矿物在油气形成过程中的作用

模拟实验结果表明,矿物组成对煤岩样品的模拟实验结果具有很大的影响,不同的矿物以及同一种矿物在不同的有机质热演化阶段,对有机质形成石油和天然气的过程均具有非常明显的影响:高岭土矿物在高温热演化阶段对有机质形成气态烃的过程具有一定的催化能力;碳酸钙（CaCO3）在中—低热演化阶段能抑制气态物质的形成,而在较高的热演化阶段则对煤生成气态物质的过程具有一定的催化作用;四氧化三铁（Fe3O4）在主要的模拟实验阶段对煤生成气态物质的过程均具有一定的催化作用;硫化亚铁（FeS）在低温热演化阶段对天然气的形成具有一定的抑制作用,而在高温热演化阶段则对天然气的形成具有较明显的催化作用;元素硫（S）在不同的热演化阶段对天然气的形成过程均具有非常明显的催化作用。矿物介质不仅对气态产物的产率有比较明显的影响,而且对液态产物的产率也有较明显的影响。模拟实验结果表明:高岭土和四氧化三铁（Fe3O4）在中、低温模拟实验阶段对“氯仿沥青A”的形成具有较明显的催化作用;硫化亚铁（FeS）在整个模拟实验的全过程中对“氯仿沥青A”的形成均具有明显的催化作用;碳酸钙（CaCO3）矿物对“氯仿沥青A”的形成具有明显的抑制作用;元素硫（S）对“氯仿沥青A”的形成具有非常明显的催化作用。     

1957-2014年库布齐沙漠地面风场特征

风对沙漠化过程具有重要影响,起沙风是塑造沙漠地貌格局的主要动力。根据1957-2014年库布齐沙漠周边4个基准气象站的地面风资料,从风速、风向和输沙势等方面分析库布齐沙漠的地面风场特征。结果显示：（1）库布齐沙漠的起沙风频率与平均风速有很高的相关性;（2）年平均风速为2.7 m·s^-1,全年盛行风向为WNW-NW,为中等变率锐双峰风况,合成输沙风向约为310°。4月风速最大,为中等变率环境;8月风速较小,为高变率环境;1月风速最小,为低变率环境。3-6月风速最大,风向集中度一般;11月至翌年2月风速较大,风向集中度高;7-10月风速最小,风向集中度差;（3）20世纪80年代中后期和2007年前后风速、起沙风频率和输沙势发生了较大变化,尤其是2007年前后由减小向增大发展;（4）大气环流和地表粗糙度的改变是库布齐沙漠地面风场变化的重要原因。     

东天山戈壁荒漠景观区地球化学勘查中某些工作方法的研究

通过东天山地区地球化学勘查中某些方法的试验,研究了一套适宜于戈壁荒漠景观中地球化学勘查的工作方法.（1）查明了盛行风对岩屑异常特征的影响程度;（2）推荐消除风成沙影响的合理采样粒级;（3）利用水溶态铜、金异常指示被运积物掩盖的铜、金矿体;（4）明确了荒漠区盐磐层不会阻碍在残积物覆盖区发现矿致岩屑异常和在运积物覆盖区发现后生晕.     

Change of crustal gravitational potential energy in the Taiwan orogen by the Chi-Chi earthquake sequence

The active convergence between the northwest corner of the Philippine Sea Plate and the southeast margin of the Eurasian Plate has given rise to the Taiwan mountain-building and produced numerous earthquakes. Among the earthquakes, the 1999 Chi-Chi earthquake is the largest one recorded in the century. In this study, we examine the crustal gravitational potential energy (GPE) change in the Taiwan orogen caused by the Chi-Chi earthquake sequence, which was catalogued by the regional broadband seismometer array for a whole year. As a result, we find that the crust was going up and down randomly during the earthquake sequence, but an overall cumulative gain of the crustal GPE, +1.82×10¹⁶ J, was rapidly achieved in 1 month after the main shock. The crustal GPE was nearly still afterwards and reached +1.90×10¹⁶ J in 1 year. Spatially, although the main surface faulting has occurred in western Taiwan, the crustal GPE gain is mainly distributed in central Taiwan at the area where the existing crustal GPE is high and the existing lithospheric GPE is relatively low. The crustal GPE loss by the Chi-Chi earthquake sequence can also be observed and is generally distributed at both sides of the crustal GPE gain area. The crustal GPE gain mainly found in central Taiwan corroborates that the uplift of the Taiwan orogen is principally taking place in central Taiwan, rather than in the more hazardous western Taiwan.     

