Phosphorus retention in constructed wetlands enhanced by zeolite- and clinopyroxene-dominated lava sand

Constructed wetlands (CWs) are engineered systems for treating wastewater by sequestering nutrients and contaminants. Our aim was to assess the main phosphorus (P) binding states in operating CWs to assess P saturation and indications on P recycling potential of filter materials, which might be necessary under future peak P scenarios. The investigated vertical flow CWs (operation time up to 16 years) are based on either fluviatile (Fluv) sand or zeolite- (Ze-LS) and clinopyroxene (Cl-LS)-dominated lava sand. Organic and inorganic P accumulated in all CWs independent of filter materials and showed a considerable increase with operation time. Concentrations of P decreased sharply with depth in the Fluv-CWs compared to only a slight decrease in the lava sand CWs, with P concentrations of deeper horizons approximating the relatively P enriched original lava sand substrates. Orthophosphate was the dominant pool in all CWs, while the sum of organic fractions ranged between 11% and 33%. Sequential extraction indicated that P was mainly associated with Fe and Al (hydr)oxides for Fluv-CWs and Ze-LS-CWs, while Ca and Mg bound mineral phosphates dominated in Cl-LS-CWs. Oxalate extractions pointed to a clear dominance of P fractions associated with poorly crystalline Fe- and Al-(oxy)hydroxides. Solution ³¹P NMR analyses revealed that inositol hexakisphosphates were a major pool of organic P in surface layers of CWs, which increased with operation time. With a maximum of 0.5% P content, filter sands do not appear to be a suitable fertilizer for direct application to agricultural fields. The dominance of inorganic, poorly crystalline P species point to potentially high desorption capacity which might be investigated further, to assess recycling potential of P or usage of filter materials as soil amendments with relatively high plant available P. The latter might become feasible and economically attractive under future P scarcity. Simultaneously, P saturation indexes (DPS) did not indicate an imminent P saturation of filters, since P accumulation was not restricted by binding to Al and Fe minerals.     

Moisture transport and seasonal variations in the stable isotopic composition of rainfall in Central American and Andean Páramo during El Niño conditions (2015–2016)

High‐elevation tropical grassland systems, called Páramo, provide essential ecosystem services such as water storage and supply for surrounding and lowland areas. Páramo systems are threatened by climate and land use changes. Rainfall generation processes and moisture transport pathways influencing precipitation in the Páramo are poorly understood but needed to estimate the impact of these changes, particularly during El Niño conditions, which largely affect hydrometeorological conditions in tropical regions. To fill this knowledge gap, we present a stable isotope analysis of rainfall samples collected on a daily to weekly basis between January 2015 and May 2016 during the strongest El Niño event recorded in history (2014–2016) in two Páramo regions of Central America (Chirripó, Costa Rica) and the northern Andes (Cajas, south Ecuador). Isotopic compositions were used to identify how rainfall generation processes (convective and orographic) change seasonally at each study site. Hybrid Single Particle Lagrangian Integrated Trajectory model (HYSPLIT) air mass back trajectory analysis was used to identify preferential moisture transport pathways to each Páramo site. Our results show the strong influence of north‐east trade winds to transport moisture from the Caribbean Sea to Chirripó and the South American low‐level jet to transport moisture from the Amazon forest to Cajas. These moisture contributions were also related to the formation of convective rainfall associated with the passage of the Intertropical Convergence Zone over Costa Rica and Ecuador during the wetter seasons and to orographic precipitation during the transition and drier seasons. Our findings provide essential baseline information for further research applications of water stable isotopes as tracers of rainfall generation processes and transport in the Páramo and other montane ecosystems in the tropics.     

