Linking pesticides and human health: A geographic information system (GIS) and Landsat remote sensing method to estimate agricultural pesticide exposure

Accurate pesticide exposure estimation is integral to epidemiologic studies elucidating the role of pesticides in human health. Humans can be exposed to pesticides via residential proximity to agricultural pesticide applications (drift). We present an improved geographic information system (GIS) and remote sensing method, the Landsat method, to estimate agricultural pesticide exposure through matching pesticide applications to crops classified from temporally concurrent Landsat satellite remote sensing images in California. The image classification method utilizes Normalized Difference Vegetation Index (NDVI) values in a combined maximum likelihood classification and per-field (using segments) approach. Pesticide exposure is estimated according to pesticide-treated crop fields intersecting 500 m buffers around geocoded locations (e.g., residences) in a GIS. Study results demonstrate that the Landsat method can improve GIS-based pesticide exposure estimation by matching more pesticide applications to crops (especially temporary crops) classified using temporally concurrent Landsat images compared to the standard method that relies on infrequently updated land use survey (LUS) crop data. The Landsat method can be used in epidemiologic studies to reconstruct past individual-level exposure to specific pesticides according to where individuals are located.     

灞河流域非点源污染最佳管理措施模拟研究

运用SWAT模型对水土保持、减少化肥农药施用量、减少表层土壤施肥量比例、退耕还林及综合措施对于不同非点源污染在灞河流域的消减效果进行了模拟。结果表明:(1)水保措施对N、P、DDT的削减效果最高可达44.4%,相对而言对于溶解磷的削减效果不是很明显。(2)减少施肥量措施对溶解P、总P、NO3-N的削减率相对较高,而对于其它指标的削减效果不是很明显;减少农药施用量措施对DDT的削减效果较好,削减率可达50.92%。(3)减少表层土壤施肥量占总施肥量的比例措施对溶解P、总P的削减效果较为明显,而对于其它指标的削减效果不是很明显。(4)退耕还林措施对于各项指标都有着明显的削减作用。(5)综合措施对于各项指标均有着很好的削减作用,总体看来综合措施可大大减少流域内的非点源污染负荷,对于改善流域水环境质量可起到巨大的作用。研究为灞河流域非点源污染最佳管理措施的实施提供了明确实际的决策支持。     

准噶尔盆地玛湖凹陷深层油气流体相态研究

准噶尔盆地玛湖凹陷深层(5000m)是我国深层油气勘探当前的一个热点风险领域。为给区域下步油气勘探提供参考,通过对区内烃源岩和油气进行系统的地质地球化学正演、反演对比综合研究,重点分析了油气流体相态。结果表明,研究区深层稳定发育石炭系—二叠系四套烃源岩,有机质丰度高,普遍达到中等—好质量,类型多种多样,既可生油亦可生气,加之所有烃源岩均已基本进入高—过成熟演化,因此深层油气流体相态总体应高熟轻质,可能包括高熟轻质油、干酪根裂解气、油裂解气等。原油地球化学研究表明,原油随埋藏深度增加、层位变老,油质有逐渐变轻的趋势,成熟度有逐渐增大的趋势,保存条件亦逐渐变好,因此预测深层原油油质更轻、成熟度更高、保存条件更好。天然气地球化学研究表明,中浅层天然气可能属于混合来源,包括干酪根裂解气和油裂解气,规模性的高过成熟天然气可能在深层。因此,研究区深层油气资源丰富,相态轻质,成藏有利,值得勘探。这些认识还可供具有相似油气地质背景地区在研究和勘探时类比参考。     

Origin and quantitative source assessment of deep oils in the Tazhong Uplift,Tarim Basin

A large amount of deep oil has been discovered in the Tazhong Uplift, Tarim Basin whereas the oil source is still controversial. An integrated geochemical approach was utilized to unravel the characteristics, origin and alteration of the deep oils. This study showed that the Lower Cambrian oil from well ZS1C (

_1x) was featured by small or trace amounts of biomarkers, unusually high concentration of dibenzothiophenes (DBTs), high δ³⁴S of DBTs and high δ¹³C value of n-alkanes. These suggest a close genetic relationship with the Cambrian source rocks and TSR alteration. On the contrary, the Middle Cambrian oils from well ZS1 (

_2a) were characterized by low δ¹³C of n-alkanes and relatively high δ³⁴S of individual sulfur compounds and a general “V” shape of steranes, indicating a good genetic affinity with the Middle–Upper Ordovician source rocks. The middle Cambrian salt rock separating the oils was suggested to be one of the factors responsible for the differentiation. It was suggested that most of the deep oils in the Tazhong Uplift were mixed source based on biomarkers and carbon isotope, which contain TSR altered oil in varied degree. The percentage of the oils contributed by the Cambrian–Lower Ordovician was in the range of 19–100% (average 57%) controlled by several geological and geochemical events. Significant variations in the δ³⁴S values for individual compounds in the oils were observed suggesting a combination of different extent of TSR and thermal maturation alterations. The unusually high DBTs concentrations in the Tazhong-4 oilfield suggested as a result of mixing with the ZS1C oil (

_1x) and Lower Ordovician oils based on δ³⁴S values of DBT. This study will enhance our understanding of both deep and shallow oil sources in the Tazhong Uplift and clarify the formation mechanisms of the unusually high DBTs oils in the region.     

