有机质对海底沉积物中粘土矿物X射线衍射分析结果的影响

X射线衍射法广泛应用于分析粘土矿物的含量和结晶特征,由于粘土矿物易与有机质结合形成有机-粘土复合体,是否去除有机质对分析结果有很大影响,实验结果表明影响最大的是伊-蒙混层矿物(含蒙脱石)和伊利石的含量,为得到可靠实验数据,必须重视对样品的前处理工作,对不同批次样品应该保持一致的处理程序。     

基于水淘选分级的长江口及邻近海域表层沉积物中磷的形态分布和迁移转化

磷是一种重要的生源要素,在河口、边缘海的初级生产中发挥重要作用,了解沉积物中磷的形态分布和迁移转化有助于深入了解该区域生态系统动力学。于2013年3月在长江口及邻近海域采集了表层沉积物样品,利用水淘选方法对沉积物进行了分级,并采用化学连续提取法分析了未分级和分级沉积物样品中的6种磷形态含量:可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷、碎屑磷和难分解有机磷,讨论了该区域沉积物中磷的形态分布、选择性输运过程和迁移转化。沉积物中总磷含量在14.0~18.4 μmol/g,其中碎屑磷是其主要成分,占54.5%,其次是有机磷和难分解有机磷,分别占到15.1%和13.1%。不同粒级沉积物中磷形态含量不同,可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷和难分解有机磷随粒级增加含量逐渐降低,而碎屑磷主要集中在粗粒级（大于32 μm）沉积物中。基于各粒级磷形态的质量分布,发现小于32 μm粒级的沉积物中各磷形态含量从长江口向浙闽沿岸逐渐增加,向外海方向逐渐减小,而大于32 μm沉积物的变化趋势与此相反,体现了不同形态磷的选择性输运。随粒径增大,总有机碳对有机磷比值（TOC/Or-P）先降低后升高,在大粒级沉积物中,TOC/Or-P比值较高主要是因为陆源有机碳贡献较高,而在小粒级沉积物中,主要是由于有机磷的迁移和转化更为活跃,体现了细颗粒物中有机磷相对有机碳的优先分解。本研究表明,从分级的角度可以对河口、边缘海的磷循环有一个更全面的认识。     

Scour depth under pipelines placed on weakly cohesive soils

We here study the scouring processes that evolve around a submarine pipeline placed on a weakly cohesive seabed. We first analyze some laboratory tests carried out by Vijaya Kumar et al. [21], Xu et al. [25] and Zhou et al. [28] that focused on the scouring around a horizontal cylinder lying on a cohesive bed, subject to waves and currents. The specific purpose is that of finding a new formula for the prediction of the equilibrium scour depth under submarine pipelines. After a theoretical analysis of the main parameters, the sought formula has been found to be a function of: (i) the hydrodynamic forces acting on the cylinder (through the Keulegan–Carpenter parameter KC), (ii) the clay content of the soil C_c, and (iii) the burial depth e₀/D. In the presence of small amounts of clay (C_c< 5 %), the scour depth depends directly on KC (as confirmed by many literature works for pipelines lying on sandy soils, e.g. [18]) and inversely on C_c (as already seen for bridge abutments on cohesive soils, e.g. [1]), the best-fit law being characterized by a coefficient of determination R² = 0.62. If some burial depth is accounted for, this being a novelty of the present work, a more general formulation can be used, valid in the presence of weakly-cohesive soils and with burial depths of the pipe smaller than 0.5 (R² = 0.79). For large clay-content ranges (2% < C_c < 75 %), the scour depth depends directly on both KC and C_c, this giving R² = 0.79 (no burial depth) and 0.91 (some burial depth). However, this finding is at odds with the main literature, because, for large amounts of clay, it is fundamental to consider the liquidity index LI, which accounts for some important clay properties, like the plasticity. We argue that the absence of LI is balanced by the direct dependence of the scour depth on C_c. Notwithstanding the small number of available data, a formula for the prediction of the scour depth under pipelines lying on cohesive soils is fundamental for several engineering applications. The present contribution represents the first attempt to build such a formula, when the pipeline is subject to the wave-current forcing and the seabed is characterized by a relatively small clay content.     

