利用AutoPrep技术抑制型电导离子色谱法检测土壤中碘

利用AutoPrep自动样品前处理技术，对土壤燃烧吸收液进行在线预浓缩，抑制型电导进行检测，建立了一种全新思路的检测土壤样品中碘的方法。选择亲水性非常强的氢氧化物选择性IonPac AS16阴离子交换色谱柱，淋洗液发生装置在线产生KOH进行等梯度淋洗，抑制型电导检测。结果表明，对于土壤燃烧吸收液中碘离子的测定，方法检出限（S／N=3）可达1．2μg/L，线性相关系数为0．9998，方法精密度（RSD，n=7）为1．161％～4．566％，回收率在90．6％～100．8％。采用AutoPrep电导检测和脉冲安培检测离子色谱法测定不同土壤样品中的碘，两种方法的检测结果基本一致。方法在提供了稳定的系统空白的同时，还具备自动化程度高、操作简单、重现性好、灵敏度高、系统稳定、节约时间、成本低廉和对环境友好等多方面特点，适合于大批量土壤普查中碘的分析。     

土壤中铅铜锌镉的吸附特性

以徐州王庄矿（WZK）、奎河（KH）、背景-1（BG-1）和背景-2（BG-2）等4个土壤样品为供试对象，加入不同浓度梯度的铅、铜、锌、镉离子，通过静态实验研究了铅、铜、锌、镉的吸附特性。结果表明，土壤对4个重金属的吸附量与加入到土壤中的重金属离子浓度呈正相关性，它们之间大部分满足线性相关关系。在4个土壤样品中加入铅、铜、锌、镉离子的初始浓度比为10：10：10：1时，平衡浓度为Czn〉Ccu〉CPh〉Ccd，吸附量为Scd〉SPh〉Scu〉Szn，4个土壤样品对铅、铜、锌、镉离子的吸附能力依次为WZK〉KH〉BG-2〉BG-1。在所选实验条件下，土壤对铅、铜、锌、镉的吸附能力受土壤中铅、铜、锌、镉的含量、土壤有机质含量、阳离子交换量、土壤饱和含水量和土壤的pH值影响较大。     

Environmental impact assessment of risk associated with groundwater overdraft remediation in cone of depression,Jining, China

In this paper, a simple scenario and probabilistic approach is used to assess the potential groundwater risk due to proposed overdraft remedial actions in cone of depression, Jining City, China. Focusing on the concentrations of Chloride ions (Cl⁻) and total hardness (TH), the impact of artificial recharge and reduced pumping on groundwater quality and quantity is analysed by using the three-dimensional finite difference groundwater flow and transport model, Visual MODFLOW, to simulate groundwater flow and transport within the study area based on scenarios, and utilizes SURFER software to map risk levels. Although 5, 10 or 15% reduced pumping with artificial recharge leads to more decrease in Cl⁻ and TH concentrations than the 25%, less volume increase is achieved for the remediation of land subsidence and other environmental problems in the cone of depression. The Cl⁻ concentrations in recovered groundwater are within the desired concentration of 200 mg/l; however, TH in some cases are above the maximum permissible limit of 500 mg/l, with an exceedence probability of about 0.67 for recharge and recharge with reduced pumping at 25%. The presence of fractures and hydrogeological complexity greatly determines impacts of remediation, and the 22% reduced pumping with artificial recharge offers an optimum strategy for overdraft remediation in the Jining cone of depression.     

Changes of oceanographic characteristics and the state of pollution in the Izmit bay following the earthquake of 1999

The Izmit Bay is an elongated semi-enclosed bay in the Marmara Sea. It is being increasingly polluted by both domestic and industrial waste discharge since 1970’s. A monitoring program was conducted between 1999-2000 to document the state of pollution in the bay. This includes the effect of Marmara (Izmit) earthquake (magnitude 7.4) that occurred in August 1999. A stable two-layer ecosystem exists in the bay throughout the year due to continuous inflows of the saltier Mediterranean and brackish Black Sea waters to the Marmara basin. Therefore, the principal biochemical characteristics of the bay are governed by the two-layer flow system over the basin. Dissolved oxygen (DO) is generally at a saturated levels in the surface layer which is 10 to 15 m thick, but it is depleted to 60–70 μM in the lower layer, exhibiting a steep gradient in the sharp halocline. When the earthquake occurred, great loads of industrial wastes were released into the bay surface waters, which enhanced primary production in the upper layer and thus large export of particulate organic matter to lower layer and eventually to the bottom. Accordingly, DO was consumed and anoxic condition was established even in the upper layer/halocline interface, the halocline and bottom waters of the eastern and central bay. In this period, concurrent increases were observed in phosphate and ammonia contents at the halocline and in deep waters whilst the nitrate was almost consumed via denitrification processes in the anoxic water. Recently, the industrial C, N and P loads increased by as much as 8 fold within five years (1995–2000) whilst domestic inputs increased by 50%. Total organic matter discharged to the bay increased more than double within the last 15 years. Besides, most factories in the region release toxic wastes into the bay after only partial treatment.     

