Paleohydrology and paleoclimate records in a saline prairie lake core: mineral,isotope and organic indicators

This pilot study examines the potential of obtaining a sedimentary record of paleoenvironmental/climatic/hydrologic conditions for saline Redberry Lake in southern Saskatchewan, Canada. The tools are mineralogy, stable isotopes and pigments. The upper meter of an offshore sediment core contains 10 to 20% by weight aragonite (CaCO₃), which apparently precipitated in the water column. The ¹⁸O and ¹³C of the bulk aragonite (corrected for content of detrital calcite) vary by 4 to 5. Enrichment in ¹⁸O in aragonite is significantly correlated with pigment concentrations (chlorophyll a, phaeophytin). The ¹⁸O and pigment data provide evidence for relatively dry and/or warm conditions and high limnetic productivity for the period 2500 to 1500 yrs B.P. After 1500 B.P., the climate was apparently similar to the present, with two episodes of relatively enhanced productivity, dryness and/or warmth, at around 1000 to 900 and 500 to 200 B.P. During the past century, Redberry Lake has decreased approximately 8 m in depth and its salinity has doubled. No clear sedimentary signal was observed in response to these recent hydrologic trends. These changes have not been associated with a significant climate trend in the region, but may have been induced by land use changes in the catchment.This publication is the third of a series of papers presented at the Conference on Sedimentary and Paleolimnological Records of Saline Lakes. This Conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor for this series.     

Palaeoclimatic studies in South Shetland Islands,Antarctica, based on numerous stratigraphic variables in lake sediments

The hitherto longest found lake sediment sequence on Byers Peninsula, Livingston Island, South Shetland Islands, was analysed with respect to lithology, chronology, diatoms, Pediastrum, pollen and spores, mosses, mineralogy, and sediment chemistry. During the ca. 5000 year long development the sediments were influenced by frequent tephra fall-outs. This volcanic impact played a major role in the lake's history during two periods, 4700–4600 and 2800–2500 BP, but was of importance during the lake's entire history with considerable influence on many of the palaeoenvironmentally significant indicators. The large and complex data set was analysed and zonated with different types of multivariate analysis. This resulted in a subdivision of the sequence into 8 time periods and 21 variables. Redundancy analysis (RDA) of this data set, both without and with the tephra periods, and with 4–6 of the variables as explanatory environmental variables, reveal that climatic/environmental signals are detectable. The palaeoclimatic picture that emerged out of the tephra noise suggests that the first 100 years were characterized by mild, humid conditions. This was followed by a less mild and humid climate until ca. 4000 BP when a gradual warming seems to have started, coupled with increased humidity. These mild and humid conditions seem to have reached an optimum slightly after 3000 BP. At ca. 2500 BP a distinct climatic deterioration occurred with colder and drier conditions and long seasons with ice cover. This arid, cold phase probably reached its optimum conditions at ca. 1500 BP, when slightly warmer conditions might have prevailed for a while. Except for the modern sample with rather mild climate, the last 1400 years seem to have been fairly arid and cold, and the effects of the frequent volcanic activity during this period is only vaguely seen in the records.     

Ratios of stable carbon isotopes in some High Arctic plants and lake sediments

¹³C/¹²C ratios for a number of High Arctic vascular plants (51 determinations), mosses (11), and freshwater algae (11) show considerable variation, particularly among the freshwater algae (range from-6.9 to -36.3). In some cases the stable carbon ratios on modern and fossil materials provide guidance as to whether marine waters formerly occupied a given pond or lake basin. In other cases the ¹³C values for algae collected along the present-day shore of a pond or lake bear no relation to the values obtained on constituents preserved within the bottom sediments, suggesting that major changes have occurred in the last few thousand years.Geological Survey of Canada Contribution No. 17291. Contribution No. 41 from the Cape Herschel Project.     

Environmental impact of the former Pb–Zn mining and smelting in East Belgium

In the mining district of Plombières-La Calamine (East Belgium), extensive Pb–Zn mining activities resulted in an important contamination of overbank sediments along the Geul river. Moreover, a huge amount of heavy metals is stored in a dredged mine pond tailing, which is located along the river. In the dredged mine pond tailing sediments, Pb–Zn minerals control the solubility of Zn, Pb and Cd. Although Pb, Zn and Cd display a lower solubility in overbank sediments compared to the mine tailing pond sediments, elevated concentrations of Pb, Zn and Cd are still found in the porewater of the overbank sediments. The considerable ‘actual’ and ‘potential’ mobility of Zn, Pb and Cd indicates that the mine pond tailing sediments and the overbank sediments downstream from the mine pond tailing represent a considerable threat for the environment. Besides the chemical remobilisation of metals from the sediments, the erosion of overbank sediments and the reworking of riverbed sediments act as a secondary source of pollution.     

