Magnetic anisotropy of calcite at room-temperature

The intrinsic room temperature magnetic properties of pure calcite were determined from a series of natural crystals, and they were found to be highly dependent on the chemical composition. In general, dia-, para-, and ferromagnetic components contribute to the magnetic susceptibility and the anisotropy of magnetic susceptibility (AMS). With a combination of magnetic measurements and chemical analysis these three contributions were determined and related to their mineralogical sources. The intrinsic diamagnetic susceptibility of pure calcite is − 4.46 ± 0.16 × 10^− 9 m³/kg (− 12.09 ± 0.5 × 10^− 6 SI) and the susceptibility difference is 4.06 ± 0.03 × 10^− 10 m³/kg (1.10 ± 0.01 × 10^− 6 SI). These diamagnetic properties are easily dominated by other components. The paramagnetic contribution is due to paramagnetic ions in the crystal lattice that substitute for calcium; these are mainly iron and manganese. The measured paramagnetic susceptibility agrees with the values calculated from the known concentration of paramagnetic ions in the crystals according to the Curie law of paramagnetic susceptibility. Substituted iron leads to an increase in the AMS. The paramagnetic susceptibility difference was found to correlate linearly with the iron content for concentrations between 500 and 10,000 ppm. An empirical relation was determined: (k₁ − k₃)^para (kg/m³) = Fe-content (ppm) × (1 ± 0.1) × 10^− 12 (kg/m³/ppm). The maximum susceptibility difference (Δk = k₁ − k₃) was found to be unaffected by iron contents below 100 ppm. Ferromagnetic contributions due to inclusions of ferromagnetic minerals can dominate the susceptibility. They were detected by acquisition of isothermal remanent magnetization (IRM) and their contribution to the AMS was separated by high-field measurements.     

南北构造带北段重磁异常的对应分析

论述了重磁异常对应分析方法原理和地质解释的地球物理基础,计算了南北构造带北段上延5 ～50km 的重磁对应分析的相关系数R和斜率α的平面分布曲线,结合其它地质和地球物理资料,初步分析认为:(1) 中朝准地台的阿拉善台隆和鄂尔多斯台缘隆起区属于正常地壳结构;鄂尔多斯台缘坳陷区属于非正常地壳结构;(2) 祁连秦岭褶皱区地壳结构比较复杂,南、北祁连和礼县 柞水褶皱带的地壳为基本正常地壳结构;祁连北部走廊过渡带、中部隆起带和南秦岭褶皱带西段的地壳属于非正常地壳结构;(3)相关系数转换带的平面分布特征大致反映了断裂带的伸展方向,在剖面上的位置大致与断裂带构造位置相对应     

河南栾川矿集区深部资源综合物探找矿勘查

河南栾川县为全国的钼都,矿产资源丰富,已探明钼钨矿产资源与出露岩体关系密切,矿体多产在岩体或岩体接触带围岩。为进一步加强栾川矿集区的资源勘查,确定隐伏岩体的空间分布和成矿规律,对深部资源进行评价,在栾川矿集区开展了重力、磁法面积测量和CSAMT电磁法剖面测量等综合物探找矿勘查。在矿集区开展1∶2.5万重力和磁法面积测量,通过向上延拓、求导及水平梯度模等方法,提取、识别与地质相关的重磁场信息,判断隐伏岩体的分布范围,依地质模型为约束条件,对资料进行定量-半定量解释,圈出隐伏岩体的空间分布形态,构建三维地质模型,得出栾川矿集区隐伏岩体规模巨大,深部资源量丰富。依据重磁解释成果,优选隐伏岩体顶界面相对较浅的黄背岭矿区,进行CSAMT剖面测量,利用卡尼亚电阻率陡变带,对隐伏岩体的顶界面进行定位。经钻孔验证,在黄背岭矿区新发现三条钼钨矿体,矿体产在岩体顶界面上下一定范围内,在岩体的凹陷部位往往矿层厚度较大,新增钼金属量102.01万吨、WO3资源量21.66万吨。成果表明,利用钼钨矿体多产在岩体界面上下一定范围内的特征,用重力、磁法面积测量确定隐伏岩体空间分布,CSAMT剖面测量确定岩体顶界面,指导钻孔定位的物探组合方法,在栾川矿集区深部资源的勘查中成果显著,该方法组合可为“中国钼都”战略资源深部找矿提供强有力的技术支撑。     

