湖南涟源凹陷构造演化与油气成藏研究

涟源凹陷经历了2个主要构造演化阶段:晚古生代海相碳酸盐岩夹碎屑岩盖层建造和中生代陆相沉积,现今的逆掩冲断构造样式和构造格局基本定型于燕山期。油气藏的形成经历了早、晚两期,早期形成于印支运动主幕,燕山运动主幕遭到破坏,部分经重新分配后形成次生气藏;晚期形成于燕山运动主幕以后,属原生油气藏。涟源凹陷中部褶断带的紧闭背斜是寻找次生气藏的首选区域,而宽缓向斜中的隐伏隆起则是寻找晚期原生油气藏的靶区。     

论层序地层学与含油气系统在油气勘探中的联系——以鄂尔多斯中生代盆地为例

虽然层序地层学与含油气系统理论的各自研究对象和研究方法不同，但由于层序地层学研究对象(沉积岩)是含油气系统研究对象(油气)的载体，二者可以由含油气盆地分析有机的结合起来。层序地层分析包含了对含油气系统的地质要素及成藏作用载体的分析，因而沉积层序的组成单元与含油气系统的地质要素有必然的联系：在一个沉积盆地的数个沉积层序中，成熟烃源岩往往是地史中具一定埋深、分布广、厚度大、有机质含量高的凝缩层，这个凝缩层往往是一个构造超层序的最大海(湖)泛面；储集岩往往是成熟烃源岩之上层序的低水位体系域或紧邻成熟烃源岩的高水位体系域；有效盖层为储集岩之上层序的水进体系域及凝缩层；成熟烃源岩之上的沉积层序为上覆岩层；低水位体系域储集岩有可能沿上倾方向尖灭，被层序界面及其上层序的水进体系域岩性圈闭；除构造裂缝外，低水位体系域下切谷可作为油气向上运移通道；一个含油气系统往往跨越不同的沉积层序甚至构造超层序。     

In-situ Formation of Light-Absorbing Organic Matter in Cloud Water

Current climate models seem to underestimate the flux of solar energy absorbed by the global troposphere. All of these models are constrained with the assumption that cloud droplets consist of pure water. Here we demonstrate in a simple laboratory experiment that aromatic hydroxy-acids which are found in continental fine aerosol can react with hydroxyl radicals under typical conditions prevalent in cloud water influenced by biomass burning. The reactions yield colored organic species which do absorb solar radiation. We also suggest that the products of such reactions may be humic-like substances whose presence in continental aerosol has been confirmed but their source mechanisms are still much sought after. We also attempt to give a first order estimate of the enhancement of water absorption at a visible wavelength under atmospheric conditions.     

临兴上古生界致密储层裂缝发育特征及对致密气富集影响

临兴区块上古生界储集层为致密砂岩，裂缝发育特征及对致密气富集影响尚不清楚，一定程度上制约了甜点区预测。 根据岩心、露头、薄片及测井资料，分析了研究区裂缝发育特征，探讨了裂缝对致密砂岩气富集的影响。临兴区块上古生界主 要发育高角度缝，其次为中低角度缝及水平缝，微观上根据裂缝与矿物颗粒的相对位置关系，可识别出粒内缝、粒缘缝和穿粒 缝，其中粒缘缝最为发育。受塑性泥岩阻挡，裂缝垂向延伸较差，一般延伸1~2 m后消失于泥岩层中，受燕山期北西—南东向 地应力影响，裂缝走向多为北东—南西向，裂缝密度一般2~5条/ｍ。裂缝可改善储集空间、提高油气充注效率，储层裂缝发育 区渗透率可增大1~2个数量级，含气饱和度高，此外，研究区裂缝是油气垂向运移的有效通道，影响着石盒子组及石千峰组致 密气的富集，在后期的勘探开发过程中应充分寻找裂缝发育区，并通过进一步压裂获得高产。     

Organic pollutants associated with macromolecular soil organic matter: Mode of binding

A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.     

吐哈盆地及二连盆地侏罗系煤微类脂组分的共聚焦激光扫描显微镜（CLSM）研究及油气意义

吐哈盆地产出有比较丰富的侏罗系煤成油气田，本文用共聚焦激光扫描显微镜和热解分析等手段研究了煤中类脂组及微类脂组的类型、含量、分布与煤成烃性能和产出的关系。观察分析结果表明：在一般煤岩组分观测中主要含煤的西山窑组和八道湾组煤层类脂组含量很少超过１０％，但是一些煤样的热解分析中Ｓ＿１可高达５－２３ｍｇ／ｇ，Ｓ＿２可达１５０─２００ｍｇ／ｇ，ＨＩ（烃／有机碳）可高达１５０─３５０ｍｇ／ｇ生烃、含烃性能较好。进一步用共聚焦激光显微镜观测结果表明：本区一些薄层状、条带状煤层的基质镜质体和叶结构镜质体中微类脂组含量比较丰富，微区定量统计含量在３％─１８％左右。这种富含微类脂组的基质镜质体和结构镜质体在煤成油气中有重要意义，而且由于多数微类脂体在煤中常成点线状、似层状、充填状、网络状分布，可能有利于煤成油气的运移和聚集。     

沉积盆地流体—岩石相互作用研究的现状

沉积盆地流体－岩石相互作用研究主要是通过实验地球化学和岩石学，地球化学模拟方法开展的，综述了这一领域的研究现状，主要包括有机酸来源和分布及期 对矿物稳定性的影响，地层水成因与演化、烃类与岩石间的氧化还原反应、以及储层润湿性的变化等，并展望了其 发展趋势。     

The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks

The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion pressure during the high evolution stage. Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”.     

Evolution model and formation mechanism of bio-thermocatalytic transitional zone gas

As a new genetic type of natural gas exploration area, the bio-thermocatalytic transitional zone gas (BTTZG) has been highly stressed by geologists both at home and abroad. Systematic study on the generation mechanism of hydrocarbon at the transitional zone is presented. Based on simulating experiments and geochemistry analysis of the source rock with lower evolution, a hydrocarbon-forming model at the transitional zone has been established. The mechanism is proposed that under the condition of low temperature and pressure combining with extremely active structural stress and clay mineral catalysis, BTTZG is formed by de-group of soluble organic matter and polarized compositions through orthocarbon ion as well as by condensation polymerization of aromatic ring-rich insoluble organic matter. This mechanism controls the formation of BTTZG, and furthermore, BTTZG is the product of superimposition and interaction of all the factors mentioned above.     

塔里木盆地卫星重力异常与油气资源的相关性研究

利用中国地区３６０阶局部重力场模型ＩＧＧ９３Ｅ，计算出不同阶窗的卫星重力异常，然后利用Ｍｏｌｏｄｅｎｓｋｙ单层密度积分方程将卫星重力转化为分层面密度异常，结合其他地球物理资料，分析并探讨了塔里木盆地油气资源与卫星重力异常的相关性。研究表明：塔里木盆地油气资源分布与１０１－１８０阶卫星分同密度异常图中负密度异常带关系密切。而１８１－３６０阶卫重分层面异常图则对盆地内生油、储油的坳陷、隆起等构造有较９