成岩作用对泥页岩储集性能的影响: 以东营凹陷古近系沙四上亚段为例*

陆相页岩油储集层孔隙结构特征及储集能力受泥页岩在埋藏过程中经历的复杂成岩改造影响,纵向上表现出显著的差异性,但相关研究仍不够深入。以渤海湾盆地东营凹陷古近系沙河街组沙四上亚段典型陆相富有机质泥页岩为研究对象,基于岩心观察描述、岩石薄片鉴定、扫描电镜等多尺度观察手段,结合X射线衍射分析、同位素地球化学分析、物性分析及能谱分析等测试资料,开展泥页岩成岩作用特征及其控储差异研究。研究结果表明: (1)研究区可识别出7种成岩作用类型,其中,建设性成岩作用以方解石重结晶、黏土矿物转化及白云石化作用为主; 沙四上亚段整体处于中成岩A阶段。(2)方解石重结晶、黏土矿物转化及白云石化作用在垂向上表现出显著的差异性演化特征,重结晶成因的亮晶方解石主要发育于纯上3小层与纯上2小层,黏土矿物转化所形成的晶间中—高孔区主要发育于纯上2小层; 研究区主要发育2种类型的白云石,其中,泥晶白云石主要发育于纯上3小层,微晶铁白云石主要发育于纯上1、2小层。(3)方解石重结晶和黏土矿物转化的协同使得纯上2小层产生了大量微孔,同时适量的铁白云石可作为骨架矿物支撑孔隙,有利于中深层孔隙的保存,是该小层成为优质储集层的关键。     

Chemical and Isotopic Constraints for Recrystallization of Sedimentary Dolomites from the Western Canada Sedimentary Basin

Mississippian shoal carbonates of Western CanadaSedimentary Basin are important hydrocarbon hosts.Dolomitization plays a major role in the evolution ofreservoir porosity in these carbonates. This processvaries across the basin and reflects, in part, divergentsources and chemistry of pore fluids. Dolomites fromseveral petroleum reservoirs were analyzed formineralogical, geochemical and isotopic variation. Thedata clearly demonstrate the progressive and complexrecrystallization of dolomite during shallow and deepburial in modified marine, meteoric and burial fluids.These data include: change in crystal size,stoichiometry, cathodoluminscence characteristics,stable oxygen and carbon isotopic shifts and changesin radiogenic Sr isotopic composition. However,regional geology, tectonic history and fluid flowevolution play important roles in the diageneticimprints and the degree of recrystallization.Early microcrystalline dolomite formed in normalmarine and evaporative conditions in Mississippiancarbonates from Western Canada Sedimentary Basinhave undergone variable degrees of recrystallization, frompristine dolomite akin to Holocene sabkha dolomitewith preserved mineralogical and chemical attributesto highly recrystallized mesodolomite, however stillnonstoichiometric, but with highly altered chemicalsignatures. Careful attention should be made to localgeology, hydrodynamics and fluid flow when investigatingdolomite recrystallization in sedimentary basins.     

Hydrothermal recrystallization of the Lower Ordovician dolomite and its significance to reservoir in northern Tarim Basin

Discovered in S15 and some other wells, the Lower Ordovician in the northern Tarim Basin consists mainly of brown gray-dark gray very fine-fine crystalline dolomite, with a minor portion of locally light gray-white medium-coarse crystalline dolomite. Silicification can be observed in the medium-coarse dolomite, and some euhedral drusy quartz can also be found in pores and fractures of the dolomite. The homogenization temperature of the fluid inclusions in the medium-coarse dolomite is between 110 and 200°C with maximum between 140 and 190°C, and the salinity is between 10.7 and 18.5 wt.% NaCl Eq. The homogenization temperature and salinity of the fluid inclusions in the medium-coarse dolomite are similar to those in the drusy quartz. Compared with the very fine-fine dolomite, the medium-coarse phase contains relatively high Fe and Mn. The average concentration of FeO and MnO in the medium-coarse dolomite is 1.917% and 0.323%, respectively. The medium-coarse dolomite has a remarkable negative Eu anomaly, consistent with the REE pattern of the intermediate-felsic igneous rocks in the Tarim Basin. The oxygen isotopic composition of the medium-coarse dolomite is relatively lighter than that of the very fine-fine dolomite. The δ18OPDB values of the medium-coarse dolomite are between -10.35‰ and -7.31‰. The δ18OSMOW values of the fluid associated with the medium-coarse dolomite can be calculated according to homogenization temperature and oxygen isotope fractionation factor between dolomite and fluid, and the calculated values are between +4‰ and +10‰, consistent with those of the hydrothermal fluid. The medium-coarse dolomite has relatively high 87Sr/86Sr ratios as well, indi- cating an origin associated with intermediate-felsic igneous rock. The homogenization temperature, element composition, REE pattern, oxygen and strontium isotopes demonstrate that the medium-coarse dolomite is the result of recrystallization of very fine-fine dolomite under hydrothermal environment. The hydrothermal dolomite recrystallization is a special event but exists extensively in the Tarim Basin. The recrystallized dolomite becomes well reservoir bed for many intercrystalline pores and dissolution pores are produced in this event, so that more attention should be paid to the altered dolomite during the petroleum exploration in the lower Paleozoic in the Tarim Basin.     

