XEPOS型偏振能量色散X射线荧光光谱仪分析蒙古铁矿石

以熔融玻璃片和粉末压片制样,采用XEPOS型偏振能量色散X射线荧光光谱仪,建立了铁矿石中总铁、氧化钙、氧化镁、二氧化硅、三氧化二铝、硫、磷、铜等组分的快速分析方法。着重讨论硫、磷两元素测定的可行性和Lucas-Tooth、Price数学校正模型的适应性和改善方法的途径。     

激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。     

青海南部熔积岩的发现:对寻找VMS型矿床的重要启示

熔积岩指的是侵入、混合到未固结或弱固结的湿沉积物中的熔浆分解、原位形成的一类特殊岩石。正确地认识该类岩石,有利于增进人们对岩浆-水(沉积物)相互作用过程的理解,恢复古环境。在青海南部沱沱河地区发现了一套角砾为撕片状、锯齿状及浑圆状的安山岩,胶结物为铁硅质组合的特殊熔积岩。研究表明,该熔积岩的角砾为岩浆遇水后快速淬火、裂解的产物,铁硅质组合为海底喷气沉积形成的含铁建造;且安山岩与含铁建造发生混合时,含铁建造尚未固结。该套熔积岩的发现,改变了长期以来对开心岭铁矿为火山热液交代安山岩而形成的认识,对于在矿区寻找VMS型矿床、区域内寻找海底热水喷流沉积型矿床具有重要的启示意义。     

Extensional tectonic origin of gneissosity and related structures of the Feiran–Solaf metamorphic belt, Sinai, Egypt

The Feiran–Solaf metamorphic belt consists of low-P high-T amphibolite facies, partly migmatized gneisses, schists, amphibolites and minor calc-silicate rocks of metasedimentary origin. There are also thick concordant synkinematic sheets of diorite, tonalite and granodiorite orthogneiss and foliated granite and pegmatite dykelets. The gneissosity (or schistosity) is referred to as S₁, and is almost everywhere parallel to lithological layering, S₀. This parallelism is not due to transposition. The gneissosity formed during an extensional tectonic event (termed D1), before folding of S₀. S₁ formed by coaxial pure shear flattening strain (Z normal to S₀, i.e. vertical; with X and Y both extensional and lying in S₁). This strain also produced chocolate tablet boudinage of some layers and S₁-concordant sills and veins. S₁ has a strong stretching lineation L₁ with rodding characteristics. Within-plane plastic anisotropy (lower ductility along Y compared to along X) resulted in L₁-parallel extensional ductile shears and melt filled cracks. Continued shortening of these veins, and back-rotation of foliations on the shears produced intrafolial F₁ folds with hinges parallel to the stretching lineation. F₁ fold asymmetry variations do not support previous models involving macroscopic F₁ folds or syn-gneissosity compressional tectonics. The sedimentary protoliths of the Feiran–Solaf gneisses were probably deposited in a pre-800 Ma actively extending intracratonic rift characterizing an early stage of the break-up of Rodinia.     

高、低煤阶煤层气藏地质特征及控气作用差异性研究

高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。     

Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis

The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem.     

The largest karst cave discovered in a tunnel during motorway construction in Slovenia’s Classical Karst (Kras)

Karst researchers of the Karst Research Institute ZRC SAZU are regularly consulted during the planning of Slovenia’s motorways and invited to observe and monitor construction in the karst areas. More than 350 caves have been discovered in the course of building 60 km of new motorways over the past decade. Access to the most important caves is preserved by concrete tubes closed with metal covers at the roadside. The largest cave system in a tunnel, named LC-S647, is almost entirely preserved. The protection of this cave will serve as a good example for the preservation of natural heritage in the future. Construction work for the motorway uncovered a high degree of karstification. In particular, the discovery of this cave in the Kastelec tunnel LC-S647 showed the existence of a major cave system in the geological and speleological past. A number of unconnected passages have also been found. Caves discovered during highway construction have brought new knowledge about the cavernosity and the geological history of this part of the karst.     

Landslide susceptibility mapping for a landslide-prone area (Findikli,NE of Turkey) by likelihood-frequency ratio and weighted linear combination models

Landslides are very common natural problems in the Black Sea Region of Turkey due to the steep topography, improper use of land cover and adverse climatic conditions for landslides. In the western part of region, many studies have been carried out especially in the last decade for landslide susceptibility mapping using different evaluation methods such as deterministic approach, landslide distribution, qualitative, statistical and distribution-free analyses. The purpose of this study is to produce landslide susceptibility maps of a landslide-prone area (Findikli district, Rize) located at the eastern part of the Black Sea Region of Turkey by likelihood frequency ratio (LRM) model and weighted linear combination (WLC) model and to compare the results obtained. For this purpose, landslide inventory map of the area were prepared for the years of 1983 and 1995 by detailed field surveys and aerial-photography studies. Slope angle, slope aspect, lithology, distance from drainage lines, distance from roads and the land-cover of the study area are considered as the landslide-conditioning parameters. The differences between the susceptibility maps derived by the LRM and the WLC models are relatively minor when broad-based classifications are taken into account. However, the WLC map showed more details but the other map produced by LRM model produced weak results. The reason for this result is considered to be the fact that the majority of pixels in the LRM map have high values than the WLC-derived susceptibility map. In order to validate the two susceptibility maps, both of them were compared with the landslide inventory map. Although the landslides do not exist in the very high susceptibility class of the both maps, 79% of the landslides fall into the high and very high susceptibility zones of the WLC map while this is 49% for the LRM map. This shows that the WLC model exhibited higher performance than the LRM model.     

