斑岩-浅成低温热液型Cu-Au矿H2O-Cl-S流体性质和演化方式对成矿的制约

斑岩—浅成低温热液型Cu—Au成矿流体最具代表性的是H2O—Cl—S流体。流体的性质强烈控制着Cu、Au的成矿行为,包括溶解性、迁移形式和气—液分配。流体的氧逸度和流体中Cl、S物种相对含量决定金属在流体中的溶解形式,高氧逸度的高温高盐度流体中Cu、Au主要和Cl络合,S-3也可能是促进Au溶解的重要S物种形式。而过量的S有利于Cu、Au等元素以含S离子络合物进入液相流体,与含S中性络合物配分进入气相流体并迁移Au至浅成低温热液环境形成矿床。岩浆需要经历充分的分异,出溶成分和性质有利于金属迁移的流体,形成高品位的斑岩型Cu、Au矿体;上覆叠加浅成低温热液型Au矿体可能需要初始的成矿流体状态进入NaCl—H2O的超临界区、有效的演化方式、良好的流体缓冲环境和有利的Au沉淀场所。相分离和流体—流体反应是沉淀斑岩—浅成低温热液型Cu—Au矿体最重要的流体演化方式。气相流体具有独特的流体性质和演化方式,可能成为十分重要的成矿流体。     

低频循环荷载下盐岩轴向蠕变的Burgers模型分析

为了研究盐岩在低频循环荷载作用下的蠕变特性,采用恒轴压、循环围压的应力加载方式对盐岩开展了低频循环荷载蠕变试验。试验结果显示,当蠕变时间较短时,盐岩轴向蠕变曲线近似为平滑曲线,波动性不大;当时间增加到一定程度以后,盐岩变形随围压变化而发生明显的波动。总体来看,循环荷载下盐岩轴向蠕变曲线与Burgers模型蠕变曲线较为相似。将Burgers模型分解为Maxwell模型和Kelvin模型,忽略材料的疲劳效应,分别推导了恒轴压、循环围压应力加载方式下Maxwell模型和Kelvin模型的轴向蠕变方程,分析了荷载循环周期对模型蠕变性的影响规律;将循环荷载下Maxwell模型和Kelvin模型的轴向蠕变方程进行叠加,得到了循环荷载下Burgers模型的轴向蠕变方程,并利用盐岩蠕变试验结果对其合理性进行了验证。结果表明:拟合曲线和试验曲线吻合良好,该模型能够较好地反映盐岩在循环荷载作用下的蠕变特性和荷载变化对盐岩蠕变性的重要影响,特别是能够反映出不同荷载循环周期下盐岩变形随荷载变化而发生的明显的波动现象。     

内蒙古中部地区岩矿石磁化率特征

为了解内蒙古中部的锡林浩特、巴林左旗等地区岩矿石磁性特征,更好地对该地区的航磁异常进行综合解释,使用航遥中心研制的ZH-1磁化率仪,于2009~2011年间先后四次在该地区进行了野外岩矿石磁化率实测。并在统计、分析实测磁化率数据的基础上,研究了该地区岩矿石磁化率分布情况,分别叙述了区内沉积岩、侵入岩、火山岩、变质岩、矿石及围岩等各种类型岩矿石的磁化率特征,对岩矿石磁化率与航磁、矿产间的联系进行探讨,为磁法勘查解释、地质找矿提供了重要依据。     

青藏高原东缘玛曲沙化高寒草地土壤理化性质北大核心CSCD

沙漠化是青藏高原东缘高寒草地退化的重要指征,土壤理化性质是反映草地沙化过程的重要特征参数。以青藏高原东缘玛曲县为例,分析天然草地和轻度、中度、重度、极重度沙化草地土壤粒度组成、温湿度、有机碳和养分等因子的差异特征,旨在阐明高寒草地沙化过程中土壤理化性质的变化。结果表明:草地土壤黏土和粉沙含量随着沙化的发展显著减小,而沙颗粒含量(细沙和中沙)随着沙化程度的增加而增大;5—8月生长季,重度沙化土壤相比轻度沙化土壤温度明显升高,土壤含水量明显降低;随着沙化程度的增加,土壤有机碳含量显著降低,轻度沙化减少50%以上,中度至极重度沙化草地减少91%—99%;土壤全氮(TN)、碱解氮(AN)、全磷(TP)、有效磷(AP)等含量在轻度以上沙化草地中显著降低,而全钾(TK)变化不明显,速效钾(AK)仅在中度至极重度沙化草地中含量降低。高寒草地沙化进程中,随着植被盖度的不断降低,表层细颗粒物逐渐风蚀、土壤养分流失,粗颗粒物质保留下来,土壤含水量降低,在风的分选作用下不断堆积形成流动性沙丘。     

