Illite/smectite transformation in detrital glaucony during burial diagenesis of sandstone: A study from Siri Canyon – Danish North Sea

Detrital glaucony in the Palaeogene glauconitic sandstones in Siri Canyon, Danish North Sea, has been analysed from 15 exploration wells by X‐ray diffraction, electron microprobe and scanning electron microscopy. These sandstones consist of mixed‐layer illite/smectite and have a large variability in chemical composition and structure. In the most shallow wells (ca 1700 m), the glaucony is rich in Fe and consists of mixed‐layer illite/smectite with random‐interstratification (R = 0). In the depth interval from 1700 to 2000 m, the composition changes as Si is incorporated. The structure changes to ordered R = 1. Further increase in burial leads to the loss of Fe. Ordered R = 3 mixed‐layer illite/smectite is recognized from burial depths of 2200 m. The proportion of illite in illite/smectite mixed layers increases only slightly with depth and temperature. Although the structural changes generally are associated with chemical changes, they can also take place isochemically when the detrital glaucony is tightly embedded in earlier cement, which prevented chemical exchange. The glaucony transformation in the Siri Canyon sandstones partly reflects a supply of Si and partly significant loss of Fe. Thus, the glaucony transformation relates to the general diagenesis of the host sandstone. These sandstones are cemented by microquartz at an early stage, followed by precipitation of Fe‐rich grain‐coating berthierine or chlorite.     

Interaction of crustal and mantle materials,sources of trace elements during the formation and evolution of Early Paleozoic Li-rich granite-pegmatite systems in southeastern Tuva

We present new data on the age, composition, and environments of formation of granites of the Kystarys complex and the associated Li-rich rare-element pegmatites of the South Sangilen pegmatite belt including the large Tastyg lithium deposit. It has been established that they formed during the Early Paleozoic collisional orogeny in the Tuva-Mongolian massif at the Cambrian-Ordovician boundary. The granites of the Kystarys complex are moderately alkaline high-K rocks and are enriched in Zr, Nb, Y, and REE; therefore, they are classified as postcollisional, transitional to within-plate (A-type). The spodumene pegmatites of the South Sangilen pegmatite belt are similar to the above granites in age and isotopic and geochemical parameters, which suggests a paragenetic relationship between these rocks. Pegmatites form several pegmatite fields within the belt, which differ in trace-element signatures. In addition to predominant Li, Cs, and Ta, specific to all spodumene pegmatites (LCT family), pegmatites of two fields have high contents of Nb, Y, REE, and Zr, which are indicator elements of NYF family pegmatites. It has been established that the formation of spodumene pegmatites with combined LCT-NYF geochemical signatures was preceded by the intrusion of dikes of monzogabbro with the geochemical characteristics of OIB and of alkali aegirine granites and by the formation of associated metasomatites enriched in Zr, Nb, Y, and REE. Based on the geological, mineralogical, and geochemical data, we substantiate the hypothesis of the formation of Li-bearing granite-pegmatite melts from a mixed source resulted from the influence of fluids of an alkaline igneous complex of mantle genesis on the crustal protolith.     

混合表面活性剂存在下镓与O—Cl—PF显色反应的研究

本文研究了在pH 6.5-7.8的(CH_2)_6N_4-HCl缓冲介质中,CDMAA和TritonX-100对Ga与o-Cl-PF和F~-显色反应的增敏作用。结果表明,Ga-o-Cl-PF-F-CDMAA-TritonX-100多元配合物λ_(max)为565nm,表观摩尔吸光系数ε=1.74×10~5L·mol~(-1)·Cm~(-1),Ga含量在0～6.0μg/25ml范围内符合比尔定律,用合成样和标样进行本方法考验,结果满意。     

陆源碎屑与碳酸盐混合沉积研究中的几点思考

在前人研究的基础上，结合一些具体研究实例，对混合沉积的定义进行了修正和补充；对混积岩和混积层系重新进行分类和命名；根据混合沉积的定义、成因、成分、结构、沉积构造及接触关系等因素，按照“沉积事件+剖面结构”的原则，提出了渐变式、突变式和复合式3种成因类型，对前人的研究成果进行了概括和归纳；对混合沉积的控制因素进行了深入讨论；在以碳酸盐沉积为主和以陆源碎屑沉积为主的2类沉积背景下详细论述了层序格架中混合沉积的发育情况；结合混合沉积本身的特点讨论了混合沉积与油气的关系。最后针对混合沉积研究现状，指出了该领域研究中存在的问题，并对未来的研究方向进行了展望。     

