从四川盆地盐类变质资料看找钾方向

四川盆地三叠系盐类在地史经历中，经受强烈的热融和水溶变质作用，使盐类沉积原始面貌发生深刻变化。（钾组分转入液相，形成液态钾盐—富钾卤水）现剖面所见硬石膏、杂卤石、硫镁矾、无水钾镁矾等多系热融和水溶变质产物。面对这一现实，理顺和拓宽四川找钾思路，勘查开发液态钾盐，是四川找钾的新方向。     

原煤尾气和煤渣中多环芳烃相关性测定

对原煤、尾气和煤渣中多环芳烃进行了相关性测试。在模拟工业锅炉代表性燃烧条件下将烟煤和无烟煤样品在管式炉中燃烧，分别采用ＧＣＭＳ和ＨＰＬＣ法对原煤、尾气和煤渣中的多环芳烃种类和含量进行了定性和定量测定。通过在特定条件下某一煤种中多环芳烃种类、含量在燃前、燃后变化的相关性，探索煤中多环芳烃在燃烧过程中的衍变规律     

Biogeochemical aromatic markers in the sediments from mahakam delta (Indonesia)

Analysis of the tri-, tetraand pentaaromatic hydrocarbon fractions of several sediments (0–600 m) from the Mahakam Delta (Indonesia), indicate the predominance of polycyclic aromatic hydrocarbons (PAH) diagenetically related to triterpenoid natural precursors. High resolution Shpol'skii spectrofluorometry (HRS) proved to be a valuable analytical tool, in conjunction with high performance liquid chromatography (HPLC) and capillary gas chromatography coupled with mass spectrometry (CGC/MS), for the identification of individual components in Chromatographic fractions obtained after a high resolution reverse phase liquid chromatography.     

黑云母温度计能否用于估计花岗质侵入岩的结晶温度？

为了探讨黑云母温度计是否适用于估计花岗质侵入岩的结晶温度,汇编了国内外典型花岗质侵入体的岩石化学和矿物化学数据,利用Henry等(2005)的黑云母Ti饱和温度计、Li 和Zhang (2022)的黑云母全组分温度计估算了岩浆温度,并与Shao等(2020)的锆饱和温度计估算结果进行了对比。结果表明,黑云母Ti饱和温度计估算的温度比锆饱和温度计和黑云母全组分温度计低50~200℃,因此认为黑云母Ti饱和温度计并不适用于估算花岗质侵入岩的结晶温度,而黑云母全组分温度计可以复现S型和I型花岗岩的锆饱和温度计结果。     

基于LC-MS/MS成分分析结合高效液相色谱法评价泻白散基准样品质量

目的：建立泻白散基准样品特征图谱方法,以LC-MS/MS指认各特征峰并对其进行归属,建立基准样品各组成药味质控指标的含量测定方法综合评价其质量。方法：以色谱柱Hypersil ODS²(250 mm×4.6 mm,5μm)、乙腈-0.1%磷酸/甲酸梯度洗脱、检测波长280nm、流速1.0 ml/min、柱温25℃、进样量10μl进行指纹图谱研究,以同一色谱条件使用LC-MS/MS联用进行峰归属并进行化学成分分析,以指认的各药味专属性峰建立基准样品质控指标含量测定方法。结果：泻白散基准样品特征图谱重复性良好,供试品溶液48 h内稳定,多批次检测显示泻白散指纹图谱共有峰14个,相似度均＞0.9;峰归属确认其中5个归属于炒桑白皮,5个归属于炙甘草,3个归属于地骨皮;并通过LC-MS/MS指认出其中11个色谱峰;选取桑皮苷A、甘草酸、枸杞素B分别建立含量测定方法,结果显示方法均具有专属性,重复性良好,加样回收率分别为94.9%、93.5%、95.2%。结论：该指纹图谱方法经验证可行,可有效鉴别泻白散三味饮片;结合LC-MS/MS成分分析可有效选取基准样品各药味的质控成分;建立的检测桑皮苷A、甘草酸、枸杞素B含量测定方法经方法学考察确认可行。     

Multiple‐tuned liquid column dampers for torsional vibration control of structures: theoretical investigation

This paper presents a theoretical investigation on the performance of multiple‐tuned liquid column dampers (MTLCD) for reducing torsional vibration of structures in comparison with single‐tuned liquid column dampers (STLCD). The analytical model is first developed for torsional vibration of a structure with an MTLCD under either harmonic excitation or white noise excitation. The experimental results are then used to verify the analytical model for coupled MTLCD‐structure systems under harmonic excitation. The performance of an MTLCD and its beneficial parameters for achieving the maximum torsional response reduction to white noise excitation are finally investigated through an extensive parametric study in terms of the distance from the centre line of the MTLCD to the rotational axis of the structure, the ratio of the horizontal length to the total length of liquid column, frequency bandwidth, head‐loss coefficient, the number of TLCD units in an MTLCD, frequency‐turning ratio and the spectral level of excitation moment. The results show that there is an optimal head‐loss coefficient and an optimal frequency bandwidth for an MTLCD to achieve the maximum torsional response reduction. It is also demonstrated that the sensitivity of an optimized MTLCD to the frequency‐tuning ratio is less than that of an optimized STLCD, and it can be further improved by increasing the bandwidth but at the cost of less torsional vibration reduction. Copyright © 2002 John Wiley & Sons, Ltd.     

