Methane hydrate formation comparisons in media with and without a water source supply

Water is a necessary element during gas hydrate formations. Therefore, by analyzing water depletion changes in media, the reaction characteristics of methane hydrate in media can be studied. In this study, two water sources supplying some liquid water which may be consumed by the methane hydrate formation reactions were designed and assembled. Using them, the full formation processes of methane hydrate was studied. Experimental results show the following： If heat released from nucleation reaction of methane hydrate is diffused rapidly, the nucleation ratios will be enhanced discernibly. While the hydrate is formed, a force is generated that sucks fresh water from the source into the vicinity of the hydrate, slowing down the cementation process and causing some hydrate grain dissociation. As a result of cementation differences, the hydrate reaction processes with different water sources present linear or quadratic equation characteristics. After a few repeated dissociation and formation processes of some hydrate grains caused by the fresh water, the gas amounts contained in hydrate will be significantly enhanced.     

利用生产动态及地震资料分析井间河流相砂体连通性

渤海PL油田是位于渤海湾盆地的大型河流相油田,在其注水开发过程中,亟需准确认识注水井与生产井之间的砂体连通性,以便优化和调整注采井网,提高采收率.针对油田砂体横向变化快,纵向上薄砂体发育的特点,利用丰富的压力、水淹等生产动态资料及相位转换后赋予地质意义的地震资料综合分析砂体的连通性,进一步完善和修正了早期以地质及测井资料确定的砂体连通性分析成果,并引入注采连通率概念,用来定量表示井组范围内注水井与生产井之间的砂体的连通性.该套方法在PL油田注水优化及井网调整研究中得到了充分的体现,对其它河流相注水开发油田井组范围内井间砂体连通性研究具有一定的借鉴作用.     

平湖油气田主断裂西部烃源评价及油源对比

平湖油气田主力含油气区位于平湖主断裂以东区域,油源主要来源于东部生烃凹陷的半封闭海湾暗色泥岩和煤层.公司于2011年11月在主断裂西部钻了一口探井XY井,目的是为探测主断裂西部含油气情况,扩大油气储量.结果钻遇油气层12m,测试获日产气14.66×104m3,日产油107.8 m3,取得了一定突破.为进一步评价西部含油气规模,钻后进行了油源对比研究,认为西部的油气主要是东部运移聚集的结果,西部源岩也有一定贡献.西部有形成一定规模油气藏的潜力.     

南黄海盆地南五凹阜宁组“广湖咸水”烃源岩及其油气勘探意义

通过对南五凹钻井所揭示的阜宁组进行岩性、地球化学、古生物及地震相等综合分析证实,南五凹阜宁组发育中深湖相泥质烃源岩,且该套烃源岩形成于"广湖咸水"沉积环境。"广湖"即湖盆分布广泛,中深湖相泥质烃源岩在凹陷深洼处和缓坡带均有发育,平面上面积大,纵向上厚度大,具备生成油气的物质基础。"咸水"即烃源岩形成时期湖盆受到了海侵影响,致使水体性质偏咸。南五凹与中国东部古新世—始新世期间曾遭受海侵影响的其他湖盆类似,其形成的咸化烃源岩具有"排烃早"的特征。南五凹阜宁组湖相烃源岩"广湖咸水"沉积特征对于油气勘探具有重要意义。     

南黄海盆地烃源潜力比较性评价

南黄海中—新生代盆地经历了中生代印支运动以来的多期构造运动改造,凹陷分隔性强,各凹陷烃源岩发育条件差异大。利用地质调查获得的最新资料,从烃源岩有机质丰度、类型、成熟度以及成熟烃源岩体积参数等方面,重点探讨了中—新生代陆相盆地生烃条件好和较好的7个凹陷的烃源潜力及中—古生界海相烃源岩的演化特征。结果表明,北部坳陷的北部凹陷、东北凹陷以及南部坳陷的南四凹陷属于一类生烃凹陷,北部坳陷的南(西)部凹陷、南部坳陷的南五凹陷属于二类生烃凹陷,而北部坳陷的中—东部凹陷以及南部坳陷的南七凹陷为三类生烃凹陷。印支构造面之下的中—古生界海相层系是盆地内另一套重要烃源岩,其有机质热演化程度分异明显,在中—新生代凹陷间低凸起区最低,坳陷周围的隆起区最高,新生代凹陷区"基底层"内热演化程度介于上述两者之间。     