石膏矿岩水致老化效应试验

为研究石膏岩的水致老化效应,在室内模拟石膏矿采空区的水环境条件,包括不同空气湿度环境和饱和地下水环境。将石膏岩岩样置于其中,定期取出测定其力学性质指标,得到石膏岩老化的宏观力学表现,并结合核磁共振技术测定试验过程中石膏岩岩样内部的孔隙结构变化,分析石膏岩的水致老化机制。研究结果表明,水对石膏岩的老化效应具有显著的影响。老化程度随时间递增,石膏岩的单轴抗压强度、巴西抗拉强度和弹性模量与置于水环境中的时间基本呈负指数关系,泊松比则无明显变化规律;石膏岩老化程度和老化速率与水的状态密切相关。相对湿度越高,石膏岩的老化越显著,老化速率也更快,尤其是被液态水浸泡时,石膏岩的老化最显著,老化速率最快。水对石膏岩的老化过程是水的物理作用与化学作用的耦合,而化学作用是水致石膏岩老化的根本原因。石膏岩与水接触时,石膏的溶解、重结晶作用的不断进行改变着石膏岩的矿物组成结构,使其结构由紧密变得松散,孔隙率增大,力学性质不断弱化。该试验研究结果可为石膏矿开采的设计及采后空区的长期稳定性评估提供参考。     

Grain Coarsening of Hematite in the Gushan Iron Deposit,Anhui Province,China

The iron ores of the Gushan mine occur in the contact zone of a Mesozoic diorite intrusion and are composed primarily of hematite microcrystallites and chalcedony,The hematite microcrystallites have undergone post-mineralization recrystallization and coarsening with resultant formation of lath-shaped hematite porphyroblasts.Microscopic investigation reveals that recrystallization and coarsening of the hematite ores of the Gushan mine took place without the formation of new nuclei,due to the coalescence of the microcrystallites.The whole process could have begun with the mutual approach of the microcrystallites,followed by grain rotation to realize paralleism and ending by the welding of these grains to form optically homogeneous porphyroblastic hematite.     

Grain‐scale dependency of metamorphic reaction on crystal plastic strain

The Breaksea Orthogneiss in Fiordland, New Zealand preserves water‐poor intermediate and mafic igneous rocks that were partially recrystallized to omphacite granulite and eclogite, respectively, at P ≈ 1.8 GPa and T ≈ 850°C. Metamorphic reaction consumed plagioclase and produced grossular‐rich garnet, jadeite‐rich omphacite, clinozoisite and kyanite. The extent of metamorphic reaction, identified by major and trace element composition and microstructural features, is patchy on the grain and outcrop scale. Domains of re‐equilibration coincide with areas that exhibit higher strain suggesting a causal link between crystal plastic strain and metamorphic reaction. Quantitative orientation analysis (EBSD) identifies gradual and stepped changes in crystal lattice orientations of igneous phenocrysts that are surrounded by homophase areas of neoblasts, characterized by high grain boundary to volume ratios and little to no internal lattice distortion. The narrow, peripheral compositional modification of less deformed garnet and omphacite phenocrysts reflects limited lattice diffusion in areas that lacked three‐dimensional networks of interconnected low‐angle boundaries. Low‐angle boundaries acted as elemental pathways (pipe diffusion) that enhanced in‐grain element diffusion. The scale of pipe diffusion is pronounced in garnet relatively to clinopyroxene. Strain‐induced mineral transformation largely controlled the extent of high‐T metamorphic reaction under relatively fluid‐poor conditions.     

