潍北平原地区全新世以来的海侵与海岸线变迁

末次冰期后,在全新世大暖期及区域沉降的影响下,渤海湾沿岸普遍发育海侵现象,位于莱州湾南岸的潍北平原区在经历全新世最大海泛面后,海水退却过程中留下了数条古海岸线,形成了多处贝壳堤、牡蛎礁等海岸带遗迹.研究区内新发现常家村、后柳家2处牡蛎礁,其14C年龄分别为(5130±30)a B.P.和(6030±30)a B.P.;...     

Measurement of nuclides of uranium and thorium series of disequilibrium using γ-spectroscopy

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｒａｄｉｏｎｕｃｌｉｄｅｓｏｆｎａｔｕｒａｌｕｒａｎｉｕｍａｎｄｔｈｏｒｉｕｍｓｅｒｉｅｓｃａｎｂｅｕｓｅｄｔｏｔｒａｃｅｍａｒｉｎｅｐｒｏ ｃｅｓｓｏｆｖａｒｉｏｕｓｔｅｍｐｏｒａｌａｎｄｓｐａｔｉａｌｓｃａｌｅａｎｄｐｒｏｐｅｒｔｉｅｓｔｈａｔｐｒｏｖｉｄｅｐｌｅｎｔｉｆｕｌｉｎｆｏｒｍａｔｉｏｎａｂｏｕｔｐｈｙｓｉｃｓ,ｃｈｅｍｉｓｔｒｙ ,ｇｅｏｓｃｉｅｎｃｅａｎｄｂｉｏｌｏｇｙｏｆｏｃｅａｎｂｅｃａｕｓｅｔｈｅｙｈａｖｅｄｉｆｆｅｒｅｎｔｃｈｅｍｉｃａｌｐｒｏ…     

折多山花岗岩时代、成因及其动力学意义

沿鲜水河断裂分布的折多山花岗岩由早期的中细粒花岗闪长岩、二长花岗岩和略晚的主体似斑状二长花岗岩、少量的伟晶岩和细晶岩构成。早期中细粒二长花岗岩的SHRIMP锆石U-Pb同位素定年表明其侵位结晶于18±0．3Ma,使折多山花岗岩岩浆侵位结晶年龄和鲜水河断裂开始活动的时间提前近6Ma。岩石中保存有818±47Ma和156±8Ma的继承锆石．表明存在扬子西缘元古宙和中生代陆壳物质的再循环。在K_2O对SiO_2分类图上,早期的中细粒花岗闪长岩和二长花岗岩落在钙碱性系列区域,似斑状二长花岗岩落在橄榄玄粗岩系列区域,两个系列岩石总体上为铝饱和到过饱和。中细粒花岗闪长岩具有中等的稀土总量(162×10~(-6)～224×10~(-6))、高的(La/Yb)_N(74～118)和明显的正Eu异常,大离子亲石元素富集,Nb、Ta、P和Ti亏损,形成于岛弧钙碱性火山岩低度部分熔融。中细粒二长花岗岩与花岗闪长岩的地球化学特征相似,只是稀土总量和(La/Yb)n较低,形成于杂砂岩部分熔融。主体岩性粗粒似斑状二长花岗岩具有很宽的稀土总量(最高达533×10~(-6)),(La/Yb)_N随着稀土总量增加而增加(最高达523),明显负Eu异常,大粒子亲石元素强烈富集,Nb、Ta、Sr、P和Ti亏损,(~(87)Sr/~(86)Sr)_0=0．7084～0．7133,ε_(Nd)(t)=-5．67～-8．69,形成于元古代上部陆壳物质—砂页岩的较低程度的部分熔融。各类岩石的地球化学特征表明,部分熔融源区的物质组成继承了元古代大陆边缘的某些地球化学特性,经历了高压变质作用,部分熔融残留相主要为石榴石等。部分熔融过程发生于鲜水河断裂早期活动的剪切熔融过程,岩浆作用之前可能发生过强烈挤压而产生了高压变质作用。     

