咸水滴灌林地风沙土中微生物群落代谢特征

选择Biolog技术方法,利用方差分析和主成分分析研究了不同矿化度水滴灌下塔里木沙漠公路防护林地土壤微生物的代谢活性。结果表明：随着培养时间的推移,微生物利用单一碳源的颜色平均变化率（AWCD）呈现升高趋势。培养48 h内小于0.5,处于缓慢增长期;48 h后进入对数增长期;216 h后进入稳定期;衰亡期不明显。随着滴灌水矿化度增大,AWCD值明显降低,这种差异主要由土壤微生物对胺类、酚类化合物、碳水化合物利用的差异所致。土壤微生物群落利用碳源活性的垂直差异明显,70~100 cm土层是AWCD值最高的区域,表层0~5 cm最小。AWCD值与土壤有机质、全氮、全磷、全钾、速效钾、速效磷的含量、pH值、阳离子交换量、容重的正相关系数均大于0.85。因此,土壤微生物利用碳源的代谢活性差异主要由土壤化学性质所致,土壤全量养分和酸碱度是主要驱动因子。胺类、酚类化合物、碳水化合物是区分不同矿化度水滴灌下土壤微生物群落生态功能的敏感碳源。     

Air masses and aerosols chemical components in the free troposphere at the subtropical northeast atlantic region

The dynamics and the aerosol chemistry of the air masses reaching the free troposphere of the subtropical Northeast Atlantic region during the period 1995–98 have been studied. Seven days backward trajectories were calculated daily with HYSPLIT-4 model for Izaña Global Atmospheric Watch (GAW) Observatory (28.3^°N 16.5^°W, 2367 m a.s.l.). These back-trajectories were classified by means of a k-means clustering strategy. The daily air masses have been coded using 16 variables to detect the aerosol load of each one of them. Four clusters were found: Cluster 1, representative of Atlantic oceanic middle troposphere air masses, (OMT), has an average frequency of occurrence of 50.6%. Cluster 2, which includes air masses originated in the African continent (AfD), has been recorded in a 19.8% of time. Cluster 3 represents a mixture at least of two of the next sources: Europe, Africa and Ocean, (EAM), with a frequency of 12.7%. Finally, Cluster 4 includes air masses with a high load of maritime aerosols, (MaA), and it has been detected in a 16.9%. An analysis of four aerosol components: NO₃ ^?, NH₄ ⁺, non-sea-salt-SO₄ ^2?, and mineral dust and its relation with the origin and transport of the air masses have been done. The highest quantities of mineral dust and nss-SO₄ ^2? are linked with African air masses with a mean value of 86.5 and 1.9 μg/m³ respectively. Whereas the highest levels of NO₃ ^?, 1.0 μg/m³, and NH₄ ⁺, 0.4 μg/m³, were obtained for AfD and EAM. The lowest levels were associated with OMT and MaA air masses types: 12.7, 0.6, 0.2, and 0.5 μg/m³ for dust, NO₃ ^?, NH₄ ⁺, and nss-SO₄ ^2? in average for the four studied years. However, it is remarkable that the values of the median for dust are 2.2 and 3.5 μg/m³ in clusters MaA and OMT respectively. Using non-parametric statistical tests the distributions of concentrations in each cluster by year have been compared in order to detect similarities. The results show that the aerosol loads of OMT and MaA air masses are quite similar and the same occurs for AfD and EAM air masses. However, the correlation analysis between the levels of anions and ammonium evidenced important differences among the air mass types. In AfD air masses is clear a low correlation between levels of nss-SO₄ ^2? and NH₄ ⁺ (r ² = 0.08) suggesting that the sulfate speciation was dominated by sulfate species others than ammonium sulfate, such as calcium sulfate. CaSO₄ ?2H₂O (gypsum) is mainly present in the coarse mode, where the radiative effects of sulfate are less important that in the accumulative mode. For OMT air masses is noticeable an important increasing on the correlation between the levels of anions and those of NH₄ ⁺ for the two last years of the study period (1997–1998, r ² = 0.61 –0.85%) with respect to the first ones (1995–1996, r ² = 0.25–0.49%), coinciding with the second strongest ENSO (El Niño Southern Oscillation) event recorded. This behavior indicates a change in the speciation of the aerosol component.     

