丁二酸桥联双核铜Cu(C_3N_2H_4)_2(C_4H_5O_4)_2晶体的超分子结构及形貌特征

用XRD,SEM和TEM研究新型配合物Cu(C3N2H4)2(C4H5O4)2的超分子结构和微观形貌,并对新型晶体的平衡外形进行模拟计算,结果表明:该配合物分子具有丁二酸桥联的双核铜结构,中心铜离子处在2个咪唑和4个丁二酸以单齿配位组成的八面体中心,在ab平面,分子中有十四元大环,环内Cu(1)-Cu(2)原子间距为0.8031nm,C(2)-C(2′)为0.4183nm;在ac平面,沿着[010]方向分子内呈现凹的六边形纳米级孔洞;沿[100]方向分子依靠弱的氢键作用,层状堆积成三维超分子结构。此外,随着丁二酸的碳链沿[001]方向无限延伸,形成以铜离子为交叉中心的带状拓扑构型。SEM观察到晶体表面形成有明显的凹坑,区域呈现层状阶梯,说明晶体在(100)面遵照台阶-扭折模型呈层状生长结晶。TEM微区形貌像显示晶体存在条纹和缺陷结构,整体保持柱状构型,这与模拟的晶体平衡外形呈柱状一致。模拟结果表明晶体最易外显晶面为(100)面,外显比例达41.247%,这与晶体超分子层沿[100]方向通过氢键作用堆积,键作用力较弱密切相关。     

向阳圩海塘围堰堤坝沉降特性原位实测及稳定性分析

以上海市向阳圩海塘围堰主堤为工程背景，在大量原位实测的基础上通过对各测试结果的统计分析研究了软土海滩围堰堤坝及地基沉降位移特性。结果表明：围堰堤坝及地基沉降具有显著的时效特性，沉降与时间的相关关系可用负指数时效特性曲线拟合；各测点位移值随时间具有明显突变变化，整个沉降时域可分为快速沉降时域区及缓慢沉降时域区。同时，在充分考察了沉降速率随时间变化特性的前提下提出了用该参量预测堤坝稳定时间及最终沉降位移的建议。     

含圆柱形弹性夹杂地基沉降量的解析解

研究各向同性地基中含一个圆柱形弹性夹杂的地基沉陷问题。考虑全场的应力、变形特征,运用复变函数的罗朗级数展开技术,构造合适的应力函数,结合夹杂的边界条件和无穷远的性态,获得了全场复势的解析表达。数值结果显示：由于两相材料剪切模量之比的不同,在某个范围内沉陷量大于基底中点沉陷;在这个范围之外,则小于基底中点沉陷。当夹杂埋深为夹杂半径的5倍以上时,就可以运用所得结果,而不致引起太大误差;含圆形隧洞和刚性夹杂的问题可作为特殊情况得到。     

The evolution of brittle and ductile structures at the surface of a partly debris-covered,rapidly thinning and slowly moving glacier in 1998–2012 (Pasterze Glacier,Austria)

Many glaciers in alpine regions are currently rapidly receding and thinning at historically unobserved rates causing changes in the velocity field and in normal and shear stresses affecting the surface expression of structures within the ice. We studied the distribution of brittle and ductile structures at the surface of Pasterze Glacier during a 14-year period by analysing orthophotos and digital elevation models of five stages (1998, 2003, 2006, 2009 and 2012). A structural glaciological mapping key was applied. Normal faults, strike-slip faults, en échelon structures (systematic stepping of fractures), thrust faults, and band ogives were distinguished. Results indicate substantial deceleration and glacier thinning in 1998–2012. Glacier thinning was not homogenous over time related to the uneven distribution of supraglacial debris causing differential ablation or the selective ablation effects of subglacial water channels. Peculiar supraglacial features observed are circular collapse structures with concentric crevasses which form when the ice between the surface and the roof of water channels decreases. The total length of brittle structures increased from 38.4 km to 56.9 km whereas the extent of the glacier tongue decreased by 25%. The fracture density doubled from 0.009 to 0.018 m/m². Areas of the glacier tongue which were up to 100 m away from the nearest brittle structure increased by 16%. The visual appearance of thrust faults shifted upglacier due to decreasing glacier velocity causing horizontal shortening or due to exhumation of faults that did not previously extend to the surface. A large number of brittle structures are progressively independent from glacier motion. Our study suggests that glacier tongues which are in a state of rapid decay and thinning are prone to fracturing due to normal fault formation and glacier disintegration. Water further increases ablation rates substantially if rather large amounts drain through supra-, en- or subglacial water channels. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

