舒兰韧性剪切带应变分析及石英动态重结晶颗粒分形特征与流变参数估算

舒兰北东向韧性剪切带位于佳木斯-伊通断裂带(佳-伊断裂带)中南段, 剪切带内糜棱岩具有明显左行走滑特征, 片麻理产状近NNE向.糜棱岩中长石有限应变Flinn图解判别岩石类型为L-S型构造岩, 属拉长型应变.石英C轴EBSD组构分析表明, 石英组构以中低温菱面为主, 滑移系为{0001} < 110>.剪切带内糜棱岩的剪应变为0.44, 不同方法计算所得运动学涡度值均大于0.95, 指示剪切变形以简单剪切为主.综合矿物变形温度计、石英C轴EBSD组构、石英的粒度-频数图及Kruhl温度计综合估计该韧性剪切带变形机制以位错蠕变机制为主, 变质相为低绿片岩相, 发生韧性变形和糜棱岩化温度范围在400~500 ℃之间.糜棱岩内石英动态重结晶新晶粒边界普遍具有锯齿状或港湾状结构, 利用分形方法对其重结晶新晶边界研究表明, 这些晶粒边界具有自相似性, 表现出分形特征, 分形维数值为1.195~1.220.根据石英重结晶粒径估算差应力值为24.35~27.59 MPa, 代表了舒兰韧性剪切带糜棱岩化作用过程的差异应力下限.使用不同实验方法估算、比较和分析了该剪切带古应变速率, 认为该速率应为10-12.00~10-13.18 s-1, 与区域性应变速率10-13.00~10-15.00 s-1对比, 说明舒兰韧性剪切带的应变速率与世界上大多数韧性剪切带中的糜棱岩应变速率一致, 是缓慢变形的结果, 其形成可能与早白垩世伊泽纳崎板块向欧亚大陆俯冲发生转向有关.      

成岩作用对泥页岩储集性能的影响: 以东营凹陷古近系沙四上亚段为例*

陆相页岩油储集层孔隙结构特征及储集能力受泥页岩在埋藏过程中经历的复杂成岩改造影响,纵向上表现出显著的差异性,但相关研究仍不够深入。以渤海湾盆地东营凹陷古近系沙河街组沙四上亚段典型陆相富有机质泥页岩为研究对象,基于岩心观察描述、岩石薄片鉴定、扫描电镜等多尺度观察手段,结合X射线衍射分析、同位素地球化学分析、物性分析及能谱分析等测试资料,开展泥页岩成岩作用特征及其控储差异研究。研究结果表明: (1)研究区可识别出7种成岩作用类型,其中,建设性成岩作用以方解石重结晶、黏土矿物转化及白云石化作用为主; 沙四上亚段整体处于中成岩A阶段。(2)方解石重结晶、黏土矿物转化及白云石化作用在垂向上表现出显著的差异性演化特征,重结晶成因的亮晶方解石主要发育于纯上3小层与纯上2小层,黏土矿物转化所形成的晶间中—高孔区主要发育于纯上2小层; 研究区主要发育2种类型的白云石,其中,泥晶白云石主要发育于纯上3小层,微晶铁白云石主要发育于纯上1、2小层。(3)方解石重结晶和黏土矿物转化的协同使得纯上2小层产生了大量微孔,同时适量的铁白云石可作为骨架矿物支撑孔隙,有利于中深层孔隙的保存,是该小层成为优质储集层的关键。     

异向性岩芯冰的反复压缩-退火实验研究

在蠕变试验机上完成了三组(6块样品)单轴反复压缩-退火实验,试验机载荷精度为1％,实验温度为-2±0.2℃。实验样品取自南极洛多姆冰帽BHQ钻孔的冰岩芯。三组试样的受压方向分别与冰岩芯的轴向平行、成45°角和垂直。试验前试样的C轴组构为单极大型或大致为单极大型,晶粒大小不一。用0.8MPa的初始轴向应力对样品进行压缩,达到10％应变后卸载退火72小时。每组实验如此反复进行6次。结果表明,在较高的温度和大载荷下,样品经反复压缩-退火,其初始组构特征消失,代之以小环状组构和细的、等粒的晶体,某些情况下发展为多极大型组构。结构和组构分析表明,新组构的形成机制主要是再结晶作用。随着压缩-退火反复进行,六块样品在组构上的差异减少,它们的流变特性趋于一致,晶粒尺寸逐渐减少而趋于一个稳定值。     

