Observations from aircraft, an island station, and tworesearch vessels are used to investigate the development of an elevated mixed layeror land plume over the Arabian sea during the Indian Ocean Experiment Intensive FieldPhase 1999 (INDOEX) through air mass modification. Much of the transport of aerosolsand gases occurs in this plume located above a well-mixed convective marine boundary layerwith a depth of 800–1000 m. The depth of the land plume isapproximately 2000 m with the peak ozone concentrations occurring near the centre of this land plume.Significant latitudinal variations in the concentration of ozone occur in the marineboundary layer and in the plume. Mean ozone concentrations in the land plume decreasedwith distance from the Indian coastline. 相似文献
Two kinds of feedback mechanisms in the coupling process between the atmosphere and ocean surface are identified in this paper. One is a negative feedback mechanism, which is effective in the dynamic interaction processes through momentum flux exchange. In this mechanism,the ocean extracts momentum from the atmosphere as a forcing field to generate waves, which decelerates atmospheric motions, lessening the intensity of synoptic systems. The second is a positive feedback mechanism, which is effective in the thermal interaction processes through heat flux exchange. This is a mechanism that is effective in the transport of sensible and latent heat fluxes to the atmosphere from the underlyingocean surface. As a result, the atmosphere obtains energy from the ocean, which intensifies atmospheric motions. For storm conditions typical of North Atlantic mid-latitudes, we consider these thermal and dynamical nteractions, the dominance of one over the other, and related implications for storm intensification. 相似文献
Having agreed upon a binding emissions reduction path by 2020, the EU plays a leading role in international climate policy. The EU currently pursues a dual approach through an Emissions Trading Scheme (ETS) at the EU level and also via national targets in sectors not covered by the ETS. The latter include the buildings sector, transportation, agriculture, and waste. Emissions from these sectors are mainly subject to policies at provincial and local levels. A method is presented for elaborating and implementing a long-term climate policy process up to 2030 for the regional (provincial) level. Building on regional GHG inventory data, a set of indicators for each sector is developed in order to arrive at a target path consistent with the deduced regional GHG reduction requirement. Policy measures and their implementation are then settled subsequent to this process. Quantitative regional targets are found to be a prerequisite for the formation of regional climate policy as they increase participant responsibility and commitment. A five-step process of stakeholder participation ensures effective implementation of regional climate action plans. Insights from an exemplary European region are drawn upon, and policy issues are discussed in both quantitative and institutional terms. 相似文献
A generalized X-ray scattering factor model experimental electron density distribution has been generated for the orthosilicate forsterite, using an essentially extinction and absorption free set of single crystal diffraction data recorded with intense, high energy synchrotron X-ray radiation (E=100.6 keV). A refinement of the model converged with an R(F)=0.0061. An evaluation of the bond critical point, bcp, properties of the distribution at the (3, –1) stationary points for the SiO and MgO bonded interactions, yielded values that agree typically within ~5%, on average, with theoretical values generated with quantum chemical computational strategies, using relatively robust basis sets. On the basis of this result, the modeling of the experimental distribution is considered to be adequate. As the bcp properties increase in magnitude, the MgO and SiO bonds decrease in length as calculated for a number of rock forming silicates. As asserted by Coppens (X-ray charge densities and chemical bonding. Oxford University Press, Oxford, 1997), large negative 2(rc) values, characteristic of shared interactions involving first row atoms, may not be characteristic of closed shell covalent bonded interactions involving second row Si, P and S atoms bonded to O. This study adds new evidence to the overall relatively good agreement between theoretical bcp properties generated with computational quantum strategies, on the one hand, and experimental properties generated with single crystal high energy synchrotron diffraction data on the other. The similarity of results not only provides a basis for using computational strategies for studying and modeling structures, defects and the reactivity of representative structures, but it also provides a basis for improving our understanding of the crystal chemistry of earth materials and the character of the SiO bonded interaction. 相似文献
ABSTRACTVolcaniclastic units are exposed at the base of the Puerto Blanco Formation in the Caborca region, northwestern Mexico. The lower unit reveals the presence of Early Cambrian mafic volcanism in this region. It consists of a volcano-sedimentary sequence represented by tuffaceous conglomerates, agglomerates, lapillistones, tuffs, and altered mafic volcanic flows. Petrographic analysis classified the volcanic clasts as albite-sphene-calcite-actinolite granofels, with a moderate to intense hydrothermal alteration, precisely characterized by EPMA analysis. Albite-actinolite geothermometry indicates temperatures from 400 to 500°C, suggesting metamorphic conditions in the upper temperature greenschist facies. Geochemistry analysis shows a high TiO2 basic–ultrabasic volcanism that originated the volcanic clasts. Rock protoliths were studied using immobile trace elements, which classified them as OIB-type alkaline basalts with the characteristic spider hump-shaped pattern, situated in an anorogenic intracontinental tectonic setting with enriched mantle signatures. 40Ar/39Ar geochronology shows metamorphic ages of 52.58 ± 2.0 and 91.67 ± 0.55 Ma, consistent with the emplacement of Laramidic granitoids identified in the region. Possible correlations of this alkaline volcanism include the Southern Oklahoma Aulacogen and the late stages of the rifting of north western Laurentia represented in western United States. 相似文献