用三氧化铬-硫酸溶剂对黑色页岩铼-锇定年方法初探

讨论了铼-锇同位素稀释法测定黑色页岩年龄的溶样方式,比较了王水和不同温度下CrO3-H2SO4的Carius管溶样技术,通过改进流程将铼空白控制在10pg之内,并结合高灵敏度的电感耦合等离子体质谱分析手段,初步研究建立了一种用CrO3-H2SO4溶剂准确测定黑色页岩年龄的方法。     

基于重点抽样法的固定式平台结构风险评价研究

在建立海上油气设施的风险分析系统时,对由台风引发的极端海况造成的结构失效进行风险评估是1个十分重要的问题。为了建立实用可靠的风险评价方法,本文使用基于重点抽样法的随机模拟技术,对渤海海域CB12-C井组平台结构进行了全概率法失效概率计算,并在此基础上进行了平台结构的风险评价。该方法是1种适用于固定式海洋平台的定量风险评价方法,充分考虑了平台结构风险分析过程中各种不确定性的影响,极大提高了定量风险评价结果的可靠性。     

氢氧化镁共沉淀测定低浓度磷方法在东海赤潮高发区的应用

2003年5月将Karl and Tien(1992)提出的Mg(OH)2共沉淀方法应用于东海赤潮高发区水体中磷酸盐的调查。本实验条件下方法的检测限为0.004μmol/L。将该方法与传统的磷钼兰方法进行对比,常规磷钼兰法高于共沉淀法。说明水体中可能存在大量酸性条件下不稳定的磷化合物,且其不能被Mg(OH)2共沉淀,如1-磷酸核糖。此时,共沉淀法的测定值更接近水体中真实的正磷酸盐含量。共沉淀法可为赤潮爆发过程中低磷阶段的样品分析提供较可靠数据。用共沉淀法提供的测定数据分析赤潮爆发过程中水体中磷酸盐的变化,长江口磷酸盐总的分布趋势是沿岸含量较高,向外海逐渐递减。赤潮爆发过程中,随着赤潮藻类增殖,水体中磷酸盐被大量消耗,表层磷酸盐浓度迅速降低;赤潮消亡阶段,表层水体磷酸盐浓度逐渐回升,而底层由于藻类死亡后逐渐沉降磷酸盐浓度升高。     

水分胁迫条件下稻田优化灌溉制度的研究

本文通过对非充分灌溉条件下水稻优化灌溉制度如何制定进行了研究。其特点是将作物产量模型与耗水规律模型相结合,以相对产量最高为目标函数,建立了优化决策系统,并利用多目标规划进行求解。该研究成果可使有限的水量在作物生育期内发挥最大的效率,对优化配置水资源,实现农业高效用水具有重要作用。实例研究结果说明,所建模型及求解方法是合理与可行的,不但提高了水分利用效率,还为查哈阳灌区水资源的优化利用提供了科学依据。     

A stabilized assumed deformation gradient finite element formulation for strongly coupled poromechanical simulations at finite strain

An adaptively stabilized finite element scheme is proposed for a strongly coupled hydro‐mechanical problem in fluid‐infiltrating porous solids at finite strain. We first present the derivation of the poromechanics model via mixture theory in large deformation. By exploiting assumed deformation gradient techniques, we develop a numerical procedure capable of simultaneously curing the multiple‐locking phenomena related to shear failure, incompressibility imposed by pore fluid, and/or incompressible solid skeleton and produce solutions that satisfy the inf‐sup condition. The template‐based generic programming and automatic differentiation (AD) techniques used to implement the stabilized model are also highlighted. Finally, numerical examples are given to show the versatility and efficiency of this model. Copyright © 2013 John Wiley & Sons, Ltd.     

Numerical characterization of dispersion coefficients by meshless‐based inverse analysis

This study presents the preliminary development of a meshless‐based indirect inverse analysis. Two goals are desired to be attained: (a) identifying fewer quantities in an indirect inverse analysis and (b) getting the interpolation results of spatial variation of a quantity insensitive to the replacement of one or few interpolation points with other points. This idea is illustrated by modifying a meshless local Petrov‐Galerkin (MLPG) formulation of a two‐dimensional (2D) contaminant transport problem under the concept of boundary control. Thus, dispersion coefficients to be identified are solved from measured or prescribed pollutant concentrations. A field problem is introduced to test the performance of resulting meshless‐based indirect inverse analysis procedure. This test finds a major motive and a minor one for performing a meshless‐based indirect inverse analysis. The major motive is attaining the aforementioned Goal (b), while the above‐mentioned Goal (a) is the minor motive. In conclusion, the development of a meshless‐based indirect inverse analysis procedure can be a valuable application of the MLPG method. Copyright © 2010 John Wiley & Sons, Ltd.     

