石墨炉原子吸收光谱法测定农业地质调查土壤样品中镉的不确定度评定

用实例对石墨炉原子吸收光谱法测定土壤样品中镉元素的不确定度进行评定,采用《测量不确定度评定与表示指南》对测量结果进行评估。分析了不确定度的主要来源,包括测量浓度的不确定度、体积的不确定度、称量不确定度及测量重复性引起的不确定度。评估了镉含量的合成标准不确定度和扩展不确定度。对于镉含量为0.42×10-6的土壤样品,其扩展不确定度为0.04×10-6。     

多目标地球化学调查土壤样品中氮和碳的快速测定

详细研究了元素分析仪的工作条件，建立了直接固体进样同时测定多目标地球化学调查土壤样苎支氮、碳的方法。方法简便、快速，检出限为氮14．5μg／g、碳0．013％。经土壤国家一级标准物质分析验证，测定值与标准值相符，精密度（RSD，n=12）为氮1．49％-3．27％、碳0.64％～3.63％。     

我国低钛月海型模拟月壤初始物质选择的地球化学依据

以Apollo14月壤样品和美国JSC-1模拟月壤的地球化学特征为基础,结合我国低钛玄武岩火山的分布,对我国不同地区新生代玄武岩的化学成分、年龄、储量等方面进行对比分析结果表明,滇西北金沙江地区和吉林辉南红旗林场-四海地区的玄武质火山喷发物的化学成分与Apollo14月壤样品和美国JSC-1模拟月壤相似,比较适合用于我国低钛月海玄武岩模拟月壤研制的初始物质。野外地质调查发现,吉林省辉南县金川镇红旗林场—四海一带产出的玄武质火山渣为距今1600 a的该玄武质火山岩的喷发物,其储量大、质地纯、粒度均匀,而且比滇西北金沙江地区最近一期的玄武质火山渣新鲜,最适合作为我国低钛月海玄武岩模拟月壤研制的初始物质。     

微生物降解有机物的碳氢同位素分馏研究进展

微生物降解使有机化合物的稳定碳、氢同位素发生不同程度分馏的研究在有机污染物来源和微生物环境修复等领域取得了长足进展,并对原油和天然气微生物降解研究有借鉴意义。微生物作用下的同位素分馏为动力同位素分馏,导致重同位素在残余物中富集。影响微生物降解有机物同位素分馏的主要因素有微生物的降解代谢途径、辅酶作用、降解类型与程度、同位素质量差异和有机物碳数等。不同的微生物代谢途径代表不同的生物化学反应,造成了同位素分馏的显著差异;辅酶对反应的催化作用使微生物作用造成的同位素分馏更加复杂。低碳数正构烷烃遭受微生物降解程度越高,碳、氢同位素的分馏也越大,同位素变重与降解程度之间有明显的相关性。但对于复杂化合物,由于降解的多级反应,同位素分馏与降解程度间的相关性并不明显。在同样降解程度下,氢同位素分馏大于碳同位素分馏,低碳数正构烷烃的同位素分馏大于高碳数正构烷烃的同位素分馏。     

电磁感应仪EM38用于土壤盐渍剖面分类与评价研究

结合电磁感应仪EM38测量与田间采样,文章分析了黄河三角洲典型区域土壤电导率的剖面分布特征,建立了磁感式表观电导率与土壤电导率间的(多元)回归解译模型,探讨了不同分类方法对土壤盐渍剖面分类结果的准确性,并对典型盐渍剖面类型进行了评价。结果表明:研究区土壤盐分具有较强的表聚性与变异强度;土壤电导率与磁感表观电导率EMh、EMv间呈极显著的相关关系,EMh对浅层土壤电导率的解译精度较高,而EMv对深层土壤电导率的解译精度较高;EMv/EMh法和理论函数法对土壤盐渍剖面的分类结果均具有较高的精度,且理论函数法分类结果的准确性明显优于EMv/EMh法;研究区土壤盐渍剖面可划分为表聚型、底聚型与均匀型,在数量上以表聚型及底聚型为主,其中表聚型与均匀型属于积盐型剖面,底聚型属于脱盐型剖面。该结果对研究黄河三角洲地区土壤盐渍化的发生、机理、预测与评估该地区土壤盐渍化的发生、发展具有重要意义。     

Evaluation of landscape changes and ecological degradation by GIS in arid regions: a case study of the terminal oasis of the Shiyang River,northwest China