Floc size variability under strong turbulence: Observations and artificial neural network modeling

The flocculation of cohesive sediment in the presence of waves is investigated using high-resolution field observations and a newly-developed flocculation model based on artificial neural networks. Vertical profiles of suspended sediment concentration and turbulent intensity are estimated using measurements of current profile and acoustic backscatter. The vertical distribution of floc size is estimated using an artificial neural network (ANN) that is trained and validated using floc size measurements at one vertical level. Data analysis suggests a linear correlation between suspended sediment concentration and turbulence intensity. Observations and numerical simulations show that floc size is inversely related to sediment concentration, turbulence intensity and water temperature. The numerical results indicate that floc growth is supported by low concentration and low turbulence. In the vertical direction, mean size of flocs decreases toward the bottom, suggesting floc breakage due to increasing turbulence intensity toward the bed. A significant decrease in turbulent shear could occur within the bottom few-cm, related to increased damping of turbulence by sediment induced density stratification. The results of the numerical simulations presented here are consistent with the concept of a cohesive sediment particle undergoing aggregation-fragmentation processes, and suggest that the ANN can be a precise tool to study flocculation processes.     

潮流界以下河段航道整治水位确定方法研究——以长江江阴以下河段为例

在总结分析现有整治水位确定方法的基础上,根据潮流界以下河段的水沙运动特性,本文提出一种基于输沙能力的航道整治水位确定方法。考虑上游来水、下游潮汐为独立事件,统计潮流界以下河段上游来水、下游潮汐不同等级组合出现的频率,采用数学模型计算相应组合下河段沿程的潮位、流速过程,以流速四次方代表水流的输沙能力,统计不同潮位等级对应的综合净输沙能力,确定最大综合净输沙能力对应的水位为(最优)航道整治水位。以长江下游白茆沙水道和福姜沙水道为例,计算了所在河段的航道整治水位,并探讨了起动流速对整治水位计算的影响和最高整治水位概念对工程的意义。     

潍坊市城区第四系地层研究

通过整理近年来地震地质工作中积累的大量钻孔资料,对比分析潍坊市城区第四纪各沉积层的组成特征、形成时代、成因类型等性质,将城区沉积层划分为23个主层及众多亚层。在此基础上,编制潍坊市城区第四系厚度等值线图、第四纪不同地层单位沉积厚度等值线图及相关的地层埋深剖面图、模型图等,从而较系统地摸清本区第四系各土层的空间分布规律及其结构变化特征,并对潍坊市城区第四系沉积的主要控制因素进行初步分析和探讨。     

Modelling of sediment movement in the surf and swash zones

Under the action of marine currents, non-cohesive sediments evolve by bed-load, by saltation or suspension depending on their granulometry. Several authors have considered that the movement of sediment...     

西北冰洋表-底层碳动力学耦合作用的同位素(13C,234Th)指示

The coupling of upper ocean-benthic carbon dynamics in the ice-free western Arctic Ocean(the Chukchi Sea and the Canada Basin) was evaluated during the late July–early September 2003 using natural stable(13C) and radioactive(238U-234Th) isotope tracers. POC export flux estimated from 234Th/238 U disequilibria and dissolved CO2 concentration([CO2(aq)]) pointed out that the strengthened biological pump in the Chukchi Shelf have significantly lowered [CO2(aq)] and altered the magnitude of isotopic(12C/13C) fractionation during carbon fixation in the surface ocean. Further, d13 C signatures of surface sediments(d13Csed) are positively correlated to those of weighted d13 CPOC in upper ocean(d13Csed =13.64+1.56×d13CPOC, r2=0.73, p0.01), suggesting that the POC isotopic signals from upper ocean have been recorded in the sediments, partly due to the rapid export of particles as evidenced by low residence times of the highly particle-reactive 234 Th from the upper water column. It is suggested that there probably exists an upper ocean-benthic coupling of carbon dynamics, which likely assures the sedimentary d13 C record an indicator of paleo-CO2 in the western Arctic Ocean.     

胶州湾及青岛近海表层沉积物重金属赋存形态研究

2008年11月和2010年11月分别在青岛近海6个站位和胶州湾9个站位采集了表层沉积物样品,应用连续提取法分离和测定其主要成分和重金属的赋存形态。结果表明,易还原态的重金属受铁锰氧化物体系显著影响,其中镍的迁移过程基本受控于该体系,有机结合态的铬和钡迁移变化受有机质一定影响,其他形态重金属主要受外源输入影响。Pb和Cr存在显著富集,相对其他金属污染较明显。Pb的生态风险最高。胶州湾东部,尤其是李村河口附近重金属污染程度和不稳定性都最为明显。     

高盐分海洋沉积物样品洗盐预处理方法的研究

选取不同沉积类型海洋沉积物通过3步洗盐法和连续洗盐法进行探索实验。结果表明,3步洗盐法不适用于海洋沉积物洗盐,原因在于第2步洗盐时上清液出现水溶胶,而胶体中元素在总沉积物中占一定比例。若弃去胶体,势必会对后续测定工作产生负误差。分析3步洗盐上清液中Na的质量分数,表明一步洗盐便可达到洗盐要求,且最佳浸泡洗盐时间为30h。