中国超基性岩变形变质作用与超微构造分析

通过野外及透射电子显微镜（ＴＥＭ）等实验研究与综合分析，认为西准噶尔、祁连山、秦岭、喜马拉雅山、阿拉善和汉诺坝等地区的蛇绿岩型、绿岩型、暗色岩型超基性岩及其主要造岩矿物——橄榄石的结构类型、形成环境、变形、变质作用、位错组态、位错密度、布格氏矢量（ｂ）、滑移系及流动应力值（σ１—σ３）具有一定的共同性与差异性。根据橄榄石变形实验资料分析，有的相当于上地幔条件下高温蠕变阶段所形成，有的则属于进入地壳后低温流变的产物。     

橄榄石位错构造及其上地幔流变学意义——以河北省大麻坪二辉橄榄岩为例

本文运用氧化缀饰法对大麻坪幔源包体的橄榄石位错进行了研究,其主要位错类型包括:[100]、[001]位错壁、亚颗粒构造、(010)位错滑动环、位错网、交叉滑移位错、{110}滑动条带构造。根据稳定态亚颗粒统计,其数值为15.53—25.72μm,平均为20.65μm,位错密度为20×10~6—90×10~6cm~(-2),相应的差异应力分别为48.4—70.8MPa和44—92MPa。     

New Olivine Reference Material for In Situ Microanalysis

A new olivine reference material – MongOL Sh11‐2 – for in situ analysis has been prepared from the central portion of a large (20 × 20 × 10 cm) mantle peridotite xenolith from a ~ 0.5 My old basaltic breccia at Shavaryn‐Tsaram, Tariat region, central Mongolia. The xenolith is a fertile mantle lherzolite with minimal signs of alteration. Approximately 10 g of 0.5–2 mm gem quality olivine fragments were separated under binocular microscope and analysed by EPMA, LA‐ICP‐MS, SIMS and bulk analytical methods (ID‐ICP‐MS for Mg and Fe, XRF, ICP‐MS) for major, minor and trace elements at six institutions world‐wide. The results show that the olivine fragments are sufficiently homogeneous with respect to major (Mg, Fe, Si), minor and trace elements. Significant inhomogeneity was revealed only for phosphorus (homogeneity index of 12.4), whereas Li, Na, Al, Sc, Ti and Cr show minor inhomogeneity (homogeneity index of 1–2). The presence of some mineral and fluid‐melt micro‐inclusions may be responsible for the inconsistency in mass fractions obtained by in situ and bulk analytical methods for Al, Cu, Sr, Zr, Ga, Dy and Ho. Here we report reference and information values for twenty‐seven major, minor and trace elements.     

Ocean-Continent Subduction within the Paleotethyan Archiopeligic Ocean from Mineralogical Evidence of Muztag Ophiolite, Eastern Kunlun Mountain, China

TheMuztagophioliteisdistributeddiscontinu ouslyalongthewest easttrendingMuztag Jingyuhu faultzoneintheEasternKunlunMountainofXin jiangUygurAutonomousRegion(Fig.1).The mountainiscomposedoftwoprincipalunitsofmeta morphicperidotitesandcumulates(Molnaretal.,1…     

云南金宝山含铂钯超镁铁质侵入体中铬铁矿的成因研究

位于扬子地台西缘的金宝山岩体赋存我国最大的独立铂族元素矿床，岩体为似层状产出的小型超镁铁岩，在时间和空间上与晚二叠纪（260Ma）峨眉山大火成岩省相关。该岩体由单辉橄榄岩、辉橄岩及橄辉岩、辉石岩异离体组成。铬铁矿以副矿物形式出现，从形态上可以分为三类：包嵌于橄榄石中的自形铬铁矿、以自形或半自形体存在于辉石中铬铁矿以及环绕结构铬铁矿。其中环绕结构铬铁矿外壁浑圆，内为棱角状，其中心为橄榄石、辉石。本文在薄片观察的基础上，结合电子探针研究，认为包嵌于橄榄石中的自形铬铁矿是在岩浆早期深部岩浆房中结晶形成的；存在于辉石中的铬铁矿则是岩浆进一步结晶演化的结果，主要为就地结晶的产物；在岩体形成的过程中，作为岩体赋存空间的堆晶相与后续岩浆持续反应，使铬铁矿不断聚集和生长，最终形成了环绕橄榄石晶体的形态。铬铁矿的生成模式进一步说明了金宝山侵入体为一岩浆通道，并且经历深部结晶分异演化。     

含水对富铁橄榄石流变性的影响

橄榄石是下地壳上地幔最丰富的造岩矿物,橄榄石集合体的高温高压流变性对地幔动力学过程有着很大的影响。以往对橄榄石单晶和集合体进行过的流变性实验研究,涉及了温度、压力、氧逸度、含铁量以及含水等因素的影响,本文研究了含水对富铁橄榄石集合体流变性能的影响,首先,利用高精度 Paterson 气体介质变形装置对含水富铁橄榄石集合体(Mg_(0.9),Fe_(0.1))_2SiO_4、(Mg_(0.7),Fe_(0.3))_2SiO_4和(Mg_(0.5),Fe_(0.5))_2SiO_4进行了高温三轴压缩蠕变试验,变形试验条件为:温度1323～1473K,围压300MPa,差应力10～300MPa,应变率10~(-7)～10~(-4)s~(-1),每个试件的最大变形量为20%。利用三维非线性拟合方法对蠕变试验数据进行分析,结果表明,含水富铁橄榄石集合体的微观变形机制为扩散域和位错域,对三种铁含量,扩散域的应力指数为1。位错蠕变域中,Fo_(50)应力指教为3.8,活化能为444kJ/mol;Fo_(70)应力指数为3.7,活化能为479kJ/mol,Fo_(90)应力指数为3.6,活化能为514kJ/mol。将实验结果与不含水富铁橄榄石集合体的强度进行对比,发现含水使富铁橄榄石的强度明显下降,舍铁量相同时,含水橄榄石集合体的流变强度比干燥时小至少一个数量级。从而得到了含水对含铁量不同的橄榄石集合体粘性(强度)影响的初步试验结果。     