等温剩磁获得曲线的累积对数高斯模型在泥河湾盆地磁组分识别中的运用

基于饱和等温剩磁(SIRM)获得曲线遵循累积对数高斯模型(CLG)的假设，利用改进的CLG模型分析，成功地对采自泥河湾河—湖相层上部的许家窑剖面样品所含的主要载磁组分进行了分离；结合先前的岩石磁学结果，进一步验证了高矫顽力的赤铁矿和低矫顽力的磁铁矿／磁赤铁矿为许家窑样品的主要载磁矿物，并对各磁组分对SIRM的贡献进行了定量估算；对CLG模型的优缺点和实用性进行了探讨；结合剩磁矫顽力曲线特征，尝试提出了X参数的概念。     

龙都尾矿库地下渗流场的数值模拟分析

利用2D-FLOW计算软件,对龙都尾矿库在不同条件下的渗流进行了模拟计算。其中,初期坝按透水和堵塞两种情况,干滩面长度分100,200,300 m三种情况考虑;同时,首次考虑了大气降雨对尾矿坝渗流场的影响,分别计算了50,100,200 mm/d三种雨型。通过计算,获得了龙都尾矿库在不同条件下地下渗流的变化规律。从计算结果中发现,如果初期坝被堵塞,则坝体浸润线会抬高,与尾矿堆积坝坝面相交,并从坝面溢出,对坝体的稳定性产生不利影响;干滩面距离的长短对坝体浸润线有影响,但均不会与堆积坝坝面相交,不会从坝面溢出;大气降雨对坝体的渗流影响较大,从模拟计算中可以看出,大气降雨越大,浸润线抬升越高,对坝体的稳定越不利。     

Tri-frequency spectrum method and results for resolving the parameters of Earth’s liquid core free nutation

The parameters of Earth free core nutation (FCN) are two relatively significant geophysical parameters. Sasao et al. (1980) and Wahr and Bergen (1986) provided the theoretical estimation values of FCN parameters. Gwinn, Herring and Shapiro (1987) first obtained the observational values of FCN parameters by very long base Interference (VLBI) at Cambridge University. In the same year, Neuberg and Zürn in former West Germany and Hinderer in France began to retrieve FCN parameters by the observation of gravity tides and introduced the stacking method. The other scholars who researched into the same geophysical problems by applying the data of gravity tides basically followed the stacking method. The results they reached were similar to the observational result of FCN parameters given by Neuberg et al. in 1987. But the observational results of FCN parameters gained from gravity tides were not identical with those from VLBI, mainly because of the large difference of quality of FCN. So there was not an affirmative observational result of FCN parameters since then. In this paper, The authors firstly introduce the tri-frequency spectrum method with clearly geometrical and geophysical meaning for the resolution of FCN parameters, and the observational results of FCN parameters obtained from tide data at three superconducting gravity stations were accordant with those from VLBI, which will be relatively important to arriving at a certain observational result of FCN parameters.     

Linkage of liquid conductivity of glacier ice with its alkalinity over the north Qinghai-Xizang (Tibet) Plateau

Liquid conductivity (EC) measurement was conducted for the samples collected from several snow pits and ice cores over the Qinghai-Xizang (Tibet) Plateau, with their time range covering seasonal, decadal and centennial scales. Unlike the previous attention mostly focused on the acidity (H⁺) responding to the solid conductance (ECM) of glacial ice, we introduce the alkalinity (OH⁻) of snow and ice to show how it responds to EC. Strong linear relationship was established between EC and OH⁻ for these snow pits and ice cores. Positive correlation is also established between EC and major cations (Ca²⁺, Mg²⁺, Na⁺ and K⁺). Since the cations are known as the proxies for the intensity of mineral dust influx onto glaciers of the northern Qinghai-Xizang Plateau, we believe that EC could be used as an indicator for the history of dust input in deep ice core study. In fact, records in Guliya ice core since the Little Ice Age (LIA) indicate that dust load in glacier may depend on the combination of temperature and humidity. “Cold-dry” combination favors the dust arising, and results in higher EC and OH⁻ values, while “warm-wet” combination prevents dust form and EC and OH⁻ values are lower. In the past century, with the atmospheric warming and precipitation increasing over the northern plateau, which means an atmospheric condition of dust decreasing, both EC and OH⁻ displayed rapid decline.