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71.
Stanislav FRANCISKOVIC-BILINSKI Halka BILINSKI Delko BARISIC Nada HORVATINCIC Institute Ruder BoSkovi POB HR- Zagre Croati E-mail: francis@rudjer.irb.hrand YUAN Daoxian Institute of Karst Geology Guilin Guangxi China 《《地质学报》英文版》2003,77(2):267-275
The paper presents an analysis of characteristic karst tufa from Guangxi, China, which has not been studied before. A comparison with tufa from Dinaric Karst of Croatia is discussed in view of the C-type climate. The major mineral is calcite. Minor minerals are quartz and dolomite, depending on location. The content of calcium carbonate varies from 65% to 92%, and that of magnesium carbonate from 0.03% to 1.77%. Among other elements, the most abundant are Fe, from 0.02% to 1.50%, and Ti, from 0.15% to 0.27%. Many other trace elements (V, Cr, Mn, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Hg and Pb) are also present. Specific activity of radionuclides 40K, 232Th, 137Cs, 226Ra and 238U varies from sample to sample. Concentration of U in tufa is close to that reported for sedimentary carbonate. Low concentration of 137Cs indicates that this part of the world was not exposed to nuclear explosions. The concentration of 226Ra is the highest in Mashan County. The ratio 238U/226Ra (0.21-0.71) in tufa from Mashan Co 相似文献
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西藏驱龙斑岩铜钼矿地球化学异常特征 总被引:6,自引:0,他引:6
驱龙铜矿发育多元素的岩石地球化学异常.成矿元素Cu、Mo、(Ag)异常强、规模大,异常与矿化区一致;伴生元素Au、Bi、Pb、As、Sb、Hg异常在Cu、Mo异常边部并套合产出的B Co、Ni Mn Zn的异常主要分布铜钼矿化带外侧.Na2O在矿化区显示负异常,K2O为正异常.从异常元素组合、水平分带性和贫Na2O、富K2O的成矿环境表明,矿床属典型的斑岩型铜矿地球化学特征,并受到了强烈的剥蚀. 相似文献
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地面上的矿物或污染物元素主要是随水系而运移的。因此,利用自然水系网信息来定量分析元素沿水系的迁移、分散,对于地质找矿和环境保护都具有重要意义。在研究应用主概率权模拟模型产生自然水系网的基础上,提出了元素在水系网中运移的计算方法,结合所模拟出的水系网,具体分析了元素在其中的迁移、扩散情况,给出了正问题和反问题的计算结果。结果表明,正、反问题的求解具有一致性,方法是有效、可行的。 相似文献
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济阳坳陷稀土元素特征及其在物源对比中的应用 总被引:6,自引:1,他引:6
物源是控制沉积物中REE组成最主要的因素,济阳坳陷区岩石稀土元素特征表明:①济阳坳陷古生界与华北地台其他地区同时代地层岩石的REE分布特征具有极大的相似性,这体现了晚古生代济阳坳陷区所处的整个华北地台区为一稳定的克拉通沉积盆地,地层横向分布稳定,具有一致的物源和构造背景;②济阳坳陷古生界为中生界的物源,反映了济阳坳陷区由古生代稳定地台型沉积到中生代山间盆地沉积的转变,中生代洼陷区的沉积主要来自对附近凸起区古生代地层的剥蚀;③新生界样品与中生界样品的REE分布模式具有很大的相似性,从一个侧面反映了济阳坳陷中生代与新生代的构造格局的转变,中生代接受沉积的部分洼陷区至古近纪成为供给物源的凸起区。 相似文献
79.
Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses 总被引:9,自引:0,他引:9
Stephen M. Eggins 《Geostandards and Geoanalytical Research》2003,27(2):147-162
A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis. 相似文献
80.
William J. Chazey III Clive R. Neal Jinesh C. Jain William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192
The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1). 相似文献