Using hydrogeochemical signatures of stream water to assess pathways for rainfall events: towards a predictive model

Thanks to its simple division into agricultural and forestry land use, the Corbeira catchment (Galicia, Spain) is used as a case study to build a predictive model using hydrogeochemical signatures. Stream data acquired under recessional flow conditions over a one year period were obtained from a sampling station near the downstream end of the catchment, and using principal component analysis, it is shown that some of the analytical parameters are covariant, and some are negatively correlated. These findings support inferences about the pathways of rainfall in the catchment. Specific signatures may be associated with the dominant hydrological source, either surface runoff or subsurface waters: additionally, the dominant land use in that part of the catchment, where the flow originated, can also be predicted. The dominant runoff shows a strong covariance between suspended solids (SS) and particulate phosphorus (PP), with a clear negative correlation with pH. Dissolved organic carbon (DOC) data are associated with this covariant set when these compounds are available in the soils in question. Dissolved phosphorus, total organic nitrogen and dissolved nitrates are also associated with the same covariant set when the runoff flows through areas of extensive agricultural use. The SS ? PP covariance is less significant at lower flows. Typical base flow regimes show a significant covariance between salinity and pH, with a marked negative correlation with SS ? PP set, confirming the dominance of subsurface waters in the baseflow, as expected. Seasonally divergent DOC ? SS behaviour proves to be a useful tracer for rainfall regimes. The DOC trend shows a sinusoidal annual variation in amplitude, determined by the rainfall regime. As a result, flow from the catchment is dominated by surface water whenever there is synchronicity between the peaks of DOC and SS. Copyright © 2013 John Wiley & Sons, Ltd.     

Measurement of stream cross section using ground penetration radar with Hilbert–Huang transform

This study presents a new method to measure stream cross section without having contact with water. Compared with conventional measurement methods which apply instruments such as sounding weight, ground penetration radar (GPR), used in this study, is a non‐contact measurement method. This non‐contact measurement method can reduce the risk to hydrologists when they are conducting measurements, particularly in high flow period. However, the original signals obtained by using GPR are very complex, different from studies in the past where the measured data were mostly interpreted by experts with special skill or knowledge of GPR so that the results obtained were less objective. This study employs Hilbert–Huang transform (HHT) to process GPR signals which are difficult to interpret by hydrologists. HHT is a newly developed signal processing method that can not only process the nonlinear and non‐stationary complex signals, but also maintain the physical significance of the signal itself. Using GPR with HHT, this study establishes a non‐contact stream cross‐section measurement method with the ability to measure stream cross‐sectional areas precisely and quickly. Also, in comparison with the conventional method, no significant difference in results is found to exist between the two methods, but the new method can considerably reduce risk, measurement time, and manpower. It is proven that the non‐contact method combining GPR with HHT is applicable to quickly and accurately measure stream cross section. Copyright © 2013 John Wiley & Sons, Ltd.     

Trend and extreme occurrence of precipitation in a mid‐latitude Eurasian steppe watershed at various time scales

The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann–Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large precipitation anomalies. The objectives of this study were to (1) formulate a trend analysis approach that considers nonstationarity due to step changes, (2) use this approach to detect trends and extreme occurrences of precipitation in a mid‐latitude Eurasian steppe watershed in North China, and (3) examine how runoff responds to precipitation trends in the study watershed. Our results indicate that annual precipitation underwent a marginal step jump around 1995. The significant annual downward trend after 1994 was primarily due to a decrease in summer rainfall; other seasons exhibited no significant precipitation trends. At a monthly scale, July rainfall after 1994 exhibited a significant downward trend, whereas precipitation in other months had no trend. The percentage of wet days also underwent a step jump around 1994 following a significant decreasing trend, although the precipitation intensity exhibited neither a step change nor any significant trend. However, both low‐frequency and high‐frequency precipitation events in the study watershed occurred more often after than before 1994; probably as either a result or an indicator of climate change. In response to these precipitation changes, the study watershed had distinctly different precipitation‐runoff relationships for observed annual precipitations of less than 300 mm, between 300 and 400 mm, and greater than 400 mm. Copyright © 2013 John Wiley & Sons, Ltd.     

Effect of rainfall uncertainty on the performance of physically based rainfall–runoff models

This paper analyses the effect of rain data uncertainty on the performance of two hydrological models with different spatial structures: a semidistributed and a fully distributed model. The study is performed on a small catchment of 19.6 km² located in the north‐west of Spain, where the arrival of low pressure fronts from the Atlantic Ocean causes highly variable rainfall events. The rainfall fields in this catchment during a series of storm events are estimated using rainfall point measurements. The uncertainty of the estimated fields is quantified using a conditional simulation technique. Discharge and rain data, including the uncertainty of the estimated rainfall fields, are then used to calibrate and validate both hydrological models following the generalized likelihood uncertainty estimation (GLUE) methodology. In the storm events analysed, the two models show similar performance. In all cases, results show that the calibrated distribution of the input parameters narrows when the rain uncertainty is included in the analysis. Otherwise, when rain uncertainty is not considered, the calibration of the input parameters must account for all uncertainty in the rainfall–runoff transformation process. Also, in both models, the uncertainty of the predicted discharges increase in similar magnitude when the uncertainty of rainfall input increase.     