陕北盐盆奥陶系马家沟组五段蒸发岩沉积环境与作用——来自石盐流体包裹体的证据

陕北盐盆地因发育全球罕见的奥陶系马家沟组五段含盐地层受到广泛关注。文章运用X射线粉晶衍射矿物组分半定量分析、流体包裹体的均一温度、拉曼光谱、扫描电镜能谱和包裹体氢同位素分析等多种手段,对陕北米脂县境内两口钻井奥陶系马家沟组石盐岩进行了分析和测试。流体包裹体均一温度测试结果表明,石盐岩中原生单一液相包裹体、次生正方形单一液相包裹体的均一温度平均值分别为27.9℃、30.6℃,峰值均为25~30℃,次生与原生的流体包裹体的形成环境基本一致。在重结晶程度高的层段,石盐岩流体包裹体的δD值和石盐岩K+含量的变化趋势相反,结合该时期内含盐层段宏观地质特征以及钾石盐颗粒常呈圆粒状赋存在石盐晶间裂缝等微观证据,笔者认为研究区石盐岩沉积时因外来水体频繁侵入导致原生石盐岩发生溶解和重结晶,降低了形成大规模钾盐矿床的概率。     

Mylonitic deformation of gabbro in the lower crust: A case study from the Pankenushi gabbro in the Hidaka metamorphic belt of central Hokkaido, Japan

The mylonitization of the Pankenushi gabbro in the Hidaka metamorphic belt of central Hokkaido, Japan, occurred along its western margin at ≈600 MPa and 660–700 °C through dynamic recrystallization of plagioclase and a retrograde reaction from granulite facies to amphibolite facies (orthopyroxene + clinopyroxene + plagioclase + H₂O = hornblende + quartz). The reaction produced a fine-grained (≤100 μm) polymineralic aggregate composed of orthopyroxene, clinopyroxene, quartz, hornblende, biotite and ilmenite, into which strain is localized. The dynamic recrystallization of plagioclase occurred by grain boundary migration, and produced a monomineralic aggregate of grains whose crystallographic orientations are mostly unrelated to those of porphyroclasts. The monomineralic plagioclase aggregates and the fine-grained polymineralic aggregates are interlayered and define the mylonitic foliation, while the latter is also mixed into the former by grain boundary sliding to form a rather homogeneous polymineralic matrix in ultramylonites. However in both mylonite and ultramylonite, plagioclase aggregates form a stress-supporting framework, and therefore controlled the rock rheology. Crystal plastic deformation of pyroxenes and plagioclase with dominant (100)[001] and (001)1/2 slip systems, respectively, produced distinct shape- and crystallographic-preferred orientations of pyroxene porphyroclasts and dynamically recrystallized plagioclase grains in both mylonite and ultramylonite. Euhedral to subhedral growth of hornblende in pyroxene porphyroclast tails during the reaction and its subsequent rigid rotation in the fine-grained polymineralic aggregate or matrix produced clear shape- and crystallographic-preferred orientations of hornblende grains in both mylonite and ultramylonite. In contrast, the dominant grain boundary sliding of pyroxene and quartz grains in the fine-grained polymineralic aggregate of the mylonite resulted in their very weak shape- and crystallographic-preferred orientations. In the fine-grained polymineralic matrix of the ultramylonite, however, pyroxene and quartz grains became scattered and isolated in the plagioclase aggregate so that they were crystal-plastically deformed leading to stronger shape- and crystallographic-preferred orientations than those seen in the mylonite.     

