Estimating gas saturation in a thin layer by using frequency‐dependent amplitude versus offset modelling

Various models have been proposed to link partial gas saturation to seismic attenuation and dispersion, suggesting that the reflection coefficient should be frequency‐dependent in many cases of practical importance. Previous approaches to studying this phenomenon typically have been limited to single‐interface models. Here, we propose a modelling technique that allows us to incorporate frequency‐dependent reflectivity into convolutional modelling. With this modelling framework, seismic data can be synthesised from well logs of velocity, density, porosity, and water saturation. This forward modelling could act as a basis for inversion schemes aimed at recovering gas saturation variations with depth. We present a Bayesian inversion scheme for a simple thin‐layer case and a particular rock physics model and show that, although the method is very sensitive to prior information and constraints, both gas saturation and layer thickness theoretically can be estimated in the case of interfering reflections.     

A Correction Algorithm for Atmospheric Visibility Based on Fog Droplet Size Data Obtained on a Moving Ship During 2016 Arctic Cruise

In this study, we measured the droplet size distribution(DSD) and visibility of sea fog using a fog droplet spectrometer and visibility meter, respectively, during the July 23-August 3 and August 22-September 13 periods of the 2016 Chinese National Arctic Research Expedition. We calculated the visibility using the Mie theory and the DSD data and then compared the calculated with the observed visibility. The comparison shows that the deviations in the calculated visibility caused by DSD data sampling errors cannot be ignored. During navigation, wind and ship speeds tended to push or pull the sampled air and cause turbulence pulsation, which influenced the sampling of the fog droplet spectrometer. This influence is weak when the liquid water content(LWC) is high but becomes stronger as the LWC decreases. Taking the sailing speed and heading into consideration, the wind speed component parallel and perpendicular to the air inlet of the fog droplet spectrometer exhibit different laws in the deviation. By performing a fitting analysis of the calculated and observed visibilities under different wind speeds and wind directions, here, we present two sets of correction coefficients for the two wind-speed components and a method for correcting the calculated visibility. This correction method shows excellent results.     

UHPLC-LTQ-Orbitrap-MS非定向筛查贝类中氮杂螺环酸毒素及其代谢产物

为了分析复杂贝类和微藻中的氮杂螺环酸毒素（AZAs）及其代谢产物,建立一种基于超高效液相色谱-线性离子阱/静电场轨道阱组合式高分辨质谱（UHPLC-LTQ-Orbitrap-MS）联用技术的非定向筛查分析方法。采用Full MS/dd MS²、PRM和Target-SIM/dd MS²三种质谱鉴定模式,整合多种数据采集挖掘策略,通过研究多种AZAs在不同基质样品中的质谱裂解规律及特征碎片离子丰度,实现AZAs及其衍生物的快速筛查检测和精准鉴别。结果表明：PRM模式能有效排除AZAs同分异构体的干扰,获得更高的专属性,适用于目标代谢物筛查;应用Full MS/dd MS²和PRM结合的方式,根据AZAs裂解途径及多种AZAs代谢产物裂解规律,在贝类中共鉴别出20种AZAs系列化合物,其中包括初步推测了3种新型AZAs代谢产物的结构。应用本方法还发现AZA9、AZA10、AZA19等代谢物均随代谢过程持续升高,是AZA2在贝类代谢过程中的末端产物。该方法能够为复杂基质中的AZAs系列毒素及其衍生常规检测与精准鉴别提供参考,可应用于解析AZAs毒素在贝类体内的代谢转化机制研究。     