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.     

Suspended sediment and total dissolved solid yield patterns at the headwaters of Urumqi River,northwestern China: a comparison between glacial and non‐glacial catchments

In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.     

Soil cracking effects on hydrological and erosive processes: a study case in Mediterranean cultivated vertisols

Shrink–swell soils, such as those in a Mediterranean climate regime, can cause changes in terms of hydrological and erosive responses because of the changing soil water storage conditions. Only a limited number of long‐term studies have focused on the impacts on both hydrological and erosive responses and their interactions in an agricultural environment. In this context, this study aims to document the dynamics of cracks, runoff and soil erosion within a small Mediterranean cultivated catchment and to quantify the influence of crack processes on the water and sediment supplied to a reservoir located at the catchment outlet using water and sediment measurements at a cultivated field outlet as baseline. Detailed monitoring of the presence of topsoil cracks was conducted within the Kamech catchment (ORE OMERE, Tunisia), and runoff and suspended sediment loads were continuously measured over a long period of time (2005–2012) at the outlets of a field (1.32 ha) and a catchment (263 ha). Analysis of the data showed that topsoil cracks were open approximately half of the year and that the rainfall regime and water table level conditions locally control the seasonal cracking dynamics. Topsoil cracks appeared to seriously affect the generation of runoff and sediment concentrations and, consequently, sediment yields, with similar dynamics observed at the field and catchment outlets. A similar time lag in the seasonality between water and sediment delivery was observed at these two scales: although the runoff rates were globally low during the presence of topsoil cracks, most sediment transport occurred during this period associated with very high sediment concentrations. This study underlines the importance of a good prediction of runoff during the presence of cracks for reservoir siltation considerations. In this context, the prediction of cracking effects on runoff and soil erosion is a key factor for the development of effective soil and water management strategies and downstream reservoir preservation. Copyright © 2016 John Wiley & Sons, Ltd.     

Assessing the effectiveness of imperviousness on stormwater runoff in micro urban catchments by model simulation

Imperviousness, considered as a critical indicator of the hydrologic impacts of urbanization, has gained increasing attention both in the research field and in practice. However, the effectiveness of imperviousness on rainfall–runoff dynamics has not been fully determined in a fine spatiotemporal scale. In this study, 69 drainage subareas <1 ha of a typical residential catchment in Beijing were selected to evaluate the hydrologic impacts of imperviousness, under a typical storm event with a 3‐year return period. Two metrics, total impervious area (TIA) and effective impervious area (EIA), were identified to represent the impervious characteristics of the selected subareas. Three runoff variables, total runoff depth (TR), peak runoff depth (PR), and lag time (LT), were simulated by using a validated hydrologic model. Regression analyses were developed to explore the quantitative associations between imperviousness and runoff variables. Then, three scenarios were established to test the applicability of the results in considering the different infiltration conditions. Our results showed that runoff variables are significantly related to imperviousness. However, the hydrologic performances of TIA and EIA were scale dependent. Specifically, with finer spatial scale and the condition heavy rainfall, TIA rather than EIA was found to contribute more to TR and PR. EIA tended to have a greater impact on LT and showed a negative relationship. Moreover, the relative significance of TIA and EIA was maintained under the different infiltration conditions. These findings may provide potential implications for landscape and drainage design in urban areas, which help to mitigate the runoff risk. Copyright © 2015 John Wiley & Sons, Ltd.     

Long-term hydrological,biogeochemical, and climatological data from Walker Branch Watershed,East Tennessee,USA

In 1967, the original Walker Branch Watershed (WBW) project was established to study elemental cycling and mass balances in a relatively unimpacted watershed. Over the next 50+ years, findings from additional experimental studies and long-term observations on WBW advanced understanding of catchment hydrology, biogeochemistry, and ecology and established WBW as a seminal site for catchment science. The 97.5-ha WBW is located in East Tennessee, USA, on the U.S. Department of Energy's Oak Ridge Reservation. Vegetation on the watershed is characteristic of an eastern deciduous, second-growth forest. The watershed is divided into two subcatchments: the West Fork (38.4 ha) and the East Fork (59.1 ha). Headwater streams draining these subcatchments are fed by multiple springs, and thus flow is perennial. Stream water is high in base cations due to weathering of dolomite bedrock and nutrient concentrations are low. Long-term observations of climate, hydrology, and biogeochemistry include daily (1969–2014) and 15-min (1994–2014) stream discharge and annual runoff (1969–2014); hourly, daily, and annual rainfall (1969–2012); daily climate and soil temperature (1993–2010); and weekly stream water chemistry (1989–2013). These long-term datasets are publicly available on the WBW website (https://walkerbranch.ornl.gov/long-term-data/ ). While collection of these data has ceased, related long-term measurements continue through the National Ecological Observatory Network (NEON), where WBW is the core terrestrial and aquatic site in the Appalachian and Cumberland Plateau region (NEON's Domain 7) of the United States. These long-term datasets have been and will continue to be important in evaluating the influence of climatic and environmental drivers on catchment processes.     

Metals discharged during different flow conditions from a mixed agricultural‐forest catchment (NW Spain)

Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.