Tidal time-scale variation in nutrient flux across the sediment–water interface of an estuarine tidal flat

We determined the range of the tidal variations in nutrient flux across the sediment–water interface and elucidated mechanisms of the flux variation in two estuarine intertidal flats (one sand, one mud) in northeastern Japan. Nutrient flux was measured using in situ light and dark chambers, which were incubated for 2 h, 2–6 times per day. Results showed that nutrient concentration in overlying water varied by tide and was also affected by sewage-treated water inflow. The nutrient fluxes responded quickly to the tidal variation in overlying water chemistry and the range of the variation in flux was as large as the seasonal-scale variation reported in previous studies. In the sand flat, salinity increase likely enhanced benthos respiration and led to increases in both O₂ consumption and PO₄³⁻ regeneration under low illumination, while benthic microalgae were likely to actively generate O₂, uptake PO₄³⁻ and suppress PO₄³⁻ release under high illumination (>900 μmol photons m⁻² s⁻¹). Also in the mud flat, PO₄³⁻ flux was related with O₂ flux, although the range of temporal variation in PO₄³⁻ flux was small. In both the flats, NH₄⁺ flux was always governed by NH₄⁺ concentration in the overlying water; either an increase in NH₄⁺ uptake or a decrease in NH₄⁺ release was observed as the NH₄⁺ concentration rose due to inflow of river water or input of sewage-treated water. Although NO₃⁻ tended to be released in both tidal flats when low NO₃⁻ concentration seawater dominated, their relationship was likely to be weakened under conditions of low oxygen consumption and suppressed denitrification. It is likely that tidal variation in nutrient flux is governed more by the nutrient concentration than other factors, such as benthic biological processes, particularly in the case where nutrient concentration in the overlying water is relatively high and with wide amplitude.     

乐清湾泥蚶血细胞周期和DNA含量

用流式细胞仪测定乐清湾泥蚶血细胞DNA含量，得出组方图中只有一个峰（G0/G1），表明了乐清湾泥蚶血液不存在合成期（S）、合成后期（G2）和分裂期（M）细胞，血细胞已失去分裂功能，不存在周期现象，以小鸡血细胞做标准对照物（DNA含量以2.3pg/N)，测得乐清湾泥蚶血细胞DNA含量为3.08pg/N。     

The role of sediments in the phosphorus cycle in Lake Lugano. II. Seasonal and spatial variability of microbiological processes at the sediment-water interface

P, Fe, Mn, and S species were analyzed in water samples from the sediment-water interface collected at four seasonally different times during the course of a year at two sampling sites in the southern basin of Lake Lugano (Lago di Lugano). The results reveal the strong influence of the biogeochemical processes in the sediment on the chemical composition of the lake water above. Consumption of oxygen and nitrate under oxic to microoxic conditions in the water column as well as sequential release of reduced manganese and iron under anoxic conditions was observed as a direct or indirect consequence of microbially mediated degradation of organic matter. The seasonal pattern observed for the release and the retainment of dissolved reduced iron and manganese correlates well with the one for dissolved phosphate. Iron, manganese and phosphorus cycling are coupled tightly in these sediments. Both sediment types act as sinks for hydrogen sulfide and sulfate. An inner-sedimentary sulfur cycle is proposed to couple iron, manganese and phosphorus cycling with the degradation of organic matter. Nutrient cycling at the sediment-water interface might thus be driven by a microbially regulated electron pumping mechanism. The results contribute to a better understanding of the role of sediment processes in the lake's internal phosphorus cycle and its seasonal dynamics.     

Stochastic modeling based on deterministic formulation: An example

In the context of seismology, an example of stochastic modeling on the basis of an established deterministic formulation is presented. The advantages of this approach to modeling over those based solely on statistical fit are discussed. It is demonstrated that the result of applying this procedure is a model whose main parameter has a physical interpretation, and therefore a validation based on criteria other than statistical goodness of fit is also possible. Statistical inference together with some demonstrating examples are also included.     

Multivariate statistical analysis and environmental isotopes of Amman/Wadi Sir (B2/A7) groundwater,Yarmouk River Basin,Jordan

Multivariate statistical techniques, cluster and factor analyses were applied on the Amman/Wadi Sir groundwater chemistry, Yarmouk River basin, north Jordan. The main objective was to investigate the main processes affecting the groundwater chemical quality and its evolution. The k‐means cluster analysis yields three groups with distinct ionic concentrations. Cluster 1 comprises the vast majority of the sampled wells, and the water that belongs to this cluster can be classified as freshwater. Cluster 2 comprises only 2% of the sampled wells; it has the highest ionic concentration. The water of this cluster can be classified as brackish water. Cluster 3 involves 23% of the sampled wells, and it has total ionic concentration intermediate to that of clusters 1 and 2. Factor analysis yields a three‐factor model, which explains 76.77% of the groundwater quality variation. Factor 1 ‘salinity factor’ involves EC, Na⁺, Cl^‐, SO₄^‐2, K⁺ and Mg⁺² and reflects groundwater salinization because of overpumping. Factor 2 ‘hardness factor’ includes Ca⁺², HCO₃^‐ and the pH value and signifies soil–water/rock interaction. Factor 3 ‘nitrate factor’ involves only NO₃^‐ and points to groundwater contamination because of human activities, mainly untreated wastewater, and crops and animal cultivation in the unconfined portion of the aquifer. Factors 1 and 3 can be described as human‐induced factors, whereas factor 2 can be described as geogenic factor. Factors' scores were mapped to deduce the controlling processes on the groundwater chemistry. Stable isotope composition of ¹⁸O and ²H has revealed that the groundwater is a mixture of two water types. The radioactive isotopes tritium and ¹⁴ C were used to evaluate present day recharge to the aquifer and to estimate the groundwater age, respectively. Present day recharge to the groundwater is taking place in the unconfined portion of the aquifer as it is indicated by the measurable tritium content and low groundwater age. Copyright © 2012 John Wiley & Sons, Ltd.     

