Surfactant Enhance DLLME/FO‐LADS: Assay of Malachite Green Level in Aquatic Environment of Trout Fish

Malachite green (MG), a traditional agent used in aquaculture although is not approved; its low cost and high efficacy make illicit use likely. We developed a small‐scale, simple, and sensitive dispersive liquid–liquid microextraction procedure for the assay of trace amounts of MG in aquatic environment of Trout fish. Fiber optic‐linear array detection spectrophotometry with charge‐coupled device detector benefiting from a microcell was used for this purpose. The method is based on enhancement effect of an anionic surfactant on the extraction of MG in to very fine multidroplets of microextraction solvent which made assisted by disperser solvent. Under the optimum conditions, the enrichment factor 77.5 was obtained from a 5‐mL water sample. The calibration graph was linear up to 5 × 10^?7 mol L^?1 with detection limit of 1 × 10^?8 mol L^?1. The relative standard deviation for seven replicate measurements of 4 × 10^?7 and 5 × 10^?8 mol L^?1 of MG were 3.3 and 4.5%, respectively.     

Multi‐Criteria Analysis for Optimization of Sodium Chromate Production from Chromic Waste

The proposal of application of multi‐criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi‐criteria analysis while multi‐criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in‐process recycling of chromic mud, off‐site recycling of chromic tannery waste and on‐site recycling of waste from the old chromic heaps.     

A Multi‐Element Ion‐Pair Extraction for Trace Metals Determination in Environmental Samples

A multi‐element ion‐pair extraction method was described for the preconcentration of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) ions in environmental samples prior to their determinations by flame atomic absorption spectrometry (FAAS). As an ion‐pair ligand 2‐(4‐methoxybenzoyl)‐N′‐benzylidene‐3‐(4‐methoxyphenyl)‐3‐oxo‐N‐phenyl‐propono hydrazide (MBMP) was used. Some analytical parameters such as pH of sample solution, amount of MBMP, shaking time, sample volume, and type of counter ion were investigated to establish optimum experimental conditions. No interferences due to major components and some metal ions of the samples were observed. The detection limits of the proposed method were found in the range of 0.33–0.9 µg L^?1 for the analyte ions. Recoveries were found to be higher than 95% and the relative standard deviation (RSD) was less than 4%. The accuracy of the procedure was estimated by analyzing the two certified reference materials, LGC6019 river water and RTC‐CRM044 soil. The developed method was applied to several matrices such as water, hair, and food samples.     

Atmospheric Concentrations and Phase Partitioning of Polycyclic Aromatic Hydrocarbons in Izmir,Turkey

Ambient air polycyclic aromatic hydrocarbon (PAH) samples were collected at a suburban (n = 63) and at an urban site (n = 14) in Izmir, Turkey. Average gas‐phase total PAH (∑₁₄PAH) concentrations were 23.5 ng m^?3 for suburban and 109.7 ng m^?3 for urban sites while average particle‐phase total PAH concentrations were 12.3 and 34.5 ng m^?3 for suburban and urban sites, respectively. Higher ambient PAH concentrations were measured in the gas‐phase and ∑₁₄PAH concentrations were dominated by lower molecular weight PAHs. Multiple linear regression analysis indicated that the meteorological parameters were effective on ambient PAH concentrations. Emission sources of particle‐phase PAHs were investigated using a diagnostic plot of fluorene (FLN)/(fluorine + pyrene; PY) versus indeno[1,2,3‐cd]PY/(indeno[1,2,3‐cd]PY + benzo[g,h,i]perylene) and several diagnostic ratios. These approaches have indicated that traffic emissions (petroleum combustion) were the dominant PAH sources at both sites for summer and winter seasons. Experimental gas–particle partition coefficients (K_P) were compared to the predictions of octanol–air (K_OA) and soot–air (K_SA) partition coefficient models. The correlations between experimental and modeled K_P values were significant (r² = 0.79 and 0.94 for suburban and urban sites, respectively, p < 0.01). Octanol‐based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. However, overall there was a relatively good agreement between the measured K_P and soot‐based model predictions.     