新疆东天山土墩基性-超基性杂岩体橄榄石成分特征及其成因意义

橄榄石通常是玄武质岩浆最早结晶出的矿物之一,其化学成分可以很好地反演母岩浆成分、岩浆结晶分异、硫化物熔离等成岩及成矿信息。本文以土墩镁铁质-超镁铁质杂岩体为研究对象,采用电子探针对岩体中的橄榄石矿物颗粒进行化学成分测试。利用橄榄石的Fo值和其中Ni含量,计算得到土墩杂岩体母岩浆中Mg O含量约为12.95%,是一种富镁的玄武质岩浆。同时,定量模拟结果表明,土墩杂岩体母岩浆中硫化物熔离几乎与橄榄石结晶作用同时进行,早阶段由橄榄石结晶(分离结晶程度约2%)而导致硫化物的熔离程度为0.2%。随后,橄榄石分离结晶程度在6%~7%时,硫化物熔体的熔离程度仅为0.01%。这些表明土墩杂岩体发生过一定程度的硫化物熔离,但成矿前景不是很好。此外,部分数据显示出Ni-Fo的负相关性,表明少许富铁橄榄石和晶间硫化物熔浆发生了Fe-Ni物质交换反应,这对橄榄石的成分有重要影响。     

The Occurrence of Forsterite and Highly Oxidizing Conditions in Basaltic Lavas from Stromboli Volcano, Italy

We report the occurrence of unusual, high-magnesium (Fo₉₆) olivinephenocrysts in a basaltic lava and an ejected lithic block fromthe Upper Vancori period (13 ka) and the recent activity (2002–2003)of Stromboli volcano, Italy. The samples that contain this distinctivemineral chemistry are a shoshonitic basalt and a basaltic andesitewith anomalous bulk-rock chemical characteristics in which theiron is highly oxidized (6–8 wt % Fe₂O₃ and <1 wt %FeO). In other respects these samples are similar to the majorityof Stromboli basalts, characterized by the coexistence of olivine,clinopyroxene, plagioclase and Fe–Ti oxides as phenocrysts,and clinopyroxene, plagioclase and Fe–Ti oxides in thegroundmass. In the high-magnesium olivine samples, Fe–Tioxides (pseudobrookite) typically occur as symplectitic intergrowthswith the olivine phenocrysts, indicating simultaneous growthof the two phases. We propose, as a paragenetic model, thatthe Fo₉₆ olivine phenocrysts crystallized from a highly oxidizedbasaltic magma in which most of the iron was in the ferric state;hence, only magnesium was available to form olivine. The highlyoxidized state of the magma reflects sudden degassing of volatilephases associated with instantaneous, irreversible, transientdegassing of the magma chamber; this is postulated to occurduring periods of sudden decompression induced by fracturingof the volcanic edifice associated with paroxysmic activityand edifice collapse. KEY WORDS: Stromboli; Mg-rich olivine; oxygen fugacity; redox state of magmas; irreversible processes     

湘西通道地区新元古代长界橄榄辉石岩中单斜辉石矿物学特征及其板内裂谷成因论证

湘西通道地区长界橄榄辉石岩主要组成矿物为单斜辉石、橄榄石和斜长石,还具有少量的Ti—Fe氧化物。本文利用电子探针对江南造山带西段湘西通道地区长界橄榄辉石岩单斜辉石进行了详细的矿物学研究,研究结果表明单斜辉石属于顽透辉石和普通辉石。长界橄榄辉石岩单斜辉石较富镁而贫铁,并且还具有高硅、贫碱、低钙的特征,其母岩浆属于拉斑玄武系列。单斜辉石温压计算结果显示,橄榄辉石岩的形成温度为1260～1383℃,压力为1.5～2.6GPa,深度为50～86km,平均深度为73km。整体来看,长界橄榄辉石岩形成的温度基本与软流圈地幔的温度(1280～1350℃)相当,其形成深度为约73km的地幔深处,且在这种温压条件下,软流圈地幔可以发生减压熔融。单斜辉石的成分特征显示示长界橄榄辉石岩是板内拉斑玄武岩,指示其构造背景为裂谷环境。另外,单斜辉石具低的Al_2O_3(0.02%～5.51%)、TiO_2(0～0.46%)和Na_2O(0.01%～1.44%)的特征,这可能是单斜辉石寄主岩石岩浆源区受到俯冲熔体/流体的交代改造作用所导致。结合作者和前人的研究结果,我们推测长界橄榄辉石岩源区为软流圈地幔,其形成可能与裂谷作用导致软流圈物质上涌并发生熔融有关,且在形成长界橄榄辉石岩之前,软流圈地幔已经遭受过俯冲熔体/流体的交代改造作用。