影响,导致未来发生较强地震。这一类包括的预报方法较多,如空区、条带、ｂ值、地震迁移、相关地震等等及其由此衍生出来的各种方法。另一类是把已经发生的一些地震作为区域应力场增强的“果”,即已经发生的地震是区域应力场增强过程中的一种反映,而未来地震不一定是已经发生的地震所导致的结果。这一类包括“地震窗口”、小震群活动等方法。针对第一类方法,各种预报方法都是力图从地震三要素中提取未来地震的信息,而具体作法又都是利用地震三要素这个多维空间的某个剖面。为了从地震活动诸要素的多维空间提取综合信息,我们对每个地震加入了破裂面方位,构成了地震第四要素,并依据地震４要素建立了地震综合效应场函数。地震综合效应场函数概括了多种测震学地震预报方法的科学思路和预报经验,从而可以形成测震学的综合预报方法。     

Estimation of covariance matrix from geochemical data with observations below detection limits

Multivariate statistical analyses have been extensively applied to geochemical measurements to analyze and aid interpretation of the data. Estimation of the covariance matrix of multivariate observations is the first task in multivariate analysis. However, geochemical data for the rare elements, especially Ag, Au, and platinum-group elements, usually contain observations the below detection limits. In particular, Instrumental Neutron Activation Analysis (INAA) for the rare elements produces multilevel and possibly extremely high detection limits depending on the sample weight. Traditionally, in applying multivariate analysis to such incomplete data, the observations below detection limits are first substituted, for example, each observation below the detection limit is replaced by a certain percentage of that limit, and then the standard statistical computer packages or techniques are used to obtain the analysis of the data. If a number of samples with observations below detection limits is small, or the detection limits are relatively near zero, the results may be reasonable and most geological interpretations or conclusions are probably valid. In this paper, a new method is proposed to estimate the covariance matrix from a dataset containing observations below multilevel detection limits by using the marginal maximum likelihood estimation (MMLE) method. For each pair of variables, sayY andZ whose observations containing below detection limits, the proposed method consists of three steps: (i) for each variable separately obtaining the marginal MLE for the means and the variances, , , , and forY andZ: (ii) defining new variables by and and lettingA=C+D andB=C–D, and obtaining MLE for variances, and forA andB; (iii) estimating the correlation coefficient _YZ by and the covariance _YZ by . The procedure is illustrated by using a precious metal geochemical data set from the Fox River Sill, Manitoba, Canada.     

The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

Interpolation by regularized spline with tension: I. Theory and implementation

Bivariate and trivariate functions for interpolation from scattered data are derived. They are constructed by explicit minimization of a general smoothness functional, and they include a tension parameter that controls the character of the interpolation function (e.g., for bivariate case the surface can be tuned from a membrane to a thin steel plate), Tension can be applied also in a chosen direction, for modeling of phenomena with a simple type of anisotropy. The functions have regular derivatives of all orders everywhere. This makes them suitable for analysis of surface geometry and for direct application in models where derivatives are necessary. For processing of large datasets (thousands of data points), which are now common in geosciences, a segmentation algorithm with a flexible size of overlapping neighborhood is presented. Simple examples demonstrating flexibility and accuracy of the functions are presented.On leave from the Department of Physical Geography and Cartography, Comenius University, Mlynská dolina, Bratislava, Czechoslovakia.On leave from the Institute of Physics, Dúbravská cesta 9, Bratislava, Czechoslovakia.