中蒙边界地区成矿区带划分

中蒙边界地区成矿区带划分是近年来该区成矿规律研究中的重要科学问题之一。以板块构造-地球动力学理论为指导,在中蒙合作完成的该区1∶100万建造-构造图和成矿规律图的基础上,对中蒙边界地区成矿区带进行了统一厘定和划分。该区Ⅰ级成矿域隶属于古亚洲成矿域和滨太平洋成矿域。古亚洲成矿域可划分为阿尔泰、准噶尔-南蒙古和塔里木3个成矿省、12个成矿带和21个成矿亚带。滨太平洋成矿域划分出大兴安岭和华北陆块2个成矿省、4个成矿带和15个成矿亚带。研究提出,蒙古的欧玉陶勒盖-查干苏布尔嘎大型-超大型斑岩型矿床成矿亚带向西与中国的东天山-北山成矿亚带相连,为该区寻找同类型斑岩型矿床指明了方向。     

基于重磁震资料的南海新生代盆地分布综合研究

作为西太平洋最大的边缘海,南海分布有30多个新生代沉积盆地,其蕴含着丰富的油气资源.但由于资料的限制,南海存在不同区域盆地研究程度不同,不同区域盆地面积差别较大,部分盆地只是坳陷而没有达到盆地的级别以及盆地外围可能存在凹陷等问题.南海新生代盆地分布问题制约了其油气分布规律、储量等基础地质问题的研究.本文以地震剖面数据为约束,以重力资料为主、辅以磁力资料,研究了南海新生代盆地分布及构造区划.通过提取新生代盆地及其构造单元引起的重力异常,结合地震剖面等资料反演了新生界底界面深度及新生界厚度.在充分调研已有盆地和构造单元划分方案的基础上,根据南海的地质及地球物理特征,确定了盆地及构造单元划分标准.以新生界厚度为基础并结合重、磁、震、地质等资料,进行地质-重磁震联合解释,将南海原有的36个盆地重新划分为24个盆地,盆地总面积扩大了约15万km2.研究表明,南海新生代盆地沉积层厚度在1.5~16 km之间,有6个北东东/北东向沉积坳陷带、2个近南北向沉积坳陷带以及1个三角沉积坳陷区;盆地展布方向主要为北东和北东东向,其次为北西和近南北向,呈现"南三北三"的分布特征.     

双能CT诊断膝关节前交叉韧带损伤可行性探讨

目的:探讨双能CT在膝关节前交叉韧带(ACL)损伤中的应用可行性。方法:30例膝关节外伤患者行双能CT和MR检查,观察软组织CT图像、双能CT肌腱伪彩(DETC)图像和MR图像上ACL。以MR图像为参考标准,评估双能CT图像诊断ACL损伤的预测值。结果:MR图像、软组织CT图像、联合软组织CT图像和DETC图像诊断明确的ACL损伤的例数分别为23、11和20。软组织CT图像诊断ACL损伤的敏感度、特异度、阳性预测值、阴性预测值及准确度分别为47.8%、100.0%、100.0%、36.8%和60.0%;联合软组织CT图像和DETC图像诊断ACL损伤的各预测值分别为82.6%、85.7%、95.0%、60.0%和83.3%。与软组织CT图像相比,联合软组织CT图像和DETC图像诊断ACL损伤的敏感度和准确度均有明显增加(敏感度和准确度相应的相似文献   

川西盐井沟断层传播褶皱的三维构造建模与磁组构分析 推荐 下载阅读CAJ格式全文 下载阅读PDF格式全文

当前断层相关褶皱研究的发展方向是从二维向三维的转换。文中基于Arcgis、Discovery以及Gocad等三维软件平台,对川西盐井沟地区地震资料进行精细的解析,得出盐井沟背斜是一个典型的三剪断层传播褶皱,并建立了它的三维模型。同时考虑到单纯符合几何约束的构造解释普遍存在着多解性和不确定性,结合几何学的三维建模和动力学的有限应变分析研究断层相关褶皱。在川西盐井沟地区18个采样点钻取了184块定向岩心样品,通过磁组构的分析结果发现,盐井沟地区的磁组构基本上都是弱应变的初始变形组构,褶皱前翼应变强度比后翼略强。断层传播褶皱三剪带是有限应变最为集中的区域,在模型预测的三剪带内,磁组构反映的有限应变也较为强烈。磁组构所指示的构造应力场大致为NW-SE向挤压缩短,与断层相关褶皱的几何学与运动学模型的预测相一致。     