南海北部荔湾3区块天然气水合物分布特征及目标识别

针对天然气水合物钻探与取样难以解决的水合物矿体空间展布等问题,利用白云-荔湾凹陷高密度分析重新处理的三维地震资料,首先基于模糊数学的多属性融合技术对水合物分布进行刻画;再通过高分辨率速度场对浅层开展高分辨率宽频无井反演技术,提高了水合物层分辨率;最后,利用岩石物理方法及多种模型对水合物饱和度进行定量预测,实现了对5～6m厚水合物层的有效辨别,进而形成了一套适合于孔隙充填型的水合物矿藏目标识别评方法。结果表明:应用该技术可有效对荔湾3水合物富集区第四条带水合物空间刻画,揭示出该区水合物饱和度最高可超40%,同时薄层与厚层水合物具有明显互层分布特征,在水合物矿体刻画及饱和度预测基础上,进一步对该区实施了井位优选,该方法预测的水合物层与实际钻探H1和H2站位吻合较好。这些结果说明常规三维油气地震数据在经过宽频处理后可应用于高分辨率水合物勘探,节约经济成本,同时提高了常规地震在水合物勘探中精度与实用性。     

Effects of periodic saturation on stress–strain relationship of a sandstone mixture

While a crushed sandstone particle mixture, usually used as an engineering fill, is filled along bank of or in a large reservoir, it is subjected to periodic saturation induced by filling-drawdown cycles of reservoir water. The periodic saturation may induce post-construction settlement, and reduce stability of the filled body. In order to evaluate the effects of periodic saturation on stress–strain relationship of the mixture, several triaxial tests are carried out. According to experimental data, the periodic saturation may induce an increment of axial strain (Δε; <0.226%), a decrement of crest of deviator stress (Δ(σ₁?σ₃)_f; <0.192?MPa) and a decrement of angle of shearing resistance (Δφ; <3.70°). With increment of the number of periodic saturation cycles, the variations of the three parameters may be fitted by logarithmic curves. And with increase in the stress level for periodic saturation, the variations of the three parameters may be fitted by straight lines. Three fitting equations to predict the three parameters’ values, and an equation to calculate the settlement induced by the periodic saturation of a large-area filled foundation, are suggested.     

胶州湾秋季文石饱和度分布及控制因素分析

基于2017-10-18航次在胶州湾调查获取的水文、碳化学和叶绿素a(Chl a)等数据与资料,分析了秋季该海域文石饱和度(Ω_arag(现场))的分布状况,探讨了影响其空间分布的主要控制因素。结果显示,秋季航次期间胶州湾表层Ω_arag(现场)为1.85～2.57,平均值为(2.20±0.24);其分布具有较大的空间差异,低值位于湾的西部和东北部(<2.05),高值位于湾口(>2.45),总体上呈现出由湾口向湾顶逐步降低的趋势。除了通过分析Ω_arag(现场)与温度、盐度和Chl a的相关性来定性确定Ω_arag(现场)的主控因素外,我们还通过引入总碱度与溶解无机碳的差值作为Ω_arag(现场)的指征参数,定量确定了影响Ω_arag(现场)空间分布的主要过程及其贡献。研究发现,陆源输入是影响胶州湾秋季Ω_arag(现场)空间分布的最重要因素(>50%),而温度和生物过程的影响相对较小。     

印度克里希纳-戈达瓦里盆地天然气水合物饱和度特征

印度国家天然气水合物计划(NGHP01)于2016年实施第1次钻探,证实了天然气水合物在印度大陆边缘的广泛分布。选择位于克里希纳-戈达瓦里盆地(KG盆地)的NGHP01-07D和NGHP01-15A钻孔,基于测井数据和岩心样品估算天然气水合物饱和度,分析天然气水合物赋存状态并探讨其形成机制。基于各向同性介质模型利用电阻率和声波测井计算NGHP01-15A钻孔的天然气水合物饱和度为0. 2%～33. 0%,平均值为9. 6%,在NGHP01-07D钻孔利用电阻率计算获得的天然气水合物饱和度高于岩心氯离子异常和气体释放获得的结果,但是基于各向同性岩石物理模型利用声波测井计算的天然气水合物饱和度与岩心结果一致,平均值为5. 0%。前人研究认为NGHP01-10D钻孔中天然气水合物以相对较高饱和度富集在高角度裂隙中。结合前人研究结果推断在克里希纳-戈达瓦里盆地存在3种不同的天然气水合物储层,即泥岩中砂质夹层各向同性储层、泥质/粉砂质高角度低连通性的低饱和度裂隙储层和泥岩中高角度高连通性的高饱和度裂隙储层,并提出对应的3种天然气水合物储层模型。     