基于时间序列模型的沉降监测预报分析

时间序列模型预测具有可靠性与高效性的特点。本文结合沉降监测工程,采用Matlab进行建模预报分析,分别基于预测模型(AR、MA、ARMA)进行应用。对比自回归模型、滑动平均模型及自回归滑动平均模型预测结果的精度,表明3种模型可预测期连续分布,模型组合可提高预测精度。     

周口电信枢纽楼基坑降水设计方案技术经济分析

通过分析两种不同的基坑降水设计方案，阐述了降水技术要求，并介绍周边建筑物不均匀沉降的防治措施。     

三峡库区城镇居民地移民迁建分布规律的分析与应用

针对三峡库区移民安置规划中的实际需求,本文以三峡库区秭归县为例,分析了居民地空间分布类型、规律,并结合人口空间化模型,对研究结果的应用作了探讨,进而对居民地空间分布规律进行了验证。     

The hydrogen peroxide impact on larval settlement and metamorphosis of abalone <Emphasis Type="Italic">Haliotis diversicolor supertexta</Emphasis>

Abalone Haliotis diversicolor supertexta is an important economic mollusk. The settlement and metamorphosis are two critical stages during its development period, which has direct influence on abalone survival and production. The influence of reactive oxygen species （hydrogen peroxide） on abalone embryo and juvenile development were examined in this study. Larvae of Haliotis diversicolor supertexta were induced to settlement and metamorphose by exposure to seawater supplemented with hydrogen peroxide. They had the best performance at 800 μmol/L. The concentration of 1 000 μmol/L or higher was toxic to the larvae, as the larvae could settle down only at benthic diatom plates without complete metamorphosis. In addition, H2O2 adding time was critical to the larval performance. 24h after two-day post-fertilization was proved to be the optimal adding time. In this paper, two action mechanisms of hydrogen peroxide are discussed： （1） hydrogen peroxide has direct toxicity to ciliated cells, thus cause apoptosis; （2） hydrogen peroxide, as a product from catecholamines＇ autoxidation process in vivo, can reverse this process to produce neuro-transmitters to induce abalone metamorphosis.     

The effects of temperature and substrate on ontogenetic behavior of bastard halibut, Paralichthys olivaceus (T. et S.)

1 INTRODUCTION Scientific management of aquacultural andnatural populations studies on the early life historyof flatfishes in the aspects of their metamorphosisand benthic settlement accompanying pronouncedtransitions in morphology, behavior and habitatecology have received much attention (Youson,1988). Accumulated data showed that temperatureand substrate played a main role in the recruitmentsuccess of flatfish during their early development(Rijnsdorp et al., 1995, Gibson and Robb, 2000…     

核幔成矿物质与地幔热柱多级演化成矿

研究认为金等成矿物质主要来自核-幔源区,以气态-气液混合态、含矿流体的形式,通过地幔热柱→地幔亚热柱→幔枝构造→有利构造扩容带,迁移到幔枝构造外围的韧脆性剪切带、侵入岩体的内、外接触带、各种脉岩与围岩的接触带等有利部位集聚成矿,并构成矿田→矿床→矿体(脉)的有序排列组合,表现出不同的矿床类型。因此,应侧重研究构造成矿控矿作用,以指导新一轮地质找矿和矿产资源评价。文中还举例分析了胶西北焦家断裂与三山岛断裂的交切关系及其控矿作用。