复杂应力条件下掺砾黏土真三轴试验

采用新型真三轴仪器,对掺砾黏土进行了复杂应力条件下加载试验,近似模拟了土石坝填筑期心墙土体单元的加荷过程。试验结果表明,由于土体单元处于复杂应力状态,即使是单向加载这样的简单加荷应力路径,在不同应力方向上的应力和变形也都呈现显著的应力各向异性。土石坝应力变形分析中坝体单元处于三向应力条件下,由于加载引起的应力各向异性对心墙乃至整个坝体的应力变形规律都有较大影响,合理的本构模型应该能够反映并描述这种复杂应力状态下的应力各向异性。     

柴北缘阿木尼克山牦牛山组火山岩地球化学特征及其地质意义

柴北缘阿木尼克地区分布有大面积的牦牛山组火山岩,通过对火山岩岩石组合、地球化学、锆石测年等研究。研究结果表明该区岩性组合以中-酸性火山岩为主,发育柱状节理,为典型陆相火山岩。里特曼指数（δ）为1.45~4.54,全碱（ALK）含量变化范围较大,铝饱和指数为0.66~1.19,具2种来源地球化学特征的火山岩（S和I型）,显示混源演化,轻稀土富集,重稀土亏损,铀亏损明显。构造环境均显示为岛弧,锆石年龄为中-晚泥盆世,表明阿木尼克山一带在该时期主体处于隆升状态,而到了晚泥盆世-早石炭世时期则出现了海相沉积岩,说明古特提斯洋重新打开,拉开了该区海相沉积帷幕。     

二维大地电磁测深交互式正、反演系统的实现及其应用

目前，大地电磁测深的资料处理与正、反演软件都是FORTRAN语言编写的，由于FORTRAN语言本身的局限性，使得这个软件存在很多的缺陷，但是因为用FORTRAN语言编写的算法已经比较成熟，将它全部用其他语言移植也比较费时费力，为了避免资料的浪费，提高大地电磁测深的资料处理与交互式系统的开发效率，并且更加完善其功能，在开发大地电磁测深二维交互式正反演系统时，对大地电磁测深中的计算部分仍用现有的FORTRAN程序，对有关的界面与图形诉开发部分用VC＋＋语言来编写，以增强和体现其交互式的功能。     

内蒙古大桦背I型花岗岩地球化学特征及其成因意义

在大桦背花岗岩体区域地质和岩石学研究的基础上,运用X射线荧光光谱分析样品主量元素,采用电感耦合等离子体质谱对其样品进行了微量、稀土元素分析.同时结合前人的锆石年龄和Pb同位素数据,认为大桦背花岗岩为I型花岗岩,主要为古亚洲洋板块向华北板块多期俯冲过程中,中下地壳、成熟岛弧和大洋岛弧大面积部分熔融的产物,伴有少量地幔与未知含量的海洋沉积物及早期造山作用产物等物质的不同程度混合作用.     

Circulation and water masses of the Arabian Sea

The dynamics and thermodynamics of the surface layer of the Arabian Sea, north of about 10N, are dominated by the monsoon-related annual cycle of air-sea fluxes of momentum and heat. The currents in open-sea regime of this layer can be largely accounted for by Ekman drift and the thermal field is dominated by local heat fluxes. The geostrophic currents in open-sea subsurface regime also show a seasonal cycle and there is some evidence that signatures of this cycle appear as deep as 1000 m. The forcing due to Ekman suction is an important mechanism for the geostrophic currents in the central and western parts of the Sea. Recent studies suggest that the eastern part is strongly influenced by the Rossby waves radiated by the Kelvin waves propagating along the west coast of India. The circulation in the coastal region off Oman is driven mainly by local winds and there is no remotely driven western boundary current. Local wind-driving is also important to the coastal circulation off western India during the southwest monsoon but not during the northeast monsoon when a strong (approximately 7 × 10⁶m³/sec) current moves poleward against weak winds. This current is driven by a pressure gradient which forms along this coast during the northeast monsoon due to either thermohaline-forcing or due to the arrival of Kelvin waves from the Bay of Bengal. The present speculation about flow of bottom water (deeper than about 3500 m) in the Arabian Sea is that it moves northward and upwells into the layer of North Indian Deep Water (approximately 1500–3500m). It is further speculated that the flow in this layer consists of a poleward western boundary current and a weak equatorward flow in the interior. It is not known if there is an annual cycle associated with the deep and the bottom water circulation.