幔源CO_2释出机理、脱气模式及成藏机制研究进展

针对幔源CO2如何从地幔岩浆中脱出并进入沉积地层中形成CO2气藏聚集这一关键问题,总结了国内外研究进展和前缘方向。研究表明,地幔深部的碱性玄武岩浆和碱性岩浆才是深部流体和CO2等挥发份大量赋存、渗滤和释出的场所。浅成侵入岩、次火山岩和火山通道等是CO2释放和聚集的有利位置,岩浆期后和岩浆衰弱期的热液活动阶段是CO2大量释放和聚集的有利时期。幔源CO2进入沉积盆地中具有3种脱气模式,即沿岩石圈断裂直接脱气模式、热流底辟体脱气模式和壳内岩浆房-基底断裂组合脱气模式。CO2的固有物化性质决定其运移相态多样,具有运移和聚集过程同步的特征。只有在满足大量的化学消耗及地层水或原油的溶解和耗散之后才能形成CO2有效聚集。幔源CO2成藏和分布主要受岩浆气源体和气源断裂体系的控制。今后,在超临界CO2及其对油气运移聚集的作用、CO2与深大断裂及火山岩的关系、CO2脱气运移机制、CO与常规烃类油气的耦合差异成藏机制等方面仍需要进一步的研究和探索。     

Cyclicity in the Main and Upper Zones of the Bushveld Complex, South Africa: Crystallization from a Zoned Magma Sheet

The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock ⁸⁷Sr/⁸⁶Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial ⁸⁷Sr/⁸⁶Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetite–ilmenite–apatite)layers and changes up-section from gabbronorite (An₇₂ plagioclase;Mg# 74 clinopyroxene) to magnetite–ilmenite–apatite–fayaliteferrodiorite (An₄₃; Mg# 5 clinopyroxene; Fo₁ olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V₂O₅ of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO₂ and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO₂ and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation     

冲绳海槽玄武岩中中酸性残余熔体研究及其岩石学意义

与洋壳有关的酸性岩由于对了解幔源岩浆的演化以及判别古老蛇绿岩套及其构造位置的重要意义而倍受岩石学家和构造地质学家的关注。本对发现于冲绳海槽玄武岩基质中的中酸性到酸性残余熔体进行了详细研究，它们提供了幔源玄武岩浆结晶分异形成酸性岩浆的直接证据。在细小的基质矿物间分布有一种玻璃质的残余熔体，其成分随距冷凝边距离(L)的增加而越来越酸性。在SiO2对Na2O K2O图解上，残余熔体的投影点从玄武岩到英安岩均有分布，反映了一个连续的演化系列。在AFM图解上，残余熔体表现出与Thingmuli火山岩系列类似的拉斑玄武岩系列的演化趋势。我们的研究表明：残余熔体的演化受结晶分异作用控制。在早期结晶阶段，辉石的结晶起主导作用，结果造成残余熔体中SiO2、Al2O3，Na2O的迅速增加，FeO、MgO、CaO迅速降低。在晚期结晶阶段，斜长石成为主导结晶相，导致残余熔体中Al2O3，Na2O的迅速消减。Al2O3、Na2O从增加到降低的转变出现在SiO2=62％左右。在L=27．5mm处，85～90％的基质岩浆已发生了结晶作用，导致残余熔体中SiO2含量达到69～70％，而且此处还新出现了一种富FeTi的氧化物。该玄武岩中残余熔体和基质矿物的成分及演化特征分别与Thingmuli火山岩系列中酸性端元的组成相似，在也佐证了Thingmuli火山岩系列是幔源岩浆结晶分异的产物.     

Origin of fine-scale sheeted granites by incremental injection of magma into active shear zones: examples from the Pilbara Craton, NW Australia

In the Archaean Pilbara Craton of Western Australia, three zones of heterogeneous centimetre- to metre-scale sheeted granites are interpreted to represent high-level, syn-magmatic shear zones. Evidence for the syn-magmatic nature of the shear zones include imbricated and asymmetrically rotated metre-scale orthogneiss xenoliths that are enveloped by leucogranite sheets that show no significant internal strain. At another locality, granite sheets have a strong shape-preferred alignment of K-feldspar, suggesting magmatic flow, while the asymmetric recrystallisation of the grain boundaries indicates that non-coaxial deformation continued acting upon the sheets under sub-solidus conditions. Elsewhere, randomly oriented centimetre-wide leucogranite dykes are realigned at a shear zone boundary to form semi-continuous, layer-parallel sheets within a magma-dominated, dextral shear zone.

It is proposed that the granite sheets formed by the incremental injection of magmas into active shear zones. Magma was sheared during laminar flow to produce the sheets that are aligned sub-parallel to the shear zone boundary. Individual sheets are fed by individual dykes, with up to 1000s of discrete injections in an individual shear zone. The sheets often lack microstructural evidence for magmatic flow, either because the crystal content of the magma was too low to record internal strain, or because of later recrystallisation.     

灵山岩体演化特征及其与稀有金属的成矿关系

从岩体时空分布、岩石化学成分、造岩矿物、副矿物、微量元素、稳定同位素、成岩温度、压力等特征，论述了灵山岩体演化与钽铌等稀有金属成矿的关系，简述了区内典型稀有金属矿床主要成矿地质特征及其与岩体的成因联系，进而肯定了区内钽铌等稀有金属找矿的良好前景，并提出了今后找矿的方向和建议。     

U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.     

黄河上游河南县地面大气冰核观测分析

用Bigg型混合云室对2001年8月黄河上游青海省河南县的地面大气冰核浓度进行了观测,分析发现(1)青海省河南县冰核浓度低于北京20世纪90年代的测值,但高于大连、西安和兰州(20世纪60年代)等地的测值,同时也高于黄河上游的玛曲(2000年)、西宁(1989年)两地的测值,高温核尤其偏高.(2)降水时大气冰核浓度减少,降水的冲刷可能是其主要原因.(3)当地冰核浓度和气压成正相关.(4)大气冰核浓度受风向的影响,无风时测值较小,偏东风时测值较大,高温核浓度增加明显.     

长白山天池火山区长白-敦化剖面结晶基底的探测和研究

时间项分析法中，应用广义最小二乘法进行反演，对长白山天池火山区岩浆系统的长白—敦化(L1)剖面的Pg波到时进行了计算处理，得到了Pg波时间项及基底速度值；取上部地壳的介质平均速度为4．5km/s，经反演求得了各点的深度值，给出了长白山天池火山区结晶基底的厚度分布。结晶基底厚度一般在2．0km左右，而在长白山天池下方结晶基底最厚处接近4．0km；在万宝和敦化附近各有一不太明显的凹陷，其原因可能与在这两个位置处有几条断裂穿过有关。