Evaluation of suitability area by ground source heat pump system in Baotou plain

According to the elements of hydrogeological conditions,lithology,stratigraphic thermal physical parameters,construction technology and economic rational elements,the evaluation system of ground source heat pump( GSHP) were established in Baotou plain. The factor weights were determined by using analytic hierarchy process,and the comprehensive element method was selected to evaluate the region suitability of GSHP system. The results show that the suitable area is 559. 63 km2 for utilizing GSHP in the studied area,accounting for 62. 58% of the total area; while the unsuitable area is 334. 60 km2,accounting for37.42%. The evaluating results can provide not only a scientific basis for development and utilization rationally of shallow geothermal heat in Baotou,but also offer an important reference to the other areas.     

Combining CLUE-S and SWAT models to forecast land use change and non-point source pollution impact at a watershed scale in Liaoning Province,China

Non-point source （NPS） pollution has become a major source of water pollution. A combination of models would provide the necessary direction and approaches designed to control NPS pollution through land use planning. In this study, NPS pollution load was simulated in urban planning, historic trends and ecological protection land use scenarios based on the Conversion of Land Use and its Effect at Small regional extent （CLUE-S） and Soil and Water Assessment Tool （SWAT） models applied to Hunhe-Taizi River Watershed, Liaoning Province, China. Total nitrogen （TN） and total phosphorus （TP） were chosen as NPS pollution indices. The results of models validation showed that CLUE-S and SWAT models were suitable in the study area. NPS pollution mainly came from dry farmland, paddy, rural and urban areas. The spatial distribution of TN and TP exhibited the same trend in 57 sub-catchments. The TN and TP had the highest NPS pollution load in the western and central plains, which concentrated the urban area and farm land. The NPS pollution load would increase in the urban planning and historic trends scenarios, and would be even higher in the urban planning scenario. How- ever, the NPS pollution load decreased in the ecological protection scenario. The differences observed in the three scenarios indicated that land use had a degree of impact on NPS pollution, which showed that scientific and ecologically sound construction could effec- tively reduce the NPS pollution load in a watershed. This study provides a scientific method for conducting NPS pollution research at the watershed scale, a scientific basis for non-point source pollution control, and a reference for related policy making.     

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莱州湾沉积物有机质来源

应用C/N、δ13C、δ15N解析了莱州湾沉积物有机质来源,发现湾内有机质主要存在海洋、河口浮游植物以及陆地有机质3种来源。通过C/N、δ13C定量示踪,发现海洋浮游植物是湾内沉积物有机质的最主要来源,相对含量在41.6%—58.5%之间。河口浮游植物有机质、陆源有机质相对含量波动较大,分别在3.8%—43.8%、0—53.5%之间。海洋浮游植物有机质在整个海湾都表现出较高含量。近岸河口附近海域往往表现出高含量的河口浮游植物有机质特征,陆源有机质含量较高区域大都集中在黄河口周围海域,高河口浮游植物有机质以及高陆源有机质特征在黄河口周围海域均有出现。     

沉积物孔隙毛细管压力与甲烷水合物饱和度关系研究

To better understand the relationship between the pore capillary pressure and hydrate saturation in sediments, a new method was proposed. First, the phase equilibria of methane hydrate in fine-grained silica sands were measured. As to the equilibrium data, the pore capillary pressure and saturation of methane hydrate were calculated. The results showed that the phase equilibria of methane hydrates in fine-grained silica sands changed due to the depressed activity of pore water caused by the surface group and negatively charged characteristic of silica particles as well as the capillary pressure in small pores together. The capillary pressure increased with the increase of methane hydrate saturation due to the decrease of the available pore space. However, the capillary-saturation relationship could not yet be described quantitatively because of the stochastic habit of hydrate growth.