A mapping of the electron localization function for the silica polymorphs: evidence for domains of electron pairs and sites of potential electrophilic attack

The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ～0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ～0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ～0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??²ρ maps. Isosurface η maps calculated for quartz and the (HO) ₃ SiOSi(OH) ₃ molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??²ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal.     

新矿物—盈江铀矿

新矿物产于云南盈江县的一个铀矿点氧化带,与多种铀矿物共生。该矿物为致密状集合体,黄色,透明至半透明。斜方晶系,空间群C222_1,晶胞参数a=13.73(1),b=15.99(1),c=17.33(2);V=3804(5);Z=8。计算比重4.17。二轴晶负光性,2V计算=83°,α=1.669;β=1.692;γ=1.710。紫外光照射发弱绿黄色荧光。化学成分UO_376.54,P_2O_511.10,K_2O 2.46,CaO 1.57,ThO 0.51,RE_2O_3 0.45,H_2O 7.37%。矿物化学式为(K_(1-x),Ca_x)(UO_2)_3 (PO_4)_2 (OH)_(1+x)·4H_2O,文中还给出X射线粉晶衍射数据。     

Phase Chemistry Study of the Zabuye Salt Lake Brine: Isothermal Evaporation at 15°C and 25°C

Zabuye Salt Lake in Tibet, China is a carbonate-type salt lake, which has some unique characteristics that make it different from other types of salt lakes. The lake is at the latter period in its evolution and contains liquid and solid resources. Its brine is rich in Li, B, K and other useful minor elements that are of great economic value. We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15°C and 25°C. The crystallization sequence of the primary salts from the brine at 25°C is halite (NaCl) → aphthitalite (3K2SO4·Na2SO4) → zabuyelite (Li2CO3)→ trona (Na2CO3·NaHCO3·2H2O) → thermonatrite (Na2CO3·H2O) → sylvite (KCl), while the sequence is halite (NaCl) → sylvite (KCl) → trona (Na2CO3·NaHCO3·2H2O) → zabuyelite (Li2CO3) → thermonatrite (Na2CO3·H2O) → aphthitalite (3K2SO4·Na2SO4) at 15°C. They are in accordance with the metastable phase diagram of the Na+, K+-Cl?, CO32?, SO42?-H2O quinary system at 25°C, except for Na2CO3·7H2O which is replaced by trona and thermonatrite. In the 25°C experiment, zabuyelite (Li2CO3) was precipitated in the early stage because Li2CO3 is supersaturated in the brine at 25°C, in contrast with that at 15°C, it precipitated in the later stage. Potash was precipitated in the middle and late stages in both experiments, while boron was concentrated in the early and middle stages and precipitated in the late stage.     

川西南及邻区地震短临预测的实践与思考

在简介川西南及邻区地震地质和历史强震活动的基础上,通过重点梳理部分典型地震短临预测实例,介绍了地方政府对防震减灾、地震预报工作的重视和支持,对工作中的一些实际问题进行了思考,供同行们讨论与参考。     

一颗罕见的金丝猫眼宝石的鉴定

一颗蛋圆形的猫眼宝石,经采用无损伤鉴定研究,确定为天然顽火辉石——金丝猫眼石。其特征为:重1.38g,呈茶褐色,玻璃光泽,Hv(50)1145kg/mm~2(莫氏硬度7级),具平行细密纹理,猫眼光学效应,明显的多色性及平行消光。电子探针分析(％):SiO_2 61.11,MgO 33.71,FeO 3.78,总量为98.60。化学式为(Mg_(1.72) Fe_(0.11))_(1.83)[Si_(2.08)O_6]。