Initial impacts of a wildfire on hydrology and suspended sediment and nutrient export in California chaparral watersheds

Stream and rainfall gauging and runoff sampling were used to determine changes in hydrology and export of nutrients and suspended sediment from a June 2004 wildfire that burned 3010 ha in chaparral coastal watersheds of the Santa Ynez Mountains, California. Precipitation during water year 2005 exceeded average precipitation by 200–260%. Burned watersheds had order of magnitude higher peak discharge compared with unburned watersheds but similar annual runoff. Suspended sediment export of 181 mt ha^?1 from a burned watershed was approximately ten times greater than from unburned watersheds. Ammonium export from burned watersheds largely occurred during the first three storms and was 32 times greater than from unburned watersheds. Nitrate, dissolved organic nitrogen, and phosphate export from burned watersheds increased by 5.5, 2.8, and 2.2 times, respectively, compared with unburned chaparral watersheds. Storm runoff and peak discharge increase in burned compared with unburned sites were greatest during early season storms when enhanced runoff occurred. As the winter progressed, closely spaced storms and above average precipitation reduced the fire‐related impacts that resulted in significant increases in annual post‐fire runoff and export in other studies in southern California chaparral. Copyright © 2012 John Wiley & Sons, Ltd.     

Characterization of water quality variation in the Mekong River at Vientiane by frequent observations

To better understand the variation of water quality in the Mekong River, sampling and measurement were scheduled twice a week for about 3 years at Vientiane, followed by basic statistical analysis of the observed data. The frequent measurement revealed detailed characteristics of the water quality variation, which had not been detected by monthly observation in the previous studies. The variation in total ionic content was considered to be governed by dilution of the amount of water. Increases in turbidity could be attributed to physical effects including surface soil erosion and bed material resuspension at the time of discharge increase. Nitrogen concentrations were stably low during the low flow period and abruptly increased in May. After the annual maximum in late May, the nitrate concentration steadily decreased regardless of the remarkable rise in the discharge from mid‐July, whereas the ammonium concentration remained at a similar level until October. It was considered that the first small discernable runoff after the long dry season flushed the accumulated nitrogen in the surface soil and mobilized the nitrogen in the riverbed. The variation in phosphorus concentrations was different from that in nitrogen concentrations. During the high flow period, continual dilutions at discharge peaks and occasional large additions of phosphorus by surface runoff were suggested. Copyright © 2011 John Wiley & Sons, Ltd.     

Investigation of Lushan earthquake ionosphere VTEC anomalies based on GPS data

Vertical total electron content （VTEC） time series were obtained from 22 GPS stations near the epicenter of the Lushan earthquake. In this paper, we have adopted a sliding average method to detect and analyze anomalous VTEC associated with the earthquake. The results show that signif- icant, negative ionosphere VTEC anomalies appeared over the 5 days before the earthquake, and on the day when earthquake occurred. The maximum value of VTEC anoma- lies that exceeded the lower bound reached 20 TECU. The spatial distribution of VTEC anomalies showed a conjugate structure, which shifted to the magnetic equator, and subse- quently moved westwards.     

Spatial and temporal dynamics of soil moisture after rainfall events along a slope in Regosols of southwest China

High frequency seasonal drought in purple soils (Regosols in FAO taxonomy) of the hilly upland areas of Sichuan basin, China, is one of the key restrictive factors for crop production. In order to manage irrigation and fertilizer application in these soils effectively, the soil water content in a sloped plot with 60 cm soil depth was measured by neutron probe devices to investigate the soil moisture regime during the 1998 rainy season after various amounts of rainfall events. The results showed that variation of soil moisture along the slope positions was highest in the top soil layer during the period of sporadic rainfall that did not induce any runoff. The coefficients of variation of soil moisture at various slope positions (upper, middle, and lower) are 17·36%, 8·95%, 10·25%, 8·58%, 8·05% and 9·21% at the 10 cm, 20 cm, 30 cm, 40 cm, 50 cm and 60 cm soil depths respectively. When surface runoff occurred, the soil moisture dynamics at various positions on the plot were then very different. Soil water content decreased more rapidly on the upper slope than on the middle and lower slope positions. When both surface runoff and throughflow occurred, the soil moisture dynamics in the various layers showed a stable period (soil water content is near constant as time elapses) that lasted about 1 week. Also, the pattern of moisture dynamics is ‘decreasing–stabilization–decreasing’. Thus, irrigation and fertilization management according to the spatial and temporal features of soil moisture dynamics on sloped land can increase the water and fertilizer utilization efficacy by reducing their losses during the stable period. Copyright © 2006 John Wiley & Sons, Ltd.