A numerical procedure for predicting rainfall‐induced movements of active landslides along pre‐existing slip surfaces

A numerical model to predict landslide movements along pre‐existing slip surfaces from rainfall data is presented. The model comprises: a transient seepage finite‐element analysis to compute the variations of pore water pressures due to rainfall; a limit equilibrium stability analysis to compute the factors of safety along the slip surface associated with transient pore pressure conditions; an empirical relationship between the factor of safety and the rate of displacement of the slide along the slip surface; an optimization algorithm for the calibration of analyses and relationships based on available monitoring data. The model is validated with reference to a well‐monitored active slide in central Italy, characterized by very slow movements occurring within a narrow band of weathered bedrock overlaid by a clayey silt colluvial cover. The model is conveniently divided and presented in two parts: a groundwater model and a kinematic model. In the first part, monthly recorded rainfall data are used as time‐dependent flow boundary conditions of the transient seepage analysis, while piezometric levels are used to calibrate the analysis by minimizing the errors between monitoring data and computed pore pressures. In the second part, measured inclinometric movements are used to calibrate the empirical relationship between the rate of displacement along the slip surface and the factor of safety, whose variation with time is computed by a time‐dependent stability analysis. Copyright © 2007 John Wiley & Sons, Ltd.     

Factors influencing determination of shale classification indices and their correlation to mechanical properties

The influence of sample preparation procedure on the measured classification indices such as clay-size fraction, liquid limit, and plastic limit of shales was investigated. Shale samples covering a wide range of composition and plasticity were tested using standard and modified preparation procedures to yield quantitative data required for this investigation. The study specifies the range of shale plasticity in which the measured values of clay-size fraction and liquid limit are sensitive to hydrometer specimen size and rehydration time, respectively. The study also revealed that the degree of shale particle disaggregation has an important influence on the measured clay-size fraction and liquid limit. This influence is maximized for shales with intermediate plasticity and can be interpreted in terms of particle size and shape. Correlations were established between classification indices derived from standard and modified sample preparation procedures. It is recommended to use these correlations to adjust shale classification indices derived from standard sample preparation procedures usually utilized by commercial laboratories. Such correlations help in creating a universally followed procedure for better estimation of shale engineering properties and reliable interpretation of case histories involving shale formations.     

中国经济高质量发展的空间关联网络及其作用机制

高质量发展是中国“十四五”乃至更长时期经济社会发展的主题,也是适应社会主要矛盾变化的基本要求,更是建设社会主义现代化国家的关键路径和遵循经济实践规律的根本所在。本文从创新、协调、绿色、开放、共享5个维度构建经济高质量发展的评价指标体系,测度了2011—2018年中国31个省（自治区、直辖市）的经济高质量发展水平,在此基础上运用社会网络分析（SNA）和二次指派程序（QAP）分别对经济高质量发展的关联网络结构特征和经济高质量发展差异的作用机制进行分析。研究发现：① 空间关联网络的关联度一直为1,且网络密度稳定在0.2~0.26之间,省际经济高质量发展的空间关联网络通达性较强且存在多重叠加现象和一定的等级性,但关联紧密程度有待提高,各网络指标保持相对稳定。② 省际经济高质量发展的空间关联网络可以分为4个板块,其中以西部省份为主的“净溢出”板块获益最小;以中部省份为主的“经纪人”板块起着“中介”和“桥梁”的作用;以环渤海省份为主的“双向溢出”板块和以长三角、东南沿海省份为主的“净受益”板块在空间关联网络中的掌控和支配作用更大,且在全国经济高质量发展过程中所起的极化作用大于涓滴作用。③ 人力资本、城市化水平、金融科技和环境质量的地区差异都会直接造成地区间经济高质量发展水平的差异,人力资本差异对其贡献超过了90%。     

滑坡灾害防治工程中施工组织设计对工程投资概算影响的研究

本文通过对具体地质灾害防治工程初步设计阶段的施工组织设计与工程投资概算之间关系分析, 指出施工组织对工程投资概算的影响不小于工程设计和地质勘查资料的影响, 施工组织设计对概算可靠度的提高有很重要的意义。