Uncoupled U/Pb and REE response in zircon during the transformation of eclogite to mafic and intermediate granulite (Blanský les,Bohemian Massif)

An eclogite–mafic granulite occurs as a rare boudin within a felsic kyanite–K‐feldspar granulite in a low‐strain zone. Its boundary is marked by significant metasomatism–diffusional gain of potassium at the centimetre‐scale, and probable infiltration of felsic melt on a larger scale. This converted the eclogite–mafic granulite into an intermediate‐composition, ternary‐feldspar‐bearing granulite. Based on inclusions in garnet, the peak P–T conditions of the original eclogite are 18 kbar at 850–950 °C, with later matrix re‐equilibration at 12 kbar and 950 °C. Four samples from the transition of the eclogite–mafic granulite through to the intermediate granulite were studied. In the eclogite, REE patterns in the garnet core show no Eu anomaly, compatible with crystallization in the absence of plagioclase and consistent with eclogite facies conditions. Towards the rim of garnet, LREE decrease, and a weak negative Eu anomaly appears, reflecting passage into HP granulite facies conditions with plagioclase present. The rims of garnet next to ternary feldspar in the intermediate granulite show the lowest LREE and deepest Eu anomalies. Zircon from the four samples was analysed by LASS (laser ablation–split‐stream inductively coupled plasma–mass spectrometry). It shows U–Pb ages from 404 ± 4.0 to 331 ± 3.3 Ma, with a peak at 340 ± 4.0 Ma corresponding to the likely exhumation of the rocks to 12 kbar. Older ages from zircon with steep HREE patterns indicate the minimum age of the protolith, and ages <360 ± 4.0 Ma are interpreted to correspond to the eclogite facies metamorphism. Only some zircon grains ≤350 ± 4.0 Ma have flat HREE patterns, suggesting that these are primarily modified protolith grains, rather than new zircon crystallized in the eclogite‐ or granulite facies. The metasomatic processes that converted the eclogite–mafic granulite to an intermediate granulite may have facilitated zircon modification as zircon in the intermediate granulite has flat HREE and ages of 340 ± 4.0 Ma. The difference between the oldest and youngest ages with flat REE patterns indicates a 16 ± 5.6 Ma period of zircon modification in the presence of garnet.     

Zircon (re)crystallization during short‐lived,high‐P granulite facies metamorphism (Eger Complex,NW Bohemian Massif)

The Eger Complex in the northwestern Bohemian Massif consists mainly of amphibolite facies granitic gneisses containing a subordinate volume of felsic granulites. Microstructural changes and modelling of metamorphic conditions for both rock types suggest a short‐lived static heating from ~760 to ~850 °C at a constant pressure of ~16 kbar, which led to the partial granulitization of the granitoid rocks. Detailed study of the protolith zircon modifications and modelling of the Zr re‐distribution during the transition from amphibolite to granulite facies suggests that the development of c. 340 Ma old zircon rims in the granulite facies sample is the result of recrystallization of older (c. 475 Ma) protolith zircon. This study suggests that the partial granulitization is a result of a short exposure of the Eger Complex metagranitoids to a temperature of ~850 °C at the base of an arc/fore‐arc domain and their subsequent rapid exhumation during the Lower Carboniferous collision along the western margin of the Bohemian Massif.     

桐柏山商丹断裂带东延段石榴云母片岩中石榴子石显微构造特征及变质—变形环境分析

韧性剪切带上岩石变质—变形条件的研究是探讨造山带造山过程及造山机制的重要环节.岩石中矿物显微、超微构造特征是造山带形成环境的真实体现,是造山带变形研究的基础.本文通过对商丹断裂带(即商南—丹凤断裂带)东延段桐柏山地区石榴云母片岩中石榴子石的位错特征及动态重结晶型式等显微构造特征,分析研究石榴子石塑性变形方式、变形机制及...     

大变形橄榄石动态重结晶的实验观测研究

本文利用高温高压大变形扭转实验,对富铁橄榄石大变形情况下的动态重结晶和颗粒尺度变化的特点进行了实验观测分析.富铁橄榄石集合体由纯铁橄榄石Fa100和圣卡罗橄榄石Fa10混合物经人工合成得到,试件的几何形状为圆柱体,直径9.6mm,高度4.86mm.实验在常角速率条件下进行,温度为1473K,围压为300MPa,剪应力为72 ～ 99MPa,剪应变率为1.35×10-4～3.11×10-4s-1,累积剪应变为3.98.对变形后样品的微结构进行了光学和扫描电镜的观测分析,得到橄榄石颗粒随应变增加而产生动态重结晶的具体物理图像,由EBSD观测结果给出了晶格取向随外加应变增加而产生的变化过程,利用两种统计方法得到了颗粒尺寸随应变增加而变化的过程,探讨了橄榄石动态重结晶的微观机制.与已有三轴压缩、简单剪切以及圣卡罗橄榄石的扭转变形结果进行了对比分析,同时对实验结果在地球物理方面的应用进行了讨论.