天然磁铁矿处理含Hg（Ⅱ）废水实验研究

利用重金属离子可在水合金属氧化物和氢氧化物矿物表面产生吸陵作用的原理，进行了天然磁铁矿处理含Hg(Ⅱ）废水的实验研究，结果表明：当温度为25℃，吸附平衡时间为60分钟、试样用量为20g/L，试样粒径为200目以下、pH值为6.40，离子强度为零时，Hg(Ⅱ）初始浓度为1.12mg/L的溶液的吸附率可达98%，使废水中Hg(Ⅱ）的浓度达到国家排放标准。pH值、离子强度、粒径、试样用量、废水浓度、温度、时间均对Hg(Ⅱ）的吸附率有一定的影响，其中pH值的影响最大，Hg(Ⅱ）在天然磁铁矿上的吸附等温曲线不同于Langmuir和Freundlich等温曲线，而是表现为台阶段，符合分级离子/配位子交换等温曲线。     

湖北省大冶铁矿区内矿石磁性特征分析

从磁铁矿矿石的磁性差异入手,对铁(铜)矿床中各矿体的矿石磁性特征进行了系统的描述,得出大冶铁矿铁(铜)矿床是一个磁性特征变化较大的矿区.之后对矿石中引起磁性差异的原因进行了分析,并指出影响磁铁矿矿石磁性特征的主要因素为矿石的矿物组成、化学成分以及矿石的结构和构造.     

"水墨画"种翡翠的矿物学特征研究

"水墨画"种翡翠是市场上出现的翡翠新品种,得名于其黑色不透明物质在无色的"地"上的不规则分布,形似水墨画。本文运用电子探针、X射线粉晶衍射、红外光谱等分析手段对"水墨画"种翡翠进行了研究,结果表明,"水墨画"种翡翠矿物组成以硬玉和绿辉石为主,含有少量的斜长石、磁铁矿及黑色不透明杂质。黑色杂质和磁铁矿为导致该种翡翠产生黑色和不透明的水墨画状外观的主要原因。     

新疆蒙库铁矿床矽卡岩矿物学特征及其意义

蒙库铁矿床是一个以下泥盆统斜长角闪变粒岩(原岩为火山岩)为围岩的大型矽卡岩型矿床,矽卡岩矿物组合为辉石、石榴子石和方柱石,退化蚀变岩的组成矿物为角闪石、绿帘石、绿泥石、磷灰石等。电子探针分析结果表明,矽卡岩矿物中单斜辉石以透辉石为主,仅存在少量普通辉石;石榴子石端员组分以钙铁榴石为主,伴以少量钙铝榴石和锰铝榴石;角闪石属于单斜角闪石中的阳起石。蒙库铁矿床的矽卡岩与正常的矽卡岩矿床形成方式不同,不是中酸性岩浆与碳酸盐地层接触交代的产物,而是由热流体沿裂隙交代火山变质岩形成的。     

新疆西天山晚古生代主要磁铁矿床(点)成因类型与成矿过程探讨

新疆西天山晚古生代磁铁矿带是中国重要的铁矿带,其成矿地质背景与成因类型一直以来存在很大的争论.本文在已有研究成果的基础上,结合大量野外调查资料和室内研究工作,对西天山主要磁铁矿床的成因类型、成矿背景、成矿规律进行了详细研究.研究表明,主要磁铁矿床矿石矿物Sr、Nd、Pb同位素基本落入洋陆俯冲碰撞下的岛弧环境;矿石形成年龄介于火山岩与中酸性侵入岩之间,接近于火山岩年龄,矿石与火山岩具有密切的成因联系.矿床总体归为海相火山岩型铁矿,可划分出3个亚类:火山喷溢型、火山-次火山热液型、火山喷溢-热液叠加型,不同亚类矿床具有不同的矿体、矿石特征.铁矿石的形成与俯冲带流体的交代作用有着密切的关系,早期为富铁岩浆交代后分异结晶作用的产物,后期则为火山热液沿断裂、裂隙交代、卸载的产物.     

山东昌乐蓝宝石砂矿中磁铁矿的宝石矿物学特征研究

采用常规宝石学鉴定方法、反光显微镜、X射线粉末衍射仪（XRD）、电子探针X射线显微分析仪（EPMA）、傅里叶变换红外光谱仪（FTIR）等测试方法,对山东昌乐蓝宝石砂矿中的一种副矿物样品进行了常规的宝石学、矿物学、谱学特征研究。肉眼观察,这种副矿物样品呈黑色、不透明,具有强磁性,摩氏硬度大于小刀。在反光显微镜下,该样品为钢灰色,呈现不透明的四边形颗粒状。X射线粉末衍射及电子探针成分分析的结果表明,该副矿物样品为富含Ti的磁铁矿,其晶体结构中类质同象替代广泛,但未见对人体有害的微量元素。该样品的红外光谱与磁铁矿的标准红外光谱基本一致。     