废雷尼镍催化剂的组成分析

运用红外光谱、X射线粉末衍射、等离子体发射光谱、X射线光电子能谱、扫描电镜、元素分析等多种仪器分析手段,对一种废雷尼镍催化剂的组成进行全面分析,该废催化剂中镍元素的含量较高,具有较高的回收利用价值;通过实验得到其中组分镍、铝、钙、铁、钼、铜、硅的定量信息和部分定性信息,建立了废雷尼镍催化剂中镍回收利用的技术方案。     

Impact of tectonic erosion by subduction processes on intensity of arc volcanism

Abstract According to new estimates, more than 2 km³ of terrestrial material is transported every year with the subducting lithospheric plates to depths greater than 20-30 km. A comparable amount of subducted material is partly restored to the nearby margins through underplating, diapirism or forearc volcanism; partly rejuvenated through arc and back-arc magmatism; and the rest is recycled into the deep mantle. This study emphasizes the connection between the consumption of some arcs and the intensity of arc volcanism. In many cases (Japan, Peru, Izu-Bonin, Guatemala), interruption in tectonic erosion of the margin is followed by a hiatus of arc volcanism. The delay between the presumed cause (i.e. absence of subducted arc-type crust) and the response (i.e. lack of explosive volcanism) corresponds to the time required for the subducting slab to reach the melting depth (i.e. 2-4 million years). Alternately, intense tectonic erosion of the margin is followed by paroxysms of arc volcanism. Crustal contamination of volcanic rocks may be caused directly by magma sources which may contain arc material derived from the subcrustal erosion of the margin.     

大别山榴辉岩的密度和波速及其对壳—幔循环的启示

测定了大别山地区榴辉岩和麻粒岩的密度和高温高压 (至 5 .0GPa和 130 0℃ )的纵波速度 (Vp)。超高压榴辉岩具有较高的密度和Vp 及较弱的各向异性。榴辉岩的压力系数为 0 .2 2～ 0 .33km/s·GPa ,超高压榴辉岩的温度系数为 - 3.41× 10 -4 km/s·℃。榴辉岩的密度和波速的分析表明 ,地幔深部的超高压榴辉岩形成后可能包含了两个过程 ,即一部分榴辉岩通过拆沉作用进入深部地幔 ,另一部分快速折返至地壳内或地表 ,榴辉岩的形成过程代表了壳幔物质循环。现今的大别山深部可能只存在少量榴辉岩。     

Nd-isotope systematics of ∼2.7 Ga adakites, magnesian andesites, and arc basalts, Superior Province: evidence for shallow crustal recycling at Archean subduction zones

An association of adakite, magnesian andesite (MA), and Nb-enriched basalt (NEB) volcanic flows, which erupted within ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts, has recently been documented in ∼2.7 Ga Wawa greenstone belts. Large, positive initial ?_Nd values (+1.95 to +2.45) of the adakites signify that their basaltic precursors, with a short crustal residence, were derived from a long-term depleted mantle source. It is likely that the adakites represent the melts of subducted late Archean oceanic crust. Initial ?_Nd values in the MA (+0.14 to +1.68), Nb-enriched basalts and andesites (NEBA) (+1.11 to +2.05), and ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts and andesites (+1.44 to +2.44) overlap with, but extend to lower values than, the adakites. Large, tightly clustered ?_Nd values of the adakites, together with Th/Ce and Ce/Yb systematics of the arc basalts that rule out sediment melting, place the enriched source in the sub-arc mantle. Accordingly, isotopic data for the MA, NEBA, and ‘normal’ arc basalts can be explained by melting of an isotopically heterogeneous sub-arc mantle that had been variably enriched by recycling of continental material into the shallow mantle in late Archean subduction zones up to 200 Ma prior to the 2.7 Ga arc. If the late Archean Wawa adakites, MA, and basalts were generated by similar geodynamic processes as their counterparts in Cenozoic arcs, involving subduction of young and/or hot ocean lithosphere, then it is likely that late Archean oceanic crust, and arc crust, were also created and destroyed by modern plate tectonic-like geodynamic processes. This study suggests that crustal recycling through subduction zone processes played an important role for the generation of heterogeneity in the Archean upper mantle. In addition, the results of this study indicate that the Nd-isotope compositions of Archean arc- and plume-derived volcanic rocks are not very distinct, whereas Phanerozoic plumes and intra-oceanic arcs tend to have different Nd-isotopic compositions.     