辽宁后仙峪硼矿区混合岩的LA-MC-ICP-MS锆石U-Pb年龄：对硼矿成矿演化的制约

辽东硼矿赋存于辽吉裂谷带的古元古代火山—沉积岩系之中,属沉积—变质型硼矿床,主矿区包括有后仙峪硼镁矿、翁泉沟硼铁矿和砖庙—杨木杆硼镁矿,一直以来是我国硼矿石的主产地。本次研究在后仙峪硼矿区采集了矿区外围的条痕状混合花岗岩(DSQ-08)和矿体上盘侵位于电英岩之中的含电气石混合花岗岩(HXY-19),挑选出其中的锆石单矿物进行LA-MC-ICP-MS测年。条痕状混合花岗岩中锆石的核部具有岩浆振荡环带,Th/U值为0.64~0.96,~(207)Pb/~(206)Pb年龄为2240±4Ma;含电气石混合花岗岩中锆石的内核和边部均具有极为清晰的岩浆振荡环带,Th/U值分别为0.12~1.05和0.41~1.08,~(207)Pb/~(206)Pb年龄分别记录了2157±6Ma和1932±26Ma两次锆石生长事件。含电气石的混合花岗岩的锆石边部形成于混合岩化过程之中,记录了辽河群下部岩石在1.9Ga左右发生的部分熔融作用事件,具有重要的地质意义。矿区外围的条痕状混合花岗岩和矿体周缘含电气石混合花岗岩的核部岩浆年龄较为接近,说明两种岩石可能均由古元古代的火山—沉积岩,在1.9Ga左右经部分熔融作用形成。因此,结合前人在后仙峪硼矿区内进行的硼同位素地球化学和岩相学方面的研究成果,我们认为后仙峪硼矿区混合花岗岩的锆石核部U-Pb年龄可基本确定辽吉裂谷早期的超基性火山岩和酸性火山岩的喷发、海相蒸发沉积事件均发生于2240~2157Ma左右,该时期的蒸发沉积作用初步形成硼酸盐矿;后期强烈的部分熔融和混合岩化作用发生在1932±26Ma,在超基性火山岩保护下,硼矿发生变质和小规模的迁移,形成了硼镁矿、硼镁铁矿及矿体周缘的电英岩和含电气石混合花岗岩。     

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

南极半岛屈韦维尔岛白垩纪中期火山岩浆作用及其构造指示:锆石U-Pb年代学和Hf同位素制约

南极半岛长期以来位于冈瓦纳古陆的西缘,是冈瓦纳古陆最后裂解的发生地。南极半岛内出露有大量的中新生代火成岩,关于其成岩期次、源区性质以及产出的动力学背景等尚存争议,从而影响到对南极半岛构造演化的认识。本文报道了南极半岛中部构造域屈韦维尔岛地区出露的安山质火山岩、闪长玢岩脉及其中闪长岩捕掳体的LA-MC-ICP-MS锆石UPb年代学和Hf同位素分析数据。其中含角砾安山质熔岩、安山质火山角砾岩、中粒闪长岩捕虏体和闪长玢岩脉4件样品的锆石U-Pb测年结果分别为103.3±1.7Ma、101.9±1.8Ma、92.0±1.2Ma和85.7±07Ma,表明该岛在白垩纪中期存在三幕火山岩浆作用事件:第一幕约为102Ma发生的强烈火山喷发;第二幕约为92Ma的闪长岩侵入作用;第三幕约为86Ma的闪长玢岩体侵入作用。锆石的Hf同位素原位分析结果表明,主要测点的εHf(t)值在+2.5~+7.9之间,平均值为+4.4,其一阶段Hf模式年龄为505~678Ma,表明白垩纪中期出露的火成岩可能由新元古代-寒武纪的亏损地幔物质部分熔融所形成。结合前人研究成果,得出本岛出露的火成岩形成于冈瓦纳古陆裂解过程所伴生的俯冲岛弧环境中,是构成南极半岛中部岩浆弧构造域的主体岩性之一。     

Late Jurassic to Early Cretaceous volcanism of Hong Kong: Insights from the Ping Chau Formation