南极绿藻中类菌胞素氨基酸对UV-B胁迫的响应

南极上空臭氧层的破坏导致了紫外辐射日益增强,高强度的UV-B辐射会造成细胞中DNA的损伤,影响蛋白质、脂类和色素的代谢过程。生长在南极的绿藻具有一系列防御机制以应对增强的UV-B辐射,其中类菌胞素氨基酸(Mycosporine-like amino acids, MAAs)是一类重要的紫外防御物质。为探究类菌胞素氨基酸对UV-B辐射的响应,本文以南极冰藻(Chlamydomonassp.ICE-L)、针丝藻(Raphidonema nivale Lagerheim, NIES-2290)和胶球藻(Coccomyxa subellipsoidea E.Acton, NIES-2166)三种生活在南极的绿藻为材料,采用UV-B辐射胁迫(强度0.35 W/m~2,短时处理3 h),并通过液相色谱-质谱联用法检测类菌胞素氨基酸的种类和含量的变化。Mycosporine-glycine为三种南极绿藻中共有的MAAs,在UV-B辐射胁迫下三种南极绿藻中Mycosporine-glycine含量变化不尽相同,表明不同的南极绿藻中MAAs对UV-B辐射的响应各有其特性。首次在绿藻(南极冰藻和胶球藻)中检测到Gadusol。Gadusol作为MAAs的合成前体,它的合成积累使得生活在海冰环境的南极冰藻和胶球藻具有良好的抗UV-B辐射能力。其中南极冰藻抗紫外能力最强,这可能得益于不同MAAs间的动态转化,含量升高的Palythine及Usujirene/Palythene可能对南极冰藻的紫外屏蔽起着至关重要的作用。     

Tuned liquid dampers for controlling earthquake response of structures

Numerical simulations of a single‐degree‐of‐freedom (SDOF) structure, rigidly supporting a tuned liquid damper (TLD) and subjected to both real and artificially generated earthquake ground motions, show that a properly designed TLD can significantly reduce the structure's response to these motions. The TLD is a rigid, rectangular tank with shallow water in it. Its fundamental linear sloshing frequency is tuned to the structure's natural frequency. The TLD is more effective in reducing structural response as the ground excitation level increases. This is because it then dissipates more energy due to sloshing and wave breaking. A larger water‐depth to tank‐length ratio than previous studies suggested, which still falls within the constraint of shallow water theory, is shown to be more suitable for excitation levels expected in strong earthquake motions. A larger water‐mass to structure‐mass ratio is shown to be required for a TLD to remain equally effective as structural damping increases. Furthermore, the reduction in response is seen to be fairly insensitive to the bandwidth of the ground motion but is dependent on the structure's natural frequency relative to the significant ground frequencies. Finally, a practical approach is suggested for the design of a TLD to control earthquake response. Copyright © 2000 John Wiley & Sons, Ltd.     

Radar remote sensing of the source areas from the Coët-Dan catchment

As interest shifts to the development of models for predicting runoff quality, identification of the source areas for runoff becomes increasingly important. Active microwave remote sensing has a unique potential for surveying source areas at the catchment scale. Thresholding of the back-scattering coefficient was initially proposed but proved unsatisfactory when applied to the ERS-1 SAR multitemporal images acquired during winter 1992 over the Coët-Dan catchment, concomitantly with ground observations. Difference images may, instead, allow the wettest part of the catchment to be identified provided that the two images encompass a marked hydrological event. A saturation plot could not however be obtained for each date; the use of a pair of images may be further limited by the residual speckle (although carefully filtered using the multitemporal information) and a slight inaccuracy in the SAR image calibration. It is therefore argued that considering the whole temporal back-scatter profile would be, at present, a safer approach to the remote sensing of saturated areas. The back-scatter temporal standard deviation appears, in this light, as a possible good indicator of the local saturation likelihood during the period of study: it is based on the fact that saturation develops on parts of the catchment that are wetter than the others through lateral recharge. Possible applications within the TOPMODEL framework are discussed. © 1998 John Wiley & Sons, Ltd.