Comprehensive Study of the Activity in the Middle Sections of Huangzhuang-Gaoliying and Babaoshan Faults

To monitor the activity of the Huangzhuang-Gaoliying and Babaoshan faults in their middle sections,a network for leveling,short-side ranging,and gravity and geomagnetic observations at the same time and at the same station was set up.By this network,the time and space distribution and the relation between different observations have been studied.It is considered that the Huangzhuang-Gaoliying fault is in a locked state for rapid strain energy accumulation,while the Babaoshan fault is in a state of creep or unrestrained motion.To do comprehensive monitoring of fault activity by making deformation,gravity,and geomagnetic observations at the same time and at the same station,it would be possible to acquire the microscopic state of fault activity and the data of earthquake preparation; such an approach is considered worth popularizing.     

龙门山南段盐井-五龙断裂磁组构特征及其对几何学、运动学的制约

盐井?五龙断裂是龙门山中央断裂北川?映秀断裂的南延部分,也是龙门山南段的三大控制性主干断裂之一。为了详细认识盐井?五龙断裂的构造几何学、运动学特征,在野外构造研究的基础上,运用磁组构方法对盐井?五龙断裂105块构造岩定向样品进行深入研究。野外构造解析表明断裂至少发生了韧性挤压剪切、脆?韧性逆冲和脆性挤压碎裂三期构造变形。磁组构研究显示构造岩磁组构样品的平均磁化率k_m值具有强磁化率和弱磁化率两种特征。磁组构形状参数T、磁面理F值、磁线理L值和T-P_J图解显示磁化率椭球体主要为压扁型,磁面理较磁线理发育,局部发育较强磁线理,进一步表明盐井?五龙断裂以挤压、剪切为主,伴有拉伸变形的整体特征,样品的P_J整体较大,显示出构造强变形磁组构特征。最小磁化率主轴K_min方位表明盐井?五龙断裂北段和南段分别受到了NW-SE向和NEE-SWW向的挤压作用;K_min方位和倾伏角表明北段晚一期的脆韧性变形主体为自NW向SE的较高角度的挤压逆冲剪切变形,局部伴有极小量的左行走滑特征。断裂南段早期韧性变形整体以自SWW向NEE的挤压逆冲剪切变形为主,上盘(西盘)远离主干断裂表现为左行走滑兼逆冲的运动学特征,下盘变形主要以逆冲剪切变形为主,走滑分量极小,并且自西向东韧性剪切变形具有相对强弱相间的特征。     

Refining P nuclear magnetic resonance spectroscopy for marine particulate samples: Storage conditions and extraction recovery

Solution ³¹P nuclear magnetic resonance (NMR) spectroscopy has recently been used to characterize phosphorus species within marine particles. However, the effects of sample collection, storage and preparation have not been thoroughly examined. In this study, samples of settling particulates collected from a 1200-m sediment trap located in Monterey Bay, California, were subjected to various storage options (i.e., no storage, refrigeration, freezing, and oven-drying and grinding) prior to extraction for solution ³¹P-NMR spectroscopy. Freezing, refrigerating and drying samples for periods of up to 6 months prior to extraction with 0.25 M NaOH + 0.05 M Na₂EDTA increased the concentration of extracted P by an average of 16% relative to samples extracted without storage. Pre-extraction storage also introduced some minor changes in P speciation, by increasing the percentage of orthophosphate by up to 15% and decreasing the percentage of pyrophosphate by up to 5%, relative to the abundances of these P species in samples extracted without storage. Drying caused the biggest changes in speciation, specifically decreasing more extensively the relative percentage of pyrophosphate compared to other treatments. Nevertheless, observed changes in speciation due to sample storage within a specific sample were small relative to differences observed among samples collected sequentially in the same area, or reported differences among samples collected at different locations. Samples were also analyzed by solid-state ³¹P-NMR spectroscopy before and after extraction, to examine extraction-related changes in P speciation. Comparison of solution with solid-state ³¹P NMR indicates that extraction with NaOH–EDTA removes the majority of organic esters, but only a variable portion of phosphonates (39–67%). In addition, there was preferential extraction of Ca-associated phosphate over Mg-, Fe- and Al-associated phosphate. Solution ³¹P NMR enables much higher resolution of P species within samples, particularly when it is important to speciate orthophosphate monoesters and diesters, or if polyphosphates are present. However, combining solid-state ³¹P NMR with solution ³¹P NMR spectroscopy for marine particles should be conducted when examining inorganic P speciation and the abundance of phosphonates.