An extension of the Saltykov method to quantify 3D grain size distributions in mylonites

The estimation of 3D grain size distributions (GSDs) in mylonites is key to understanding the rheological properties of crystalline aggregates and to constraining dynamic recrystallization models. This paper investigates whether a common stereological method, the Saltykov method, is appropriate for the study of GSDs in mylonites. In addition, we present a new stereological method, named the two-step method, which estimates a lognormal probability density function describing the 3D GSD. Both methods are tested for reproducibility and accuracy using natural and synthetic data sets. The main conclusion is that both methods are accurate and simple enough to be systematically used in recrystallized aggregates with near-equant grains. The Saltykov method is particularly suitable for estimating the volume percentage of particular grain-size fractions with an absolute uncertainty of ±5 in the estimates. The two-step method is suitable for quantifying the shape of the actual 3D GSD in recrystallized rocks using a single value, the multiplicative standard deviation (MSD) parameter, and providing a precision in the estimate typically better than 5%. The novel method provides a MSD value in recrystallized quartz that differs from previous estimates based on apparent 2D GSDs, highlighting the inconvenience of using apparent GSDs for such tasks.     

秦岭伏牛山构造带的矿物岩石学特征与流变学分析

本文通过对伏牛山构造带岩石的矿物岩石学、石英重结晶型式、石英分维值和有限应变等特征分析研究,认为伏牛山构造带的变质-变形深受洛南-栾川断裂带的影响,其变化有明显的规律性,从断裂带往北岩石从糜棱岩依次过渡为片岩-片麻岩-花岗岩原岩.构造带内发育多种糜棱岩,岩石变形强烈,远离构造带岩石的变形逐渐变弱.从构造带往北,石英的重...     

MgCl2+NaCl+H2O体系相图计算及其在氯化镁重结晶提纯中的应用

利用Pitzer电解质溶液热力学模型,对MgCl2+NaCl+H2O体系部分多温相图进行了模拟。借助获得的多温相图,对含有NaCl杂质的六水氯化镁试剂重结晶提纯中出现的异常现象进行了分析。研究结果表明,重结晶法提纯化学纯试剂的有效性不是绝对的。虽然化学试剂中的杂质含量已经很低,但是是否能够使用重结晶法进一步提纯是由试剂和试剂中所含杂质的类型决定的。对于主要含有NaCl杂质的六水氯化镁试剂,只有当NaCl杂质含量低于一定值时才能够利用一步重结晶取固相的方法进行提纯;高于此值时,利用一步重结晶取固相的方法反而会使产品质量越来越差。当六水氯化镁中杂质含量高于临界值时,想要对其进行提纯,必须采用分步结晶的方法,首先去除先析出的NaCl杂质。     

五莲拆离断层带动态重结晶石英颗粒的分形特征及流变参数估算

五莲拆离断层带中石英韧性变形明显,在野外主要表现为条带状、拔丝状,显微镜下主要表现为多晶石英条带,发育亚颗粒旋转重结晶和膨凸重结晶,剪切带经历了中低温条件下的变形,变形温度为300～450℃。利用分形方法对石英颗粒边界的研究表明,发生动态重结晶的石英颗粒边界具有统计学意义上的自相似性和明显的分形特征,亚颗粒旋转重结晶石英颗粒分维数介于1. 260～1. 319之间,均值1. 276;膨凸重结晶石英颗粒的分维数为1. 217～1. 297,均值为1. 256;根据石英粒径估算出亚颗粒旋转重结晶和膨凸重结晶作用变形阶段的古差异应力,分别为7. 84～21. 58MPa和18. 51～56. 65 MPa;基于分维值计算的应变速率计算公式,获得亚颗粒旋转与膨凸重结晶石英颗粒的应变速率分别为10-8. 4～10-7. 7s-1、10-10. 5～10-9. 7s-1;基于石英流变率计算,亚颗粒旋转重结晶的石英应变速率介于10-12. 88～10-11. 73s-1之间,膨凸重结晶的为10-13. 72～10-12. 46s-1。本地区韧性变形的应变速率大于一般性韧性剪切带应变速率,可能与拆离断层带的快速拆离伸展作用有关。