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61.
Geochemistry of trace elements and Sr-Nd isotopes of foraminifera shell from the Okinawa Trough 总被引:1,自引:0,他引:1
INTRODUCTIONProvenanceofmarinesedimentshasalwaysbeenafocusedprobleminmarinesedimentge ology.Recognitionofendmembersandestimationoftheirrelativeproportionsfrommixedsedimentshavebeenakeycontentinthestudyofprovenance .Forthisaim ,itisnecessarytoselectendme… 相似文献
62.
A finite element model is set up and experimental tests are performed to help understand the behavior of a concrete canoe and subsequently optimize its design. First, the performance criteria that must be satisfied to participate at the annual ASCE/Master Builders competition are described. Then, the finite element model and the different loading cases that were studied are presented. Results from these loading cases are discussed and used to optimize the material properties as well as the thickness of the hull and the dimensions of the gunwale and reinforcing ribs. Static and dynamic experimental tests were also conducted to validate the results of the finite element analyses. The results indicate that the main stresses and strains are caused by the static load cases. The additional stresses caused during races are small. 相似文献
63.
Christopher L. Dupont James. W. Moffett Robert R. Bidigare Beth A. Ahner 《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(12):1961-1974
Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation. 相似文献
64.
Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas 总被引:3,自引:0,他引:3
The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (Ls), ranging from 19 to 93 pM with an average conditional stability constant (KHgLs) of 1028, and a weak class (Lw) ranging from 1.4 to 9.8 nM with an average KHgLs of 1023. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgClx, Hg(OH)x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters. 相似文献
65.
A numerical model to compute wave field is developed. It is based on the Berkhoff diffraction-refraction equation, in which an energy dissipation term is added, to take into account the breaking and the bottom friction phenomena. The energy dissipation function, by breaking and by bottom friction, is introduced in the Berkhoff equation to obtain a new equation of propagation.The resolution is done with the hybrid finite element method, where lagrangians elements are used. 相似文献
66.
The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated
during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The
spatial variability of SPM distribution (0.3–6.5 mg l−1) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental
fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio
intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward
for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the
influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water
(mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations
were highly significant. Particulate CaCO3 distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with
sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of
the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal
agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across
or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total
area of 0.45 × 106 km2 of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water
column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences
of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang
and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate
that continental sources and cross-shelf transport modulate ECS particulate matter in summer. 相似文献
67.
A model for solving the two-dimensional enhanced Boussinesq equations is presented. The model equations are discretised in space using an unstructured finite element technique. The standard Galerkin method with mixed interpolation is applied. The time discretisation is performed using an explicit three-step Taylor–Galerkin method. The model is extended to the surf and swash zone by inclusion of wave breaking and a moving boundary at the shoreline. Breaking is treated by an existing surface roller model, but a new procedure for the detection of the roller thickness is devised. The model is verified using four test cases and the results are compared with experimental data and results from an existing finite difference Boussinesq model. 相似文献
68.
U–Th decay series isotopes, δ18O and Si measurements in the river estuarine waters and sediments of the polluted Hooghly estuary as well as the surface waters of the Bay of Bengal, its high salinity end member, are reported. Dissolved Si indicates that there are probably two mixing regimes, dissolved U behaviour is nonconservative and δ18O behaves conservatively in the overall estuarine region. Isotopes of reactive elements, viz. 234Th and 210Po, are removed from the estuarine waters in <2 days and <1 month, respectively, which is due to high suspended matter (30–301 mg l−1). 228Ra and 226Ra are profusely released into the estuarine waters in the low to mid-salinity regions.As expected, the opposite trend is observed in the case of estuarine sediments and suspended matter. Reactive isotopes of Th, 210Pb and 210Po are enriched, whereas Ra isotopes are depleted with respect to their parent nuclides in the estuarine sediments and suspended matter. 232Th/Al ratio appears well suited to study the distribution and mixing of the bed load sediments of the Ganga–Brahmaputra (G–B) and the Hooghly rivers with those from other rivers on the Bay of Bengal floor. 相似文献
69.
R. Danovaro N. Della Croce A. DellAnno A. Pusceddu 《Deep Sea Research Part I: Oceanographic Research Papers》2003,50(12):1411-1420
The Atacama trench, the deepest ecosystem of the southern Pacific Ocean (ca. 8000 m depth) was investigated during the Atacama Trench International Expedition. Sediments, collected at three bathyal stations (1040–1355 m depth) and at a hadal site (7800 m) were analyzed for organic matter quantity and biochemical composition (in terms of phytopigments, proteins, carbohydrates and lipids), bacterial abundance, biomass and carbon production and extracellular enzymatic activities. Functional chlorophyll-a (18.0±0.10 mg m−2), phytodetritus (322.2 mg m−2) and labile organic carbon (16.9±4.3 g C m−2) deposited on surface sediments at hadal depth (7800 m) reached concentrations similar to those encountered in highly productive shallow coastal areas. High values of bacterial C production and aminopeptidase activity were also measured (at in situ temperature and 1 atm). The chemical analyses of the Atacama hadal sediments indicate that this trench behaves as a deep oceanic trap for organic material. We hypothesize that, despite the extreme physical conditions, benthic microbial processes might be accelerated as a result of the organic enrichment. 相似文献
70.
台风作为事件性的强动力因素,其对河口海域沉积环境的影响目前研究较少,开展典型台风事件对长江口外海域悬浮体分布的影响研究对于深入理解长江径流挟带陆源物质向东海陆架扩散机制等具有重要意义。利用2015年09号台风"灿鸿"过境前后长江口外海域现场调查数据,分析台风前后长江口外水体结构和悬浮体粒度分布变化,结合同期环境观测数据与开源数据,阐明台风对河口外海域悬浮体分布的影响机制。结果表明:长江口外海域悬浮体中细颗粒组分(≤ 128μm)主要为无机矿物颗粒,而粗颗粒组分(>128μm)主要是生源有机颗粒。生源有机粗颗粒主要分布于中上层水体,而无机细颗粒主要分布于底层水体,使得长江口外海域悬浮体平均粒径分布呈双层结构。台风前后悬浮体粒度分布变化反映了台风对长江口外海域物理和生物过程的双重影响,其中物理过程主要影响无机细颗粒分布变化,生物过程主要影响有机粗颗粒。台风期间强烈的偏北风使得长江冲淡水在口门外海域由东北输运转为往东输运,与长江冲淡水输运方向一致的表层无机细颗粒在台风后输运方向同样往东。另外,台风作用在河口区产生的下降流将12250-4站位底部再悬浮的泥质沉积物向东搬运至12300-4站,导致12300-4站底层悬浮体浓度增加、粒度变细。台风过境还造成长江口外海域初级生产力提高,而浮游植物生长对悬浮体中有机粗颗粒的形成有促进作用,使得口门外海域上层水体中有机粗颗粒体积浓度升高。长江口外海域由于台风过境导致悬浮体中无机细颗粒和生源有机颗粒含量均增加,使得其平均粒径整体变化不大。 相似文献