广西铝业可持续发展的战略思考

广西铝土矿资源十分丰富，铝业发展具有得天独厚的优势。针对广西铝业的发展现状，分析、阐述了铝业循环经济发展的一系列问题，提出了广西铝业循环经济的战略对策。     

A Comparative Analysis of Curbside Recycling Behavior in Urban and Suburban Communities*

This study explores the variations in household participation rates in recycling projects implemented in urban and suburban communities. A causal model is developed to compare the demographic attributes of residents, their awareness of the recycling programs, their environmental attitudes, and their overall willingness to recycle. The model is assessed by Linear Structural Equations Methodology (LISREL). The results suggest that household recycling behavior is not consistent across communities due primarily to variations in demographic characteristics of residents and their evaluation of program policies.     

Roller-coaster atmospheric-terrestrial-oceanic-climatic system during Ordovician-Silurian transition: Consequences of large igneous provinces

The Ordovician-Silurian transition (OST) hosted profound and frequent changes in the atmospheric-terrestrial-oceanic-climatic system (ATOCS). Previous studies have found contrasting stages for such changes, primarily based on hiatus-interrupted sections. However, the dominant driving factors and mechanisms reconciling such frequent changes remain controversial. Mercury isotopes, which undergo both mass-dependent and mass-independent fractionation, can provide critical insights into the deep-time ATOCSs, especially for those impacted by large igneous provinces (LIPs) events. Here, we build a high-resolution multi-proxy record of Hg (concentrations and isotopic compositions) combined with organic carbon isotopes (δ¹³C_org) and whole-rock geochemical data (including trace elements and phosphorus) from continuous cores in the Yangtze Platform, South China. Our data, combined with reported ones, indicate the occurrence of LIP eruptions against localized volcanism, and four successive, yet contrasting stages of ATOCSs during the OST. Moreover, we identified the coupling between two-pulse LIP magmatism and extreme ATOCSs, each with special pCO₂, weathering rate, primary productivity, redox condition, climatic mode, and biotic evolution. For stage I, the first pulse of LIP magmatism triggered global warming, enhanced terrestrial weathering, oceanic acidification, eutrophication, anoxia, P recycling, and thereby widespread deposition of black shales. During stage II, the Hirnantian glaciation and oxygenation arose from the intense chemical weathering and black shale deposition of stage I; slashed terrestrial weathering and oceanic oxygenation facilitated CO₂ accumulation. In stage III, another pulse of LIP magmatism triggered the de-glaciation, and the ATOCS was largely similar to that of stage I. This led to another round of oxygenation and positive δ¹³C_org excursion in stage IV. Compared with the environmental pressure by the peculiar ATOCS of each stage, their transitions might have been more devastating in triggering the prolonged Late Ordovician Mass Extinction (LOME). Moreover, limited biotic recovery was possible in the later portion of stages I and III. The multi-proxy study of continuous strata of the OST provides an excellent framework for better illuminating LIPs’ essential role in driving the “roller-coaster” behavior of the ATOCS and thus biotic crisis during the pivotal period of the OST.     

小海岛固体废弃物产生特点与处置模式研究

为探求小海岛固体废弃物合理的处理方式,通过文献资料查阅及对我国南海海岛的实地调查,总结出国内外小海岛固废的产生特点为夏秋季节总产量高于冬春季节、日人均产量高于大陆地区、组分以有机垃圾和可燃垃圾为主,处理方式以全部岛内填埋、全部岛外处理和岛内外协同处理为主。针对小海岛的环境特点,探讨出近距离小海岛"岛内生化+岛外焚烧、回收利用"和中远距离海岛"岛内生化+岛内焚烧"的固废处置模式,以期为我国小海岛合理开发治理提供参考。