Characteristics and origins of lee-side stratification sequences in late pleistocene drumlins,northern Ireland

Spindle- and parabolic-shaped drumlins examined at fifty-five localities in northern Ireland possess stratification sequences on their lee-side flanks. These forms lack the distinctive steep stoss- and tapering lee-ends of classical drumlins and tend to occur in linear zones transverse to late Pleistocene ice-flow. In most cases (90 per cent) the stratified deposits infill embayments excavated in the lee-side of barkhanoid forms and, in the remainder (10 per cent), they are superimposed on the lee-side of whaleback forms. The stratification sequences developed as a result of sedimentation in interconnected subglacial water-filled cavities and are unlike remanie proglacial sediments moulded by ice into drumlin form. Stratigraphic evidence indicates that the lee-side sequences developed during drumlin streamlining, which supports the view that subglacial hydraulic processes played an important role in drumlin formation.     

Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

影响生油门限深度的地质因素

本文根据三水盆地下第三系心组有机地化资料的分析,确定其生油门限深度为400米。进一步讨论了影响我国东部第三系含油气盆地成油门限值的几种地质因素。提出这些年青的盆地只要具有高地温梯度、高沉降速度、埋深大、剥蚀少就能在较短时间中形成油气。     

Effects of temperature and sliding rate on frictional strength of granite

Layers of artificial granite gouge have been deformed on saw-cut granite surfaces inclined 30° to the sample axes. Samples were deformed at a constant confining pressure of 250 MPa and temperatures of 22 to 845°C. The velocity dependence of the steady-state coefficient of friction (^ss) was determined by comparing sliding strengths at different sliding rates. The results of these measurements are consistent with those reported bySolberg andByerlee (1984) at room temperature andStesky (1975) between 300 and 400°C. Stesky found that the slip-rate dependence of (^ss) increased above 400°C. In the present study, however, the velocity dependence of (^ss) was nearly independent of temperature.     

Fault dimensions,displacements and growth

Maximum total displacement (D) is plotted against fault or thrust width(W) for 65 faults, thrusts, and groups of faults from a variety of geological environments. Displacements range from 0.4 m to 40 km and widths from 150 m to 630 km, and there is a near linear relationship betweenD andW ². The required compatibility strains (e _s) in rocks adjacent to these faults increases linearly withW and with and ranges frome _s=2×10^–4 toe _s=3×10^–1. These are permanent ductile strains, which compare with values ofe _s=2×10^–5 for the elastic strains imposed during single slip earthquake events, which are characterised by a linear relationship between slip (u) andW.The data are consisten with a simple growth model for faults and thrusts, in which the slip in successive events increases by increments of constant size, and which predicts a relationship between displacement and width of the formD=cW ². Incorporation of constant ductile strain rate into the model shows that the repreat time for slip events remains constant throughout the life of a fault, while the displacement rate increases with time. An internally consistent model withe _s=2×10^–5, giving repeat times of 160 years and instantaneous displacement rates of 0.02 cm/yr, 0.2 cm/yr, and 2.0 cm/yr when total displacement is 1 m, 100 m, and 10 km, and slip increasing by 0.5 mm with each event, gives a good approximation of the data. The model is also applicable to stable sliding, the slip rate varying with ductile strain rate and withW ².     

The Chemical Composition of Global Subducting Sediments and Its Geological Significance

Subducted sediments play an important role in crust-mantle interaction and deep mantle processes, especially for subduction zone magmatism and mantle geochemistry. The current rate of Global Subducting Sediments (GLOSS) is 0.5~0.7 km³/a. The GLOSS are composed of terrigenous material(76 wt.%), calcium carbonate(7 wt.%), opal(10 wt.%) and mineral-bound H₂O⁺(7 wt.%). The chemical compositions of GLOSS are similar to those of upper continental crust which is mainly controlled by the terrigenous materials, and yet the materials formed by marine processes will dilute the terrigenous materials. The components of subducted sediments are different among trenches. In the accretionary margin, the components of subducted sediments are similar to those of the upper crust, while in the non-accretionary margin the components are terrigenous materials plus those produced by marine processes. During subduction, subducted sediments will released fluids, melt or supercritical fluid to affect island arc/back-arc basin magmatism by means of aqueous fluid or sediment melt. In addition, a part of subducted sediments, together with underlying altered oceanic crust/lithosphere, recycle into the mantle and contribute to the mantle heterogeneity. Geochemical tracers indicate that subducted sediments play variable contributions to the magmatic processes in different tectonic setting. Thus, subducted sediments play an important role in two relatively independent dynamics systems (plate tectonics and mantle plume), as well as related mantle evolution models. As a result, by accurately calculating the compositions of subduction sediments and using various geochemical indicators, we can further limit the input and output fluxes of various elements or isotopes, and then obtain more accurately residual subducted components, which can provide us some important clues for geodynamic process.     

灰色系统关联度的新模型及其在预测矿体埋深中的应用

首先提出了灰色系统关联度的一个新模型，分析了该模型的性质，其次讨论了应用该模型和关联滤波法预测矿体埋深的问题，然后进行了理论模型试算，证实了本方法的理论效果，最后，指出了新模型的主要优点。     

Rapid entrenchment of stream profiles in the salt caves of Mount Sedom,Israel

Rock salt is approximately 1000 times more soluble than limestone and thus displays high rates of geomorphic evolution. Cave stream channel profiles and downcutting rates were studied in the Mount Sedom salt diapir, Dead Sea rift valley, Israel. Although the area is very arid (mean annual rainfall ≈ 50 mm), the diapir contains extensive karst systems of Holocene age. In the standard cave profile a vertical shaft at the upstream end diverts water from a surface channel in anhydrite or clastic cap rocks into the subsurface route in the salt. Mass balance calculations in a sample cave passage yielded downcutting rates of 0–2 mm s^?1 during peak flood conditions, or about eight orders of magnitude higher than reported rates in any limestone cave streams. However, in the arid climate of Mount Sedom floods have a low recurrence interval with the consequence that long-term mean downcutting rates are lower: an average rate of 8·8 mm a^?1 was measured for the period 1986–1991 in the same sample passage. Quite independently, long-term mean rates of 6·2mm a^?1 are deduced from ¹⁴C ages of driftwood found in upper levels of 12 cave passages. These are at least three orders of magnitude higher than rates established for limestone caves. Salt cave passages develop in two main stages: (1) an early stage characterized by high downcutting rates into the rock salt bed, and steep passage gradients; (2) a mature stage characterized by lower downcutting rates, with establishment of a subhorizontal stream bed armoured with alluvial detritus. In this mature stage downcutting rates are controlled by the uplift rate of the Mount Sedom diapir and changes of the level of the Dead Sea. Passages may also aggrade. These fast-developing salt stream channels may serve as full-scale models for slower developing systems such as limestone canyons.     

黄河上游某坝址平硐开挖后岩体变异时间效应规律分析

工程岩体开挖后改变了原来的赋存条件与环境，沿硐壁岩体表面卸荷由于应力的重新调整，表现在波速上升的下降，即岩体性状发生变异。随着时间的增加，变异程度加大，而变异的速率却逐年下降，文章根据黄河上游某水电工程坝址平硐壁不同时间（几个同点位）弹性波速测量结果，拟合了波速年下降率Ｄ（％）与开挖一测定时间间隔Ｎ（ａ）的函数关系。并根据这种关系进行岩体波速的反算，求得了开挖时岩体的波速值，反映其本来的性状，对一     

FTIR studies of reactions between the nitrate radical and haloethenes

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.