25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

Ordovician Graptolite Rhabdosome Complication and Its Implications on Sea Level Changes

A total of four times of rhabdosome complication events, i.e., the lateral branching of graptolite stipes during the Late Middle Ordovician, the secondary branching of graptolite stipes at the earliest Upper Ordovician, the early Qiantangjiangian of Upper Ordovician and the middle Qiantangjiangian, respectively, is discussed in this paper. These events and other adaptation events demonstrate close relationships between a diverse graptolite fauna and sea level changes, and consequently can be employed to study sea level fluctuations. It is safe to conclude that the complication of rhabdosome started at the maximum flooding surface (MFS) and terminated at the beginning of regression.     

Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.     

山地丘陵地区物探爆破孔钻机及配套机具的研究与开发

为满足我国山地丘陵地区物探爆破孔施工技术的要求，研究适合土层、岩层钻进用的钻机及工具，对钻机的配套设备进行了开发研究。分析了国内山地丘陵地区物探爆破孔施工技术现状，并着重介绍了研制设计内容及生产试验情况。     

桩土接触面单元参数分析

桩的抗拔特性与接触面的特性密切相关，正确选定接触面的力学参数对于分析桩的抗拔机理有重要意义。根据桩土接触面点面接触模型和库仑摩擦变形原理，在10组土－结构（钢、混凝土）剪切摩擦试验分析的基础上，对桩土接触面摩擦参数的取值问题进行了研究，得到了一些结论，对于桩土接触面力学参数正确取值有一定的参考价值。     

Une méthode de quantification de la dégradation d'un escarpement de faille au cours des cycles climatiques du Quaternaire : la faille de Jobourg (Nord Cotentin,France)Quantification of a fault-scarp degradation through Quaternary: the Jobourg fault (North Cotentin,France)

The degradation of the Jobourg fault-scarp occurred by cryoclastic processes in a periglacial environment during a part of Quaternary time. An attempt of quantification indicates a bulk scarp erosion of about 39 m³ m^?2, while the head accumulated at the bottom of the fault scarp only represents 4.6 m³ m^?2. To cite this article: M. Font et al., C. R. Geoscience 334 (2002) 171–178.     

山西水2井和岳42井水位记震能力分析

对比分析了唐山地区同一地质单元内、同一观测含水层、水位动态相同的山西水2井和岳42井记录的水震波曲线，显示两井记震能力相差很大，从井孔结构、地震面波特性等方面分析了两井记震能力差异性的成因机理，结果表明，井孔的固有周期是影响水位记震能力大小的首要条件。     

震源时间函数与震源破裂过程

简要介绍了现代数字地震学的两个重要概念。一个是震源时间函数，另一个是地震震源的时空破裂过程。首先，从地震断层位移表示定量出发，介绍震源时间函数和震源破裂过程的基本概念。然后，分别介绍两种从远场地震记录中提取震源时间函数和获取有限断层面上时空破裂过程图像的反演方法。     

以2000年4月29日河南内乡地震为例谈谈关于计算震级误差的有关问题

2000年4月29日河南内乡发生地震，地这次地震，河南地震局台网和中国地震局台网震级量度之间有一定差异。采用不同量规函数和尾波持续时间震级公式计算发现，它们之间所产生的最大差异可达0.5-0.7级。综合分析后认为，2000年4月29日河南内乡地震震级定为ML5.0级较为适宜。