A Study on Sulfate Optical Properties and Direct Radiative Forcing Using LASG-IAP General Circulation Model

The direct radiative forcing(DRF) of sulfate aerosols depends highly on the atmospheric sulfate loading and the meteorology,both of which undergo strong regional and seasonal variations.Because the optical properties of sulfate aerosols are also sensitive to atmospheric relative humidity,in this study we first examine the scheme for optical properties that considers hydroscopic growth.Next,we investigate the seasonal and regional distributions of sulfate DRF using the sulfate loading simulated from NCAR CAM-Chem together with the meteorology modeled from a spectral atmospheric general circulation model(AGCM) developed by LASG-IAP.The global annual-mean sulfate loading of 3.44 mg m 2 is calculated to yield the DRF of 1.03 and 0.57 W m 2 for clear-sky and all-sky conditions,respectively.However,much larger values occur on regional bases.For example,the maximum all-sky sulfate DRF over Europe,East Asia,and North America can be up to 4.0 W m 2.The strongest all-sky sulfate DRF occurs in the Northern Hemispheric July,with a hemispheric average of 1.26 W m 2.The study results also indicate that the regional DRF are strongly affected by cloud and relative humidity,which vary considerably among the regions during different seasons.This certainly raises the issue that the biases in model-simulated regional meteorology can introduce biases into the sulfate DRF.Hence,the model processes associated with atmospheric humidity and cloud physics should be modified in great depth to improve the simulations of the LASG-IAP AGCM and to reduce the uncertainty of sulfate direct effects on global and regional climate in these simulations.     

Biological Processes Responsible for Travertine Deposition: A Review and Future Prospect

The investigation of biological processes responsible for travertine deposition allows us to better understand the travertine petrographic and geochemical signatures as proxies of climatic and environmental change. This paper reviewed the organisms associated with travertines, the biotic micro-fabrics formed within travertines, the biological processes associated with travertine precipitation and their controls on travertine geochemical properties. Prospects of the future research on biological processes responsible for travertine precipitation were provided. Bacteria, algae and mosses are the most important organisms that involve in the precipitation of travertines. The growth of these organisms leads to the formation of a range of various porosity, crystal fabrics and lamination within travertines. Three main biological processes responsible for travertine deposition can be classified, including \mathrm{①} a process of aquatic plant growth generating a turbulent condition and consequent CO₂ evasion, \mathrm{②} a metabolic (mainly photosynthetic) process mediating carbonate precipitation and \mathrm{③} a ‘surface-control’ process influencing nucleation and crystal growth. These processes play an important role in the migration and transformation of elements in travertine-depositing system and thus determine the properties of water chemistry and geochemistry of carbonate deposits. Travertine deposits have great potential to be valuable records for the geobiological study. Further investigation is required to simultaneously track biotic and abiotic interactions in modern travertine-depositing environments and quantify the contribution of these two processes and apply the results to accurately interpret travertine records.     

河南省主要城市浅层地温能特征及开发利用建议

河南省浅层地温能资源具有分布广泛、资源量丰富、开发利用方便等特点,发展前景广阔。通过对河南省主要城市的地质、水文地质条件和岩土体结构特征等浅层地温能赋存特征的分析,采用数理统计和对比分析等综合研究的方法,对比研究了不同地貌类型城市200m以浅的岩土体热物性特征、浅层地温场分布特征和岩土热响应特征等的异同及其分布与变化规律。结果显示:河南省主要城市浅层地温能的赋存层位主要为第四系及新近系上部的各类松散堆积物,这些松散的堆积物和储存于其孔隙内的地下水为浅层地温能的载体;岩土导热系数会随着孔隙率的增加而减小,随岩性颗粒变粗而增大;城市地层综合导热系数和换热能力与地下水径流条件呈正相关;位于盆地和山前地带水文地质条件优越的城市或地段,浅层地温能开发利用宜采用地下水换热方式,松散堆积物厚度较大且以细粒相沉积为主的城市或地段,宜采用竖直地埋管换热方式。     

