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151.
152.
Mark E. Hodson 《Chemical Geology》2002,190(1-4):91-112
Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10−14 mol/m2/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10−14 mol/m2/s) and sheet silicates (100×10−14 mol/m2/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10−14 mol/m2/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions. 相似文献
153.
淤积泥砂对水平地运动作用时刚性坝面动压力的影响 总被引:1,自引:0,他引:1
文章基于固体介质,流体介质,液固两相饱和介质的时域显示有限元波动分析方法,研究了可压缩库水条件下淤积泥砂对水平地运动作用时刚性坝面上动压力的影响,研究中分析了作为两相介质处理的淤积泥砂的饱和度、厚度、渗透系数和孔隙率对坝面动压力的影响,还比较了作为流程两相介质,单相固体介质、单相重流体介质处理的不同淤积泥砂层模型间的计算结果差异。 相似文献
154.
Jean‐Jacques Macaire Saïda Bellemlih Christian Di‐Giovanni Patrick De Luca Lionel Visset Jacques Bernard 《地球表面变化过程与地形》2002,27(9):991-1009
In the Négron River catchment area (162 km2), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 106 t) and loess (21 × 106 t), and Holocene alluvium (12·6 × 106 t), peat (0·6 × 106 t) and colluvium (18·5 × 106 t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km?2 a?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km?2 a?1 from alluvium stores and 7·6 t km?2 a?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km?2 a?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km?2 a?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
155.
Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons 总被引:1,自引:0,他引:1
B. Heisinger D. Lal A. J. T. Jull P. Kubik S. Ivy-Ochs K. Knie E. Nolte 《Earth and Planetary Science Letters》2002,200(3-4):357-369
We have determined the production yields for radionuclides in Al2O3, SiO2, S, Ar, K2SO4, CaCO3, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides 10Be, 14C and 26Al produced in quartz targets, 26Al in Al2O3 and S targets, 36Cl in K2SO4 and CaCO3 targets, and 53Mn in Fe2O3 targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ− capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ− capture, by fast muons and by neutron capture. 相似文献
156.
157.
黄河中游降雨特性对泥沙粒径的影响 总被引:6,自引:3,他引:6
以黄河中游36个有泥沙粒径资料的水文测站流域为样本,在不同自然地理类型流域划分的基础上,建立了流域泥沙粒径特片与降雨特性的关系。结果表明,在不同类型流域,流域泥沙的粗细与降雨季节性变率和年际变率之间存在着相当好的线性正相关关系;而与年降雨量和降雨不均匀系数之间呈明显的非线性关系。流域地面物质、植被和地貌发育程序等下垫面环境因素对泥沙粒径特性与降雨特性之间关系起着十分重要的控制作用。不同类型流域曲线的斜率各不相同,在图中所处的位置也不相同。 相似文献
158.
该文依据美国陆地卫星 (Landsat)接收的MSS、TM资料 ,得到廉州湾海区表层悬沙分布的解译图 ,分析廉州湾及湾外海区水流流场特征、悬沙的分布及输移扩散特征 ,并就潮流、径流等水动力对湾内悬沙运动、滩槽冲淤的作用和影响进行了讨论 相似文献
159.
山东月湖的沉积物分布特征及搬运趋势 总被引:12,自引:0,他引:12
1998年 11~ 12月和 1999年 8~ 9月各一个月对月湖进行的野外工作 ,共取得表层沉积物样品 131个 ,应用激光粒度仪并结合传统的筛分法对这些样品进行粒度分析 ,进行矩法计算获得粒度参数。采用Gao命名方法 ,将沉积物划分出 5种主要类型。利用Gao -Collins粒径趋势分析模型 ,计算该区沉积物粒径趋势所显示的沉积物净搬运方向 ,结果表明 ,沉积物从四周向湖中心搬运 ,同时显示湾顶的西部和北部、涨潮三角洲以及湖心等地貌单元是沉积的优势区域。 相似文献
160.
Combining ordination techniques and geostatistics to determine the patterns of diatom distributions at Lake Lama, Central Siberia 总被引:4,自引:0,他引:4
The patterns of spatial variation of diatom assemblages from surface sediments in Lake Lama were quantified using a combined approach of ordination and geostatistics. The aims were (i) to estimate the amount of variation between diatom assemblages within the lake, (ii) to model the spatial variability of the diatom assemblages and their diversity, and (iii) to map the diatom distributions in the lake. A correspondence analysis (CA) separated the diatom assemblages into a planktonic and a periphytic group. Rheophilic taxa were found within the periphytic group. Variogram analysis showed that only the sample scores of the first CA axis and the Shannon diversity index were spatially structured. The range of spatial correlation was estimated to be 55 km for both variables. The diversity and, to a lesser extent, the sample scores had considerable small-scale variability of about 20 and 3%, respectively. Estimates of the first component of the CA and the Shannon index were derived using block-kriging. The maps of the estimates provided a basis for partitioning Lake Lama according to the spatial structures into an eastern and a western basin, a north–south connection between the basins, and a north–south directed tip at the far eastern end. It was shown that variation in diatom assemblages is mainly spatially structured at the catchment scale and that there is a considerable amount of variation at smaller scales. According to the modeled spatial distribution, the assemblages are most likely affected by the lake size, morphology, and the water and nutrient input introduced by rivers. This has to be taken into account when paleolimnological interpretations are drawn from records of complex lake systems like Lake Lama. 相似文献