Assessment of Metal Pollution in Water and Surface Sediments of the Seyhan River,Turkey, Using Different Indexes

The aim of this study was to assess the level of heavy metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) contamination and enrichment in the surface sediments of the Seyhan River, which is the receiving water body of both treated and untreated municipal and industrial effluents as well as agricultural drainage waters generated within Adana, Turkey. Sediment and water samples were taken from six previously determined stations covering the downstream of the Seyhan dam during both wet and dry seasons and the samples were then analyzed for the heavy metals of concern. When both dry and wet seasons were considered, metal concentrations varied significantly within a broad range with Al, 7210–33 967 mg kg^?1 dw; Cr, 46–122 mg kg^?1 dw; Cu, 6–57 mg kg^?1 dw; Fe, 10 294–26 556 mg kg^?1 dw; Mn, 144–638 mg kg^?1 dw; Ni, 82–215 mg kg^?1 dw; Pb, 11–75 mg kg^?1 dw; Zn, 34–146 mg kg^?1 dw in the sediments while Cd was at non‐detectable levels for all stations. For both seasons combined, the enrichment factor (EF) and the geo‐accumulation index (I_geo) for the sediments in terms of the specified metals ranged from 0.56 to 10.36 and ?2.92 to 1.56, respectively, throughout the lower Seyhan River. The sediment quality guidelines (SQG) of US‐EPA suggested the sediments of the Seyhan River demonstrated “unpolluted to moderate pollution” of Cu, Pb, and Zn, “moderate to very strong pollution” of Cr and Ni. The water quality data, on the other hand, indicated very low levels of these metals suggesting that the metal content in the surface sediments were most probably originating from fine sediments transported along the river route instead of water/wastewater discharges with high metal content.     

Geometric characteristics and evolution of a tidal channel network in experimental setting

This paper reports on a laboratory study that aims to reproduce a tidal channel network, in order to enhance the understanding of the morphodynamic evolution of the channel characteristics as the network expands and finally reaches equilibrium. A high‐resolution laser system scanned the bed topography at different time steps creating multiple digital elevation models of the channel network. Two hundred and seventy individual channel segments are analyzed and cross‐correlated in terms of their width, depth and length. The laboratory results show positive linear correlations between depth and width as well as between length and width of channel segments of the network configuration at final equilibrium. In a downstream direction, channels appear to widen more than they deepen, indirectly a sign that discharge has a stronger control on channel width than on depth. In contrast to fluvial drainage networks that commonly display fractal and scale‐invariant behavior, the geometric properties of the experimental tidal creek network shows scale dependence. Channel attributes exhibit consistent patterns of exponentially decreasing abundance, with increasing creek length, depth and width. The nature of the observed exponential distributions within creek attributes (width, depth, length) allows for statistical predictability of relative creek attribute dimensions downstream and through time. Copyright © 2010 John Wiley & Sons, Ltd.     

Predicting the equilibrium bed slope in natural streams using a stochastic model for incipient sediment motion

In this paper, a method to predict the equilibrium bed slope in natural streams based on the incipient motion criterion is proposed. The method is based on the criterion suggested by Gessler to simulate the grain size distribution of the armour coat using the concept of critical shear stress of a sediment mixture. In particular, a different expression of the probability for a single particle size to be part of the armour coat is firstly proposed; then, a simple two‐steps criterion is suggested to estimate the safety factor required by the proposed approach. The method is applied in three different Italian regions (Calabria, Basilicata, and Tuscany) and required several field campaigns involving the survey of 251 stream reaches upstream of grade‐control structures. The area including five Calabrian streams is firstly used to test the suitability of the two‐steps approach. In this area, considering the detailed information about the particle size of bed material, the effect of using a simplified grain size distribution for each torrent is also checked. The method is then applied within the two additional areas (Basilicata and Tuscany) in order to check the geographic influence on the prediction of the stable longitudinal profile. A comparison between measured and estimated values of the equilibrium bed slope showed a good agreement for the Calabrian streams, where the number of the investigated stream reaches is greater, and satisfactory results for the torrents located in Basilicata and Tuscany where the field data set is more limited. The overall results encourage the extension of the proposed method to additional field data and suggest the use of this approach by hydraulic designers in order to stabilize the longitudinal profile of natural streams. Copyright © 2011 John Wiley & Sons, Ltd.     