Geochemical mapping using a geomorphologic approach based on catchments

The Extended Sample Catchment Basin (ESCB) mapping technique, discussed in this paper, can be used to display the spatial distribution of geochemical variables measured in stream sediments taking into consideration the geomorphologic settings and the hydrographic patterns of surveyed areas. This approach is based on the association of an area of statistical representativeness with each sample, and on the assumption that the concentrations measured in the stream sediments can be considered as average reference values for this area.ESCBs can be easily identified considering the position of the sampling points within the hydrographic network and using the confluences between the streams of highest rank as break points for representing changes of the geochemical background. This approach, different from the traditional geostatistical and deterministic ones, does not consider the Euclidean distance among the sampling points as a measure of geochemical similarity but only refers to their functional relationship along the streams (following the water and the sediment flow) to measure their proximity.ESCBs can be seen as a specific development of previous techniques based on catchments and proves to be especially useful for supporting land planning in a preliminary survey phase while it is not specifically suitable for the identification of point sources of geochemical anomalies.Due to the fractal nature of the hydrographic network, all the procedures can be driven in a GIS environment by using digital terrain models apart from their spatial resolution.     

Cross-formational hydrocarbon fluid flows in the Tertiary deltaic system of the Beaufort–Mackenzie Basin

Molecular and isotopic compositions of crude oils in the Beaufort–Mackenzie Basin confirm three genetic end-member oil groups and suggest extensive cross-formational hydrocarbon fluid flows in the Tertiary deltaic system. Inter- and intra-fractional variations in the geochemistry of the Tertiary-reservoired oils indicate that the oil source/maturity signatures were substantially masked by biomarkers that were picked up along migration pathways. Thus, many of the previously recognized “immature non-marine oils” are in fact thermally mature, probably derived from unpenetrated deeper marine source rocks. Although the effective source rock volumes have not been evaluated and their exact stratigraphic levels remain unknown, the relative timing of oil generation versus trap formation, rather than poor source quality, may be the cause of under-filled traps in the offshore area.     

Biostratigraphy of Jurassic-Cretaceous boundary sediments in the Eastern Crimea

The Dvuyakornaya Formation section in the eastern Crimea is described and subdivided into biostratigraphic units based on ammonites, foraminifers, and ostracodes. The lower part of the formation contains first discovered ammonites of the upper Kimmeridgian (Lingulaticears cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Olóriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian (?(Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel)). Based on the assemblage of characteristic ammonite species, the upper part of the formation is attributed to the Berriasian Jacobi Zone. Five biostratigraphic units (zones and beds with fauna) distinguished based on foraminifers are the Epistomina ventriosa-Melathrokerion eospirialis Beds and Anchispirocyclina lusitanica-Melathrokerion spirialis Zone in the upper Kimmeridgian-Tithonian, the Protopeneroplis ultragranulatus-Siphoninella antiqua, Frondicularia cuspidiata-Saracenaria inflanta zones, and Textularia crimica Beds in the Berriasian. The Cyrherelloidea tortuosa-Palaeocytheridea grossi Beds of the Upper Jurassic and Raymoorea peculiaris-Eucytherura ardescae-Protocythere revili Beds of the Berriasian are defined based on ostracodes. A new biostratigraphic scale is proposed for the upper Kimmeridgian-Berriasian of the eastern Crimea. The Dvyyakornaya Formation sediments are considered as deepwater facies accumulated on the continental slope.     

Synchronism of Holocene East Asian monsoon variations and North Atlantic drift-ice tracers

Eighteen radiocarbon-dated eolian and paleosol profiles within a 1500-km-long belt along the arid to semi-arid transition zone of north-central China record variations in the extent and strength of the East Asian summer monsoon during the Holocene. Dated paleosols and peat layers represent intervals when the zone was dominated by a mild, moist summer monsoon climate that favored pedogenesis and peat accumulation. Brief intervals of enhanced eolian activity that resulted in the deposition of loess and eolian sand were times when strengthened winter monsoon conditions produced a colder, drier climate. The monsoon variations correlate closely with variations in North Atlantic drift-ice tracers that represent episodic advection of drift ice and cold polar surface water southward and eastward into warmer subpolar water. The correspondence of these records over the full span of Holocene time implies a close relationship between North Atlantic climate and the monsoon climate of central China.     

A pronounced dry event recorded around 4.2 ka in brine sediments from the northern Red Sea

Partly laminated sediments were sampled from the brine-filled, anoxic Shaban Deep basin in the northern Red Sea. At about 4200 cal yr BP more than two millennia of anoxic sedimentation is replaced by a sub-oxic facies strongly suggesting the episodic absence of the brine. At the same time stable oxygen isotopes from surface dwelling foraminifera show a sharp increase (within less than 100 yr) pointing to a strong positive salinity anomaly at the sea surface. This major evaporation event significantly enhanced the renewal of deep water and the subsequent ventilation of the small Shaban Deep basin. The timing and strength of the reconstructed environmental changes around 4200 cal yr BP suggest that this event is the regional expression of a major drought event, which is widely observed in the neighboring regions, and which strongly affected Middle East agricultural civilizations.