青藏高原东北部观赏地被植物马蔺根系固土护坡效应研究

为了进一步丰富青藏高原东北部地区植被护坡工程植物选择,推动区内植被护坡工程实用性和观赏性兼顾发展。该项研究以青藏高原东北部观赏地被植物马蔺为研究对象,以青海省大通县朔北藏族乡至东峡镇之间区域为研究区,在野外植物分布特征和生长特征调查的基础上,结合单根拉伸试验和重塑根-土复合体三轴压缩试验,定量评价了野生马蔺植株和根系生长特征、单根抗拉特性以及根系对土体抗剪强度的增强效应。试验结果表明：马蔺主要分布在研究区内洪积扇、坡积裙和河漫滩等地貌单元,立地条件包括上述地貌单元内的林下坡地、田间、道旁、湿地、荒地等;通过选取两处试验区开展调查可知,马蔺平均株高、冠幅和植株密度分别为75.22±11.40 cm、106.09±25.62 cm和1.51±0.55 株/m2;马蔺标准株根系分布深度可达50 cm,主要分布在0~30 cm深度范围内,根幅约40~50 cm;马蔺根径为0.20～0.70 mm,单根抗拉力、抗拉强度和延伸率平均值分别为7.94±2.91 N,46.30± 11.06 MPa和54.17%±17.08%,随着根径的增大,单根抗拉力和单根抗拉强度分别呈幂函数增大和幂函数降低关系,单根极限延伸率随着根径的增大呈逐渐增大变化趋势,但二者之间未表现出相对显著性的关系;马蔺根系对土体黏聚力和内摩擦角均有增强作用,可分别显著增强0~30 cm和0~10 cm深度范围内土体黏聚力和内摩擦角,且对土体黏聚力的增强作用较为显著。该项研究成果对于选用观赏地被植物马蔺进行研究区坡面水土流失、浅层滑坡等地质灾害现象的生态防护工作,具有理论研究价值和实际指导意义。     

273.15 到 308.15 K下二元体系（LiCl-H2O 和 MgCl2-H2O）和三元体系（LiCl-MgCl2-H2O）的体积性质研究

用高精度振动管在 273.15 至 308.15 K 的温度范围内以 5 K 的间隔对两个二元系统（LiCl-H2O 和 MgCl2-H2O）和三元系统（LiCl-MgCl2-H2O）的密度进行了实验测定密度计。基于 Vogel-Fulcher-Tamman (VFT) 方程,对 LiCl(aq) 和 MgCl2(aq) 密度与温度和摩尔浓度的相关方程的系数进行了参数化。 Young的理想混合规则被成功地应用于基于相关的二元解性质关联三元系统的密度。根据二元和三元体系的体积特性数据,根据 Pitzer 离子相互作用理论,得到 Pitzer 单盐参数和混合离子相互作用参数。在本工作中确定了三元体系在恒定离子强度下的混合体积 (ΔVm)。     

Meso‐scale particle modeling of concrete deterioration caused by alkali‐aggregate reaction