Greening as strategic development in industrial change - Why companies participate in eco-networks

Networking between companies and other regional key actors has grown into a widespread instrument for economic development since the 1990s. Participatory networks have formed the concept for many activities of Local Agenda 21. Simultaneously, economic geography has focused on network theories to explain innovation in and the economic success of regions.This article focuses on the reasons why individual actors participate in environmentally oriented information networks. The questions approached are: Does the concept of learning within networks influence a firm’s development? How do the participants interact with each other? What effects do the networks have on their environment (arenas)?The changing arenas of a firm are analysed with regard to environmental concerns. These changes need to be anticipated for reliable strategies. To gain information and knowledge about current behaviour and activities, the functions of networks as learning platforms are discussed. Drawing upon arguments from different network theories, the motivations of participating in a network are threefold: actor and firm oriented, network internal (inter-firm), and network external. From these, a generic target cube of network motivations and actions is set up.The concept is reviewed by examining 12 ‘regional environmental information-oriented corporation networks’ (RUN) in the Greater Munich Area. The empirical material reveals that this type of network does not provide a guarantee for significant improvements in a firm’s environmental behaviour. However, participants learn about best practices while pursuing explicit or implicit aims as to influence their arenas.     

Global Correlations of Ocean Ridge Basalt Chemistry with Axial Depth: a New Perspective

The petrological parameters Na₈ and Fe₈, which are Na₂O andFeO contents in mid-ocean ridge basalt (MORB) melts correctedfor fractionation effects to MgO = 8 wt%, have been widely usedas indicators of the extent and pressure of mantle melting beneathocean ridges. We find that these parameters are unreliable.Fe₈ is used to compute the mantle solidus depth (P_o) and temperature(T_o), and it is the values and range of Fe₈ that have led tothe notion that mantle potential temperature variation of T_P= 250 K is required to explain the global ocean ridge systematics.This interpreted T_P = 250 K range applies to ocean ridges awayfrom ‘hotspots’. We find no convincing evidencethat calculated values for P_o, T_o, and T_P using Fe₈ have anysignificance. We correct for fractionation effect to Mg^# = 0·72,which reveals mostly signals of mantle processes because meltswith Mg^# = 0·72 are in equilibrium with mantle olivineof Fo_89·6 (vs evolved olivine of Fo_{88·1–79·6}in equilibrium with melts of Fe₈). To reveal first-order MORBchemical systematics as a function of ridge axial depth, weaverage out possible effects of spreading rate variation, local-scalemantle source heterogeneity, melting region geometry variation,and dynamic topography on regional and segment scales by usingactual sample depths, regardless of geographical location, withineach of 22 ridge depth intervals of 250 m on a global scale.These depth-interval averages give Fe₇₂ = 7·5–8·5,which would give T_P = 41 K (vs 250 K based on Fe₈) beneathglobal ocean ridges. The lack of Fe₇₂–Si₇₂ and Si₇₂–ridgedepth correlations provides no evidence that MORB melts preservepressure signatures as a function of ridge axial depth. We thusfind no convincing evidence for T_P > 50 K beneath globalocean ridges. The averages have also revealed significantcorrelations of MORB chemistry (e.g. Ti₇₂, Al₇₂, Fe₇₂,Mg₇₂, Ca₇₂, Na₇₂ and Ca₇₂/Al₇₂) with ridge axial depth. Thechemistry–depth correlation points to an intrinsic linkbetween the two. That is, the 5 km global ridge axial reliefand MORB chemistry both result from a common cause: subsolidusmantle compositional variation (vs T_P), which determines themineralogy, lithology and density variations that (1) isostaticallycompensate the 5 km ocean ridge relief and (2) determine thefirst-order MORB compositional variation on a global scale.A progressively more enriched (or less depleted) fertileperidotite source (i.e. high Al₂O₃ and Na₂O, and low CaO/Al₂O₃)beneath deep ridges ensures a greater amount of modal garnet(high Al₂O₃) and higher jadeite/diopside ratios in clinopyroxene(high Na₂O and Al₂O₃, and lower CaO), making a denser mantle,and thus deeper ridges. The dense fertile mantle beneath deepridges retards the rate and restricts the amplitude of the upwelling,reduces the rate and extent of decompression melting, givesway to conductive cooling to a deep level, forces melting tostop at such a deep level, leads to a short melting column,and thus produces less melt and probably a thin magmatic crustrelative to the less dense (more refractory) fertile mantlebeneath shallow ridges. Compositions of primitive MORB meltsresult from the combination of two different, but geneticallyrelated processes: (1) mantle source inheritance and (2) meltingprocess enhancement. The subsolidus mantle compositional variationneeded to explain MORB chemistry and ridge axial depth variationrequires a deep isostatic compensation depth, probably in thetransition zone. Therefore, although ocean ridges are of shalloworigin, their working is largely controlled by deep processesas well as the effect of plate spreading rate variation at shallowlevels. KEY WORDS: mid-ocean ridges; mantle melting; magma differentiation; petrogenesis; MORB chemistry variation; ridge depth variation; global correlations; mantle compositional variation; mantle source density variation; mantle potential temperature variation; isostatic compensation