The vast expanse of Mesozoic igneous rocks in Hong Kong contain important geological records of late Mesozoic magmatic events and tectonic processes from the coastal region of Southeast China. Of these,the Ping Chau Formation in the northwestern New Territories is the youngest known stratum. We perform a detailed study of the volcanic rocks of the Ping Chau Formation utilizing zircon U-Pb dating,with major and trace elements geochemistry. LA-ICP-MS zircon U-Pb data reveal Early Cretaceous age from two volcanic rock samples, with zircon crystallization from magmas at 140.3 ± 0.8 Ma and 139.3 ± 0.9 Ma,respectively. These rocks have high contents of total alkalis(Na_2O + K_2O = 5.58-9.45 wt.%), high-field-strength elements and light rare earth elements, conspicuous negative Eu anomalies, and depletions in Nb, Ta, Ti, Sr, Ba and P. Using this data, in combination with previous studies on the late Mesozoic volcanic belt in Southeast China, we propose that the volcanic rocks of the Ping Chau Formation probably originated from deep melting of the crust in a back-arc extensional setting induced by the subduction of the paleo-Pacific Plate. This formation represents the final stages of Early Cretaceous volcanic activity in Hong Kong, as associated with large-scale lithospheric extension, thinning and magmatism. Our results provide new information that can be used in evaluating the significance of Early Cretaceous volcanism and tectonics in Southeast China.     

浙西闲林岩体的锆石SHRIMP U-Pb定年及其地质意义

浙西闲林铁钼矿床地质特征表明,矿床为岩浆期后热液接触交代矽卡岩型,根据岩石蚀变、矿石结构构造和矿物组合,划分了4个成矿阶段。研究表明:闲林矽卡岩型铁钼矿与中生代侵入岩成岩期岩浆热液作用关系密切。运用SHRIMP锆石U-Pb定年方法对闲林花岗闪长岩体的成岩时代进行测定,为(151.8±2.2)Ma,认为与磁铁矿成矿密切相关;结合辉钼矿Re-Os同位素年龄(132.05±0.47)Ma,与早白垩世花岗岩成岩时代相耦合,进一步限定了闲林地区成岩→成矿活动的时间轨迹,铁钼矿床是晚侏罗世和早白垩世两期成矿形成的。     

分离的大陆板块边缘镁铁－超镁铁岩系Th／Hf—Ta／Hf判别

本文在论述了Ｔｈ／Ｈｆ－Ｔａ／Ｈｆ关系判别岩浆岩源区大地构造环境机理的基础上，根据世界上典型大地构造环境区岩浆岩系的Ｔｈ、Ｔａ、Ｈｆ特征，提出了分离的大陆板块边缘镁铁－超镁铁岩的Ｔｈ／Ｈｆ—Ｔａ／Ｈｆ判别标志：Ｔｈ／Ｔａ＝１．８～４．０，Ｔａ／Ｈｆ＞０．１。     

The chronology of a large ice-dammed lake and the Barents–Kara Ice Sheet advances, Northern Russia

Beach and shoreface sediments deposited in the more than 800-km long ice-dammed Lake Komi in northern European Russia have been investigated and dated. The lake flooded the lowland areas between the Barents–Kara Ice Sheet in the north and the continental drainage divide in the south. Shoreline facies have been dated by 18 optical stimulated luminescence (OSL) dates, most of which are closely grouped in the range 80–100 ka, with a mean of 88±3 ka. This implies that that the Barents–Kara Ice Sheet had its Late Pleistocene maximum extension during the Early Weichselian, probably in the cold interval (Rederstall) between the Brørup and Odderade interstadials of western Europe, correlated with marine isotope stage 5b. This is in strong contrast to the Scandinavian and North American ice sheets, which had their maxima in isotope stage 2, about 20 ka. Field and air photo interpretations suggest that Lake Komi was dammed by the ice advance, which formed the Harbei–Harmon–Sopkay Moraines. These has earlier been correlated with the Markhida moraine across the Pechora River Valley and its western extension. However, OSL dates on fluvial sediments below the Markhida moraine have yielded ages as young as 60 ka. This suggests that the Russian mainland was inundated by two major ice sheet advances from the Barents–Kara seas after the last interglacial: one during the Early Weichselian (about 90 ka) that dammed Lake Komi and one during the Middle Weichselian (about 60 ka). Normal fluvial drainage prevailed during the Late Weichselian, when the ice front was located offshore.