Buckling of Piles under Liquefied Soil Conditions

The paper pertains to the analysis of piles embedded in liquefiable soils to predict its’ critical buckling load under partial to full loss of lateral support over a portion of the pile length. The analysis is based on extension of Mindlin solution for a point load acting inside a semi infinite elastic half space. Degenerated solutions obtained by using the developed method compares very well with reported results. Parametric studies showed that the depth of liquefiable soil, degradation of soil strength on liquefaction, slenderness ratio, pile stiffness factor and end conditions have significant influence on the buckling behavior of the piles.     

土壤侵蚀治理范式与生态学理论的耦合关系

目前土壤侵蚀已经成为全球普遍关注的环境问题, 土壤侵蚀治理范式是近年水土保持研 究中的一个热点。本文探讨了“范式”在科学研究中的变迁过程以及对土壤侵蚀防治的重要意义, 并且讨论了土壤侵蚀防治范式与生态学范式之间的耦合关系, 指出生态学思想对土壤侵蚀科学 的发展有重要的借鉴作用, 强调在进行土壤侵蚀研究过程中必须考虑生态因子。土壤侵蚀过程和 生态过程是相互渗透在一起, 它们之间所表现的是相辅相成的耦合关系, 生态学中的自然均衡思 想、系统非平衡态理论、等级缀块动态理论都深刻的影响着土壤侵蚀科学的发展并且都得到不同 程度的应用。在土壤侵蚀研究过程中必须重视生态环境平衡思想。     

黄土高原大南沟流域非耕地中土壤养分变化

选取黄土高原区大南沟流域非耕地中灌木林地、摞荒地、荒草地、林地土壤养分数据,利用常规数据处理软件进行分析,得出如下结论:(1)水土流失造成摞荒地中土壤养分最低,需要把摞荒地改为灌木林地或林地;(2)磷含量从生长季开始随着时间推移一般呈现逐渐降低趋势,主要是水土流失造成的;(3)改变非耕地土地利用结构,增加地表植被覆盖率;占黄土高原一半以上的非耕地区是环境脆弱区之一,非耕地区土壤养分变化对环境产生重要影响,为土地利用结构的改变和当地的可持续发展提供理论支持.     

澜沧江典型对比流域水力侵蚀快速调查与评价

根据水力侵蚀面蚀和沟蚀两种不同侵蚀形态发生过程尺度空间大小不一的侵蚀特点,确定了研究区面蚀和沟蚀的不同调查评价方法.面蚀的发生过程空间尺度小,选用小区调查方法进行,而沟蚀的发生过程尺度空间大,在典型调查小流域尺度进行全面调查.然后在两种尺度下,分析形成沟蚀和面蚀的影响因素,进行沟蚀程度和面蚀强度分级,并把研究成果展延到澜沧江凤庆河流域和晓街河流域.最后,以在典型调查小流域的研究结果为对照判别依据,判断风庆河和晓街河流域的土壤侵蚀状况.结果显示,澜沧江典型流域的面蚀强度差异不大,沟蚀是造成不同流域土壤侵蚀和沟道输沙差异的主要水力侵蚀形式.     

基于3S技术和USLE的深圳市茜坑水库流域土壤侵蚀强度预测研究

基于RS、GPS和GIS(3S技术)的集成提出了USLE 6大因子的算法,在建立的专题地理信息数据库基础上,运用USLE对深圳市茜坑水库流域的土壤侵蚀强度进行预测和估算.结果表明:整个流域90.5%的区域土壤流失强度为中度以下,强度侵蚀以上的区域虽然仅占整个流域面积的9.5%,但是年土壤侵蚀量达到了整个流域土壤侵蚀量的49.4%.流域土壤侵蚀强度和植被覆盖情况明显相关,茜坑水库流域的东北山区部分是整个流域的严重侵蚀区.研究证明:在3S技术集成支持下,采用USLE对流域的土壤流失强度进行预测和估算的方法具有直观、方便、快捷的优点,成果能充分满足小流域水土保持工作的需要.     

Fault induced permanent ground deformations: Experimental verification of wet and dry soil, numerical findings’ relation to field observations of tunnel damage and implications for design

Few building codes contains provisions fault surface ruptures and accompanying soil deformations which constitutes a great risk to human lives, buildings and infrastructure. A numerical and experimental comparison show a fair agreement of result. Analysis of “real” scale show the how water increases the incompressibility of wet soil causing shear deformations to become larger and conjugate ruptures to appear for reverse faults. Field observations and numerical analysis indicates that horizontal compression of soil surrounding underground structures should be taken into account in design.