引入国家基准站的北斗导航卫星精密定轨

卫星精密轨道的确定是北斗卫星导航系统位置与服务的核心技术之一,而国家基准站是影响卫星轨道精度的一个重要因素。本文基于中国测绘科学研究院国际GNSS监测与评估中心自主开发的软件计算国家基准站和MGEX站对北斗卫星精密定轨的影响。得出结果：加上国家基准站后GEO卫星轨道精度平均能达到2.0 m,比没有国家基准站时提高约14%,在GEO切向方向改善最为明显,大约提高30%。IGSO和MEO卫星也有所提高。加上国家基准站后,三类卫星的轨道重复弧段的径向精度优于5 cm。有了国家基准站数据BDS精密轨道会有明显的改善。国家基准站的建立使我国北斗导航卫星的服务能力有很大提高。     

Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS

Trace amounts (from nanogram to microgram levels) of bromine and iodine were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in twenty-three geochemical reference materials issued by the GSJ, USGS, IAEA etc. The pyrohydrolysis technique was used to separate bromine and iodine from samples analysed in the form of powder. The accuracy and precision of the experimental values were assessed by the comparative analysis of well established reference materials such as USGS AGV-1, BCR-1 and IGGE GBW07312. The measured values agreed well with reported values within a 10% error range. We also report reliable new data for these elements in these geochemical reference materials.     

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).     

A simple method using climatic variables to estimate canopy temperature,sensible and latent heat fluxes in a winter wheat field on the North China Plain

Estimation of evapotranspiration from a crop field is of great importance for detecting crop water status and proper irrigation scheduling. The Penman–Monteith equation is widely viewed as the best method to estimate evapotranspiration but it requires canopy resistance, which is very difficult to determine in practice. This paper presents a simple method simplified from the Penman–Monteith equation for estimating canopy temperature (T_c). The proposed method is a biophysically‐sound extended version of that proposed by Todorovic. The estimated canopy temperature is used to calculate sensible heat flux, and then latent heat flux is calculated as the residual of the surface energy balance. An eddy covariance (EC) system and an infrared thermometer (IRT) were installed in an irrigated winter wheat field on the North China Plain in 2004 and 2005, to measure T_c, and sensible and latent heat fluxes were used to test the modified Todorovic model (MTD). The results indicate that the original Todorovic model (TD) severely underestimates T_c and sensible heat flux, and hence severely overestimates the latent heat flux. However, the MTD model has good capability for estimating T_c, and gives acceptable results for latent heat flux at both half‐hourly and daily scales. The MTD model results also agreed well with the evapotranspiration calculated from the measured T_c. Copyright © 2008 John Wiley & Sons, Ltd.     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.     

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Accurate analytical nutation series

In this letter we present the first accurate analytical nutation series, deduced from the Hamiltonian theory by the authors. They provide the highest accuracy ever obtained by any analytical nutation series, since the deviation in CEP (celestial ephemeris pole) offsets with respect to that of the IERS Conventions 1996 is kept below 1 mas in the time domain, in spite of still lacking ocanic corrections.     

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.     

长距离GPS/BDS参考站网多频载波相位整周模糊度解算方法

长距离网络RTK是实现GPS/BDS高精度实时定位的主要手段之一,其核心是长距离参考站网GPS/BDS整周模糊度的快速准确确定。本文提出了一种长距离GPS/BDS参考站网载波相位整周模糊度解算方法,首先利用GPS双频观测数据计算和确定宽巷整周模糊度,同时利用BDS的B2、B3频率观测值确定超宽巷整周模糊度。然后建立GPS载波相位整周模糊度和大气延迟误差的参数估计模型,附加双差宽巷整周模糊度的约束,解算双差载波相位整周模糊度,并建立参考站网大气延迟误差的空间相关模型。根据B2、B3频率的超宽巷整周模糊度建立包含大气误差参数的载波相位整周模糊度解算模型,利用大气延迟误差空间相关模型约束BDS双差载波相位整周模糊度的解算。克服了传统的使用无电离层组合值解算整周模糊度的不利影响。采用实测长距离CORS网GPS、BDS多频观测数据进行算法验证,试验结果证明该方法可实现长距离参考站网GPS/BDS载波相位整周模糊度的准确固定。     

中国海及大陆架沉积物标准物质系列评介

自20世纪90年代末以来,在有关国家专项的支持下,中国先后研制了分别取自黄海、东海和南海的共9个大陆架沉积物地球化学标准物质,基本构成了一个比较有代表性的中国海及大陆架沉积物标准物质系列,为中国海洋国土及专属经济区调查研究工作提供了有力技术支撑.本文简介了这些标准的研制背景、概况,着重评介了这些标准物质的特点,特别说明了该标准物质系列在海洋地质调查与研究中应用及在地质分析技术发展上的意义.