Bioturbation on a south‐east Australian hillslope: estimating contributions to soil flux

The contribution of bioturbation to downslope soil transport is significant in many situations, particularly in the context of soil formation, erosion and creep. This study explored the direct flux of soil caused by Aphaenogaster ant mounding, vertebrate scraping and tree‐throw on a wildfire‐affected hillslope in south‐east Australia. This included the development of methods previously applied to Californian gopher bioturbation, and an evaluation of methods for estimating the volume of soil displaced by tree‐throw events. All three bioturbation types resulted in a net downslope flux, but any influence of hillslope angle on flux rates appeared to be overshadowed by environmental controls over the spatial extent of bioturbation. As a result, the highest flux rates occurred on the footslope and lower slope. The overall contribution of vertebrate scraping (57.0 ± 89.4 g m^?1 yr^?1) exceeded that of ant mounding (36.4 ± 66.0 g m^?1 yr^?1), although mean rates were subject to considerable uncertainty. Tree‐throw events, which individually cause major disturbance, were limited in their importance by their scarcity relative to faunalturbation. However, tree‐throw might be the dominant mechanism of biotic soil flux on the mid‐slope provided that it occurs at a frequency of at least 2–3 events ha^?1 yr^?1. Although direct biotic soil flux appears to be geomorphologically significant on this hillslope, such transport processes are probably subordinate to other impacts of bioturbation at this site such as the enhancement of infiltration following wildfire. Copyright © 2011 John Wiley & Sons, Ltd.     

Application of an S‐shaped curve model to the temporal development of tafoni of salt‐weathering origin

To describe temporal change in tafone development, an S‐shaped curve equation is proposed: Z = Z_c [1 ? (n + 1) exp (? β t ) + n exp (? (1 + 1/n) β t )] , where Z is observed tafone depth, Z_c is ultimate tafone depth, t is time, and n and β are constants. The applicability of this model is examined using tafone data selected from seven sites, which are categorized into three different salt‐weathering environments: a spray/splash‐dominant (occasionally wave‐affected) supra‐tidal zone, aerosol‐affected coastal regions, and inland desert areas. The results indicate that the equation can well describe tafone development in each of these environments. An investigation based on the values of n and β, determined through a best fit of the equation to the data, suggests that n characterizes site‐specific environmental conditions and β reflects the magnitude of factors controlling the recession mechanism of tafone surfaces. It is found that (1) the maximum rate of tafone growth dramatically decreases from supra‐tidal, through coastal, to desert environments, and (2) the growing mode of tafoni is different depending on the environmental settings. The erosional force to facilitate the development of tafoni at supra‐tidal sites is estimated to be about 400 times greater than that in the general coastal area. Copyright © 2011 John Wiley & Sons, Ltd.     

Variability in erosion rates related to the state of landscape transience in the semi‐arid Chilean Andes

We quantify erosion rates in the higher sectors of the Huasco Valley, in the Main Cordillera of the semi‐arid Andes of Chile, using elevation differences between three successive geomorphic markers (pediments and paleo‐valleys) and the present day valley. Available Ar‐Ar ages of Neogene pediments are used to estimate mean erosion rates for the three periods (16 to 13 My, 13 to 8 My, and following 8 My). The landscape of the Huasco Valley is in a transient state, as indicated by well‐preserved pediment surfaces in interfluves, valleys deeply incised by fluvial and glacial erosion and scarped head‐valleys that represent the current knickzones. Higher erosion rates (45–75 m/My) are calculated for the more recent period (< 8 My) during which deep incision developed compared to previous periods (6–31 m/My). Quantitative data indicate that glaciers had a much higher erosional capability than fluvial activity in the higher sectors of the Main Cordillera. Comparison with erosion rates calculated in other drainage basins of the Chilean Andes suggests that the variability of erosion rates depends on the landscape's transient erosive state. The landscape's geomorphologic response to the uplift of the Main Cordillera results in the retreat of a knickzone, for which retreat velocity depends on precipitation rate pattern and glacial erosion intensity. Copyright © 2011 John Wiley & Sons, Ltd.