The development and utilization of water and land resources in the Shiyang River basin are the highest among the inland rivers in northwestern China. Using GIS and the landscape structure analysis program FRAGSTATS, landscape metrics of a study area in the lake-district in Minqin Oasis in the lower reaches of Shiyang River basin were calculated and analyzed based on TM images from 1987 to 2001 at class level and landscape level, respectively. Transformation matrix of the landscape mosaics was also examined. The driving forces of landscape changes were analyzed, including the dynamics of runoff and groundwater resources and their exploitation, and influences of policies and market economy. The results showed that: (1) Patch number of farmland and desert decreased, but their mean patch area increased, indicating that reclamation and desertification was very serious in the study area. Contagion index for oasis increased and edge density and landscape diversity were reduced. (2) Farmland and desert areas have enlarged by 1,520.46 and 4,941.27 hm², respectively. This increase was at the cost of woodland and grassland, which shrank by 1,520.46 and 4,941.27 hm², respectively. (3) The net utilization of surface water decreased by 50% in the last 10 years, and dropped to 22.3 × 10⁶ m³ in the later 1990s. Exploitation of groundwater increased remarkably, up to 80 × 10⁶ m³ per year in the last 5 years. (4) The capability of the economic structure to withstand pressures of the market economy has depressed distinctly because of the simplified planting pattern, which is dominated by salinity-enduring cash crops, such as cotton. Based on the above analysis, strategies of ecological reconstruction in the lake-district were suggested.     

Surface properties of stabilizing coastal dunes: combining spectral and field analyses

The coastal dunes of Israel have been undergoing a process of stabilization since 1948. One of the major features of this process is a change in the surface properties of the dunes – the development of a biological soil crust (BSC), and a change in the properties of the sand grains themselves. In Ashdod, at the southern coastal plain of Israel, sand properties that include the BSC, their fines (silt and clay) content and free iron-oxide (indicating their degree of rubification) have been analysed in detail using field and lab spectroscopy methods. In addition, sand erosion and deposition were measured using erosion pins to determine their effect on the presence of the above-mentioned factors. It was found that the BSC over these dunes is comprised of green algae that differs in its reflectance spectra from cyanobacterial crust, especially in the blue band. The crust was found to be particularly developed in the stable areas (mainly the interdunes) and on the north-facing slopes rather than on the south-facing slopes. A positive correlation was found between the crust fines and chlorophyll content, with stable areas showing more developed BSC. The stable areas showed also a lower albedo and slightly more developed reddish colour, indicating a slightly higher rate of rubification. This study demonstrates that the intensity of sand erosion/deposition rates affects soil properties, with the BSC being the fastest to react to the stabilization process (months to several years), followed by the content of fine particles (several years to a decade), whereas the rubification process is a much weaker marker and may need much longer time periods to develop (decades to centuries).     

被动微波反演裸露区土壤水分综述

被动微波具有全天候、穿透性以及不受云的影响等特征,使其在反演土壤水分时具有很大的优势。通过研究发现,被动微波遥感是反演土壤水分的各种技术中最有效的方法之一。概括了主要的被动微波传感器并从被动微波遥感的原理出发,针对被动微波遥感裸露区地表随机粗糙面的模型以及土壤水分反演算法作了简要介绍。     

用ERS风散射计数据估算土壤水分方法的研究

欧空局ERS1/2卫星上的风散射计(WSC),分辨率是50km,4天内能覆盖全球超过80%的范围,并可在多角度下对地物目标进行观测。本文研究利用该散射计数据估算土壤水分的方法。首先,利用基于ERS散射计数据建立的全球C波段雷达后向散射系数数据库,根据传统的几何光学模型(GOM),反演得到与土壤含水量密切相关的法线方向Fresnel反射率,并与两个采样点(安多和那曲)上的实测降雨量及土壤水分相对比,证明了ERS散射计数据与土壤水分的高相关性;第二步,以水云模型为基础,结合AIEM模型,发展了一种简化模型来估算土壤水分绝对值,分别利用气象站实测点数据和同时期的Basist湿度指数(BWI)进行验证,表明反演结果能较好反映土壤水分的空间分布状况。     

Analysis of the impact of conservation measures on stream flow regime in catchments of the Loess Plateau,China

Catchments in the Loess Plateau have been under the influence of human activities for centuries. In the last four decades, soil conservation measures have accelerated and intensified. These measures were designed to reduce soil erosion, improve agricultural productivity, and enhance environmental quality. It is important to evaluate the effects of these measures on hydrology in order to develop sustainable catchment management plans in the region. This study evaluated changes in stream flow data for four selected catchments in the Loess Plateau following large‐scale soil conservation measures. The non‐parametric Mann–Kendall test was used to identify trends in annual stream flow and the results showed significant downward trends in three of the four catchments. The Pettitt test indicated that a change point occurred in 1978 in these three catchments. Annual precipitation in all the catchments showed no significant trend during the period of record. Comparison of daily flow duration curves for two 20‐year periods (1957–1978) and (1979–2003) showed significant changes in stream flow regime. Reduction in most percentile flows varied between 20 and 45%, and the reduction in low flows was greatest. Overall, the reductions in daily flow were increasing with time, with significant changes occurring in the 1990s. However, it is not clear whether these catchments have seen the full effects of the soil conservation measures, so the results of this study might underestimate the final impact of soil conservation on stream flow regime. Copyright © 2007 John Wiley & Sons, Ltd.