苏门答腊岛(印尼)成矿带的岩浆作用和源区及其对比

本文介绍了苏门答腊岛上两个成矿带(即铜-金矿成矿带和锡矿成矿带)的矿产分布,岩浆岩的岩石类型和地球化学特征。根据本研究课题在巴东地区岩石化学资料,本文总结了铜-金矿成矿带含矿母岩的地球化学特征,探讨其岩浆岩成因和源区。同时,将其锡矿成矿带岩浆岩的岩石类型和地球化学-大地构造环境与其相邻地体进行对比。研究结果表明:西苏门答腊地体的铜-金矿成矿带的含矿母岩为SI-型埃达克质花岗岩,形成于活动大陆边缘(ACM)火山弧构造环境,其岩浆物质主要来源于俯冲洋壳板片局部熔融叠加上弱的地幔楔熔融-混染作用(MASH)。而东苏门答腊地体‘锡岛’和"暹缅马苏"地体的锡矿带含矿母岩为过铝质(S-型)花岗岩类,其形成构造环境为碰撞带的弧后盆地和陆内裂谷,物质源区来自地壳重熔和岩浆分异。地球化学资料表明,该两地体具有共同的深部岩浆源区。     

藏北羌塘盆地角木茶卡地区下二叠统展金组烃源岩特征及意义

在羌塘盆地中央隆起带附近角木茶卡南发现一套下二叠统展金组含凝灰质烃源岩。依据露头样品和测试数据,从有机质丰度、有机质类型及成熟度方面对这套烃源岩特征进行了研究。研究结果表明,展金组烃源岩有机碳含量在0.35%~0.98%之间,达到了烃源岩标准,且大部分接近中等烃源岩标准;通过干酪根镜鉴、干酪根元素分析、干酪根碳同位素等结果分析,其有机质类型主要为Ⅱ2-Ⅲ型;有机质镜质组反射率Ro为1.54%~1.59%,岩石热解峰温Tmax介于467~530℃之间,干酪根腐泥组颜色为棕黄色,显示有机质热演化处在高成熟阶段。研究结果显示该套烃源岩具有较好生烃潜力,在以后的勘探中要予以重视。     

四川广元长江沟大隆组的沉积特征及与烃源岩关系的研究

四川广元长江沟上二叠统大隆组是以灰岩为主夹泥岩的沉积类型,生物群组合面貌十分丰富,沉积特征以还原、低能、低速、缺氧为特点。根据生物群组合面貌和沉积特征,其形成环境应为较深"浅水",而并非"半深海"。本区大隆组由于生物多样性和始终处于特殊的斜坡和缺氧环境,具有优质烃源岩特征,有机碳平均含量达5%,是四川今后寻找油气的有效标志层。     

内蒙古额济纳旗西部ZK0-1井二叠系烃源岩特征及其意义

银额盆地以古生界为目的层的钻井极少,获得的钻井岩心更是十分有限。对银额盆地西部路北凸起带ZK0-1井揭示的地层岩性组合特征进行分析,在此基础上对下二叠统暗色泥岩层段岩心系统地采集烃源岩样品,并进行有机质丰度、干酪根类型、有机质成熟度等地球化学特征分析。结果表明,银额盆地路北凸起带二叠系烃源岩厚度大(单层厚度大于43m),有机质丰度高(平均有机碳含量为3.1%),为以Ⅱ型干酪根为主、低成熟—成熟演化阶段的良好烃源岩。通过与二叠系地表剖面烃源岩地球化学特征对比,探讨了风化作用对烃源岩评价指标的影响。     

青岛市秋冬季霾期PM1及其含碳组分理化特征及来源研究

对2017年11月1日—2018年1月31日与2018年11月1日—2019年1月31日连续两年青岛市大气PM₁进行监测,获取了PM₁中含碳组分的变化趋势,结合国控站点监测数据和气象条件,分析了秋冬季PM₁来源.结果表明：2017、2018年秋冬季观测期间PM₁日均质量浓度分别为40.58±25.98、42.55±25.05 μg/m³;霾日质量浓度分别为84.71±16.70、81.52±18.39 μg/m³.与2017年相比,2018年同期PM₁质量浓度增长4.85%,霾日下降3.76%.2017年霾日PM₁中OC、EC质量浓度分别为13.67±3.95、3.95±1.02 μg/m³,2018年分别为16.48±6.34、3.34±1.16 μg/m³.与2017年相比,2018年霾日OC质量浓度增长20.56%,EC下降15.44%.2017、2018年霾日SOC质量浓度分别是非霾日的1.28和2.15倍,表明霾污染发生时易发生有机碳二次转化.含碳组分主成分分析均解析出3个因子.因子1解释变量均最大,分别为58.98%、67.14%,其表征含碳组分主要源于生物质燃烧、燃煤、道路扬尘及汽油车尾气等排放源.由后向气流轨迹分析得出,2017、2018年秋冬季气团轨迹多起源于内蒙古,经河北、天津、山东等省市抵达青岛.     

PLAM指数跟踪方法对中国沙尘天气过程及其波动变化特征的研究

采用1980-2011年气象台站地面气象要素观测资料、高空探空资料,时间和空间加密气象观测站资料,以及中国气象档案馆原始天气图表等资料,基于沙尘气溶胶浓度（PM₁₀）潜势源地贡献函数PSCF（Potential source contribution function）的沙尘系统追踪方法,发展空气质量气象条件PLAM（……）指数对沙尘天气过程的路径跟踪,给出1980-2011年东北亚沙尘天气过程特征分布;采用Spline趋势分析,讨论沙尘天气系统强度的年变化特征。结果表明：基于气溶胶浓度PSCF函数和气象条件PLAM指数追踪得出,中国和东亚地区沙尘天气过程年际强度变化并非单调减弱,具有历史持续性与转折突变性并存的波状变化趋势,出现准10 a的高低频活动特征。