秋免耕对坝上地区农田风蚀及土壤理化性质的影响

秋免耕是中国北方风蚀区农田保护性耕作的主要措施,对土壤风蚀的抑制作用已得到普遍验证,但对土壤性质的影响还缺乏足够认识,是否具有保墒作用还存在争议.以地处北方农牧交错带的河北坝上地区康保县作为典型研究区,采用野外调查取样和室内实验分析手段,通过比较秋免耕地与邻近秋翻耕地风蚀前后表层土壤理化性质变化的差异,研究秋免耕对土壤...     

四硼酸铯溶液的Raman光谱和物化性质研究

由摩尔比为1∶2的Cs2CO3和H3BO3反应得到四硼酸铯样品,用FT-IR和Raman等方法对其溶液结构进行表征并分析其中的阴离子类型。同时测定了四硼酸铯溶液在298.15 K和333.15 K下的密度、电导及p H,通过298.15 K下的pH测量值和相关硼酸盐平衡常数,计算298.15 K下四硼酸铯溶液的化学物种分布,并对其相互转换反应进行推测。研究表明,298.15 K下四硼酸铯溶液中存在的主要物种有B(OH)4-、B(OH)3、B3O3(OH)4-、B3O3(OH)52-和B4O5(OH)42-,与Raman光谱所得结果基本一致。     

Thermodynamic mixing properties of olivine derived from lattice vibrations

We use a lattice vibrational technique to derive thermophysical and thermochemical properties of fayalite, Fe₂SiO₄. This semi-empirical technique is based on an extension of Kieffer’s model to incorporate details of the phonon spectrum. It includes treatment of intrinsic anharmonicity and electronic effects based on crystal field theory. We extend it to predict thermodynamic mixing properties of olivine (Mg,Fe)₂SiO₄ solid solutions by using results of our previous work on the system MgO–SiO₂. Achieving this requires a relation between phonon frequency and composition and a composition relation for the energy of the static lattice. Directed by experimental Raman spectroscopic data for specific optic modes in magnesium–iron solid solutions of olivine and pyroxene we use an empirical relation for the composition dependence for phonon frequencies. We show that lattice vibrations have a large effect on the excess entropy and that the static lattice contribution and lattice vibrations have a large impact on excess enthalpy and excess Gibbs energy. Our model indicates that compositional effects in electronic and magnetic properties are negligible. The compositional variation the Néel temperature has a large impact on excess heat capacity for temperatures below 100 K.     

锥形形状记忆合金阻尼器性能分析与试验研究

本文对一种新型形状记忆合金阻尼器——锥形形状记忆合金阻尼器的性能进行了数值分析和试验研究。基于形状记忆合金的超弹性双线型本构模型,利用非线性有限元方法分析了锥形形状记忆合金阻尼器的滞回性能,并且用大型能用程序ANSYS进行了验证,得出锥形形状记忆合金阻尼器的滞回模型可简化为分段线性滞回模型,试验包括形状记忆合金丝的本构试验、疲劳试验阳阻尼器的性能试验．试验结果与数值分析结果基本吻合,形状记忆合金表现出良好的超弹性。     

高温冻结粉土力学特性试验研究

为了探讨高温冻结粉土的力学特性,进行了一系列常规三轴压缩和三轴压缩加卸载试验。结果表明：（1）随着围压的增大,应力应变曲线先表现为应变软化,后应变硬化,最后又应变软化。（2）体积应变曲线均表现为先体缩后体胀,且围压越大,体胀越弱。（3）通过引入改进的双曲线模型,能较好地模拟应变软化和硬化特性。在q-p平面内建立了一个新的强度准则,并利用修正Mohr-Coulomb屈服准则,探讨了黏聚力c和内摩擦角φ的变化规律。根据试验结果,确定了不同围压及不同加卸载循环次数下高温冻结粉土的回弹模量及其损伤变化规律。最后,建立了塑性体积变形和塑性剪切变形之间的关系式和表达式,进一步探讨了高温冻结粉土的剪胀特性。