黑海西北部冷泉碳酸盐岩的沉积岩石学特征及氧化还原条件的稀土元素地球化学示踪

黑海西北部罗马尼亚大陆架(水深120m)和乌克兰陆坡(水深190m)发育冷泉碳酸盐岩结壳。XRD测试表明此结壳主要由高镁方解石和文石组成。结壳中与渗漏系统微生物活动有关的凝块和葡萄状文石等特殊的沉积组构非常发育。冷泉碳酸盐岩酸可溶部分(碳酸盐岩相矿物)的稀土元素含量很低(0.068×10-6~2.817×10-6),稀土元素页岩标准化配分模式显示罗马尼亚大陆架冷泉碳酸盐岩具有明显的Ce负异常,乌克兰陆坡冷泉碳酸盐岩具Ce的正异常,表明它们是分别在氧化和还原环境中沉积的。稀土元素和V、Cd和U等微量元素的含量在泥晶中最高,亮晶中最低,可能反映成岩过程对元素含量有控制作用。     

填土表面倾斜时的主动土压力计算

支护结构工程中,当坡顶填土表面倾斜时,无法采用常规的土压力理论进行计算。探讨了《建筑边坡工程技术规范》存在的问题,提出了推荐方法。通过算例验证了推荐方法,具有计算简单、计算结果合理的优点,可供工程设计中参考使用。     

内蒙古敖包吐萤石矿床地质和地球化学特征

笔者总结了敖包吐萤石矿床的地质特征,并通过萤石的稀土元素的地球化学和Nd同位素研究,探讨了该矿床的成矿作用和成矿物质来源。敖包吐萤石矿床产出于下二叠统大石寨组火山—沉积岩与燕山中期花岗岩的接触带,为单一萤石矿床。萤石矿石的稀土元素的含量(∑REE)变化范围为(8.04～30.04)×10-6,平均为19.42×10-6;轻重稀土LREE/HREE值0.24～0.65,平均0.52;LaN/YbN为0.07～0.62,平均0.26;δEu为0.42～0.90,平均0.60,具Eu负异常和明显重稀土富集的特征。岩矿石的Nd同位素研究表明,萤石矿石的εNd(t)都表现为很大的负值,以成矿主期年龄138Ma计算的εNd(138Ma)为-7.30～-30.55,具有古陆壳的演化特征,暗示其成矿的物质来源主要是壳源物质。在Moller的Tb/La-Tb/Ca成因判别图解中,敖包吐矿床的萤石的结晶作用表现为重新活化的趋势,反映流体具有混源的特征,既有热液成因,又有沉积成因。二叠世的海相火山活动通过海底喷气和喷流的作用形成了初始矿源层,而燕山中期花岗岩浆的侵位与结晶分异,又对初始矿源层的活化和富集提供了流体和热能的来源。成矿流体在经历了长期的演化后在大石寨组的构造薄弱破碎的的部位沉淀析出,形成敖包吐萤石矿床。     

广州航空邮件处理中心土洞及桩端软土层处理工艺研究

广州航空邮件处理中心位于岩溶发育地区,场区内存在大量土洞、溶洞等不良地质现象。该建筑物拟采用静压桩基础。为保证建筑物及场道安全,须对场区土洞进行处理。结合场地具体情况和施工工期要求,首先对大体积土洞进行泵注细石砼骨料充填处理,以消除地面大面积塌陷的危险,消灭压桩机械施工安全隐患,然后开始进行静压桩基础施工,同时在场地允许区域对中小体积土洞、桩端软土层等分别进行泵注砂浆骨料和袖阀注浆处理．以确保洞体密实和保证桩基承载力。通过对处理工艺、处理范围的比较筛选和对质量控制要点、施工技术要点的分析提炼．达到了施工简便、造价合理、安全高效的目的,并采用骨料取芯检测、土体标贯试验和压缩试验、洞体物探等多种检测手段,完全达到了设计要求,取得了良好的工程效果和经济效益。     

“Tripoli”的含义及译名的讨论

“Tripoli”是一种新型的石英质工业矿物原料,在我国长期被误译为硅藻土,影响地质部门对这一新矿种的认识和寻找。本文追溯了“Tripoli”一名的由来,正确地阐述了“Tripoli”的本质特征,分析了在国内文献中长期被误译的根源,指明了其正确含义,并建议废除各种不正确的中译名,译为“粉石英”。     

Effects of low molecular weight organic acids on sorption and desorption behavior of p-chlorophenol by yellow earth

Low molecular weight organic acids （LMWOAs） are important components of root exudates. They play an important role in immobilizing and remobilizing contaminants in rhizospheric soil. Effects of four LMWOAs on the sorption and desorption behavior of p-chlorophenol by yellow earth was studied in batch mode. The results showed that the previous application of LMWOAs to enhanced adsorption capacity of p-chlorophenol of the soil in the order of maleic acid〉malic acid〉oxalic acid〉citric acid. However, when LMWOAs were applied to soil where p-chlorophenol had been previously adsorbed, substantial p-chlorophenol was desorbed from soil by oxalic acid, whereas citric acid, malic acid and maleic acid didn＇t desorb as much p-chlorophenol from soil as deionized water.     

近几十年我国极端气温变化特征分区方法探讨

采用聚类统计检验分析和旋转主分量分析相结合确定中心站的方法,利用我国多年极端气温资料,对我国最高和最低气温年际变化型态进行区划。结果表明,这两种方法结合可以互相补充,使分区结果更具客观性。中国极端高温和极端低温年际变化分别可划为12和11个不同类型的区域,分别计算了各区域第一主成分的方差贡献率以及各区域之间的两两相关系数,检验证明分区是合理的。     

Monazite behaviour and age significance in poly-metamorphic high-grade terrains: A case study from the western Musgrave Block, central Australia

Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.     

New Approach for Estimation of Static and Seismic Active Earth Pressure

To estimate static and seismic active earth pressure (P_ad) on a rigid retaining wall, numerical analyses using different step sizes have been carried out in this paper, based on the modified Culmann line method by considering Coulomb’s planar rupture surface. Equivalent pseudo-static seismic forces are considered in the analysis. A new concept of modified unit weight by considering ground surcharge is introduced under static and seismic conditions. By numerical analysis, area of soil (A) has been estimated to obtain the ratio of A/A₀ where A₀ is θh², θ is the angle between retaining structure and ground surface and h is the vertical height of the wall. This ratio remains constant for a particular type of soil and has been used to estimate the maximum active earth pressure using force diagram. Results are provided in tabular form for easy calculation of the coefficient of static and seismic active earth pressure. Present results by considering the new technique, compares well with the results obtained by earlier researchers.