A meso‐scale particle model is presented to simulate the expansion of concrete subjected to alkali‐aggregate reaction (AAR) and to analyze the AAR‐induced degradation of the mechanical properties. It is the first attempt to evaluate the deterioration mechanism due to AAR using the discrete‐element method. A three‐phase meso‐scale model for concrete composed of aggregates, mortar and the interface is established with the combination of a pre‐processing approach and the particle flow code, PFC2D. A homogeneous aggregate expansion approach is applied to model the AAR expansion. Uniaxial compression tests are conducted for the AAR‐affected concrete to examine the effects on the mechanical properties. Two specimens with different aggregate sizes are analyzed to consider the effects of aggregate size on AAR. The results show that the meso‐scale particle model is valid to predict the expansion and the internal micro‐cracking patterns caused by AAR. The two different specimens exhibit similar behavior. The Young's modulus and compressive strength are significantly reduced with the increase of AAR expansion. The shape of the stress–strain curves obtained from the compression tests clearly reflects the influence of internal micro‐cracks: an increased nonlinearity before the peak loading and a more gradual softening for more severely affected specimens. Similar macroscopic failure patterns of the specimens under compression are observed in terms of diagonal macroscopic cracks splitting the specimen into several triangular pieces, whereas localized micro‐cracks forming in slightly affected specimens are different from branching and diffusing cracks in severely affected ones, demonstrating different failure mechanisms. Copyright © 2012 John Wiley & Sons, Ltd.     

Assessing the impact of the hydraulic properties of a crusted soil on overland flow modelling at the field scale

Soil surface crusts are widely reported to favour Hortonian runoff, but are not explicitly represented in most rainfall‐runoff models. The aim of this paper is to assess the impact of soil surface crusts on infiltration and runoff modelling at two spatial scales, i.e. the local scale and the plot scale. At the local scale, two separate single ring infiltration experiments are undertaken. The first is performed on the undisturbed soil, whereas the second is done after removal of the soil surface crust. The HYDRUS 2D two‐dimensional vertical infiltration model is then used in an inverse modelling approach, first to estimate the soil hydraulic properties of the crust and the subsoil, and then the effective hydraulic properties of the soil represented as a single uniform layer. The results show that the crust hydraulic conductivity is 10 times lower than that of the subsoil, thus illustrating the limiting role the crust has on infiltration. Moving up to the plot scale, a rainfall‐runoff model coupling the Richards equation to a transfer function is used to simulate Hortonian overland flow hydrographs. The previously calculated hydraulic properties are used, and a comparison is undertaken between a single‐layer and a double‐layer representation of the crusted soil. The results of the rainfall‐runoff model show that the soil hydraulic properties calculated at the local scale give acceptable results when used to model runoff at the plot scale directly, without any numerical calibration. Also, at the plot scale, no clear improvement of the results can be seen when using a double‐layer representation of the soil in comparison with a single homogeneous layer. This is due to the hydrological characteristics of Hortonian runoff, which is triggered by a rainfall intensity exceeding the saturated hydraulic conductivity of the soil surface. Consequently, the rainfall‐runoff model is more sensitive to rainfall than to the subsoil's hydrodynamic properties. Therefore, the use of a double‐layer soil model to represent runoff on a crusted soil does not seem necessary, as the increase of precision in the soil discretization is not justified by a better performance of the model. Copyright © 2005 John Wiley & Sons, Ltd.     

Laboratory Research into Permeable Reactive Barriers for Groundwater Remediation

Permeable Reactive Barriers (PRB) is a new technology for groundwater pollution remediation. Contaminants are converted into harmless by products in situ as the polluted water passes through a reactive wall. Experimental results demonstrate how reactive media can be used to remove contaminants from polluted water by laying the reactive wall across the flow direction of the water. The most comprehensively studied and applied reactive barrier type uses granulated Zero Valent Iron (ZVI) particles. In this process elemental iron provides a reducing environment which makes reductive dechlorination of chlorinated organic compounds feasible or changes redox sensitive metals, so that they are immobilized by a precipitation reaction. A reactive wall column which is made up of ZVI, sand and zeolite has shown the highest contaminant removal capacity compared to the other two which have different components. The potentials of ZVI, zeolite and Powdered Activated Carbon (PAC) to remove contaminants are due to their different physico-chemical proper-ties which make them to "sorb"metal contaminants. The results of this experiment show that PRB technology is an efficient method for the treatment of leachate-contaminated groundwater.     

LBQS类星体样品球空间功率谱分析

本文用球空间功率谱分析方法研究了ＬＢＱＳ类星体样品的成团性，讨论了ｑ０、边界效应、红移测量误差的影响，并与相关函数的结果进行了比较，认为本样品类星体是不成团的或极弱成团。