长江与黄河沉积物中磁铁矿成分标型意义

长江与黄河沉积物中磁铁矿的元素组成揭示,两者的ＦｅＯ与Ｆｅ２Ｏ３及一些置换元素的含量差异明显。长江磁铁矿中ＦｅＯ与Ｆｅ２Ｏ３含量稍高于黄河磁铁矿,而Ｔｉ、Ｖ、Ｓｉ、Ａｌ、Ｃｒ、Ｍｇ及Ｍｎ等元素含量明显地低于黄河磁铁矿,元素含量变化显著小于黄河磁铁矿。这反映长江磁铁矿中Ｆｅ＾２＋及Ｆｅ＾３＋的类质同象置换较少,主要为均质相单矿物颗粒,而黄河磁铁矿中元素含量变化大,既有均质相的颗粒,也存在一些Ｆｅ＾２     

宁陕县南付家河磁铁矿地质特征及成因分析

南付家河磁铁矿地处南秦岭被动陆缘菜子坪—柞水推覆岩片带内,近矿围岩为一套钠长岩,泥盆系发育的同沉积断层控制了矿体的空间位置,矿床成因属热水喷流沉积型。     

陕西汉南毕机沟钒钛磁铁矿锆石U-Pb年代学及其意义

毕机沟钒钛磁铁矿位于扬子板块北缘汉南杂岩的西北部,是基性-超基性杂岩体分异演化的产物。矿区范围出露的岩石主要包括橄长岩、辉长岩、辉长闪长岩和闪长岩,具有明显岩相分带和韵律旋回特征。目前,已发现的多个钒钛磁铁矿体均位于基性岩-超基性杂岩体的辉长岩相带内。本次研究对毕机沟矿区的含矿辉长岩和穿切含矿辉长岩的花岗岩脉进行了原位微区LA-MC-ICPMS锆石U-Pb定年,获得两者的侵位时间分别为(783±4)Ma(MSWD=0.09)和(759±4)Ma(MSWD=1.50),结果表明毕机沟钒钛磁铁矿的成矿时代大约为783 Ma,但不晚于759 Ma。结合前人区域成果资料,毕机沟含钒钛磁铁矿的基性-超基性杂岩体与该区新元古代大规模具岛弧性质的基性-超基性杂岩体的形成时代相近,我们认为毕机沟钒-钛磁铁矿可能形成于活动型大陆边缘环境。     

Petrological and Geochemical Constraints on the Protoliths of Serpentine‐Magnetite Ores in the Zhaoanzhuang Iron Deposit,Southern North China Craton

The uncommon Mg-rich and Ti-poor Zhaoanzhuang serpentine-magnetite ores within Taihua Group of the North China Craton(NCC) remain unclear whether the protolith was sourced from ultramafic rocks or chemical sedimentary sequences. Here we present integrated petrographic and geochemical studies to characterize the protoliths and to gain insights on the ore-forming processes. Iron ores mainly contain low-Ti magnetite(TiO_2 ~0.1 wt%) and serpentine(Mg#=92.42–96.55), as well as residual olivine(Fo=89–90), orthopyroxene(En=89–90) and hornblende. Magnetite in the iron ores shows lower Al, Sc, Ti, Cr, Zn relative to that from ultramafic Fe-Ti-V iron ores, but similar to that from metamorphic chemical sedimentary iron deposit. In addition, interstitial minerals of dolomite, calcite, apatite and anhydrite are intergrown with magnetite and serpentine, revealing they were metamorphic, but not magmatic or late hydrothermal minerals. Wall rocks principally contain magnesian silicates of olivine(Fo=83–87), orthopyroxene(En=82–86), humite(Mg#=82–84) and hornblende [XMg=0.87–0.96]. Dolomite, apatite and anhydrite together with minor magnetite, thorianite(Th-rich oxide) and monazite(LREE-rich phosphate) are often seen as relicts or inclusions within magnesian silicates in the wall rocks, revealing that they were primary or earlier metamorphic minerals than magnesian silicates. And olivine exists as subhedral interstitial texture between hornblende, which shows later formation of olivine than hornblende and does not conform with sequence of magmatic crystallization. All these mineralogical features thus bias towards their metamorphic, rather than magmatic origin. The dominant chemical components of the iron ores are SiO_2(4.77–25.23 wt%), Fe_2O_3 T(32.9–80.39 wt%) and MgO(5.72–27.17 wt%) and uniformly, those of the wall rocks are also SiO_2(16.34–48.72 wt%), Mg O(16.71–33.97 wt%) and Fe_2O_3 T(6.98–30.92 wt%). The striking high Fe-Mg-Si contents reveal that protolith of the Zhaoanzhuang iron deposit was more likely to be chemical sedimentary rocks. The distinct high-Mg feature and presence of abundant anhydrite possibly indicate it primarily precipitated in a confined seawater basin under an evaporitic environment. Besides, higher contents of Al, Ti, P, Th, U, Pb, REE relative to other Precambrian iron-rich chemical precipitates(BIF) suggest some clastic terrestrial materials were probably input. As a result, we think the Zhaoanzhuang iron deposit had experienced the initial Fe-Mg-Si marine precipitation, followed by further Mg enrichment through marine evaporated process, subsequent high-grade metamorphism and late-stage hydrothermal fluid modification.