高效液相色谱-紫外光谱分析氢醌-双(β-羟乙基)醚

建立了高效液相色谱-紫外光谱法测定聚氨酯扩链剂氢醌-双(β-羟乙基)醚(HQEE)工业品中HQEE主含量和对苯二酚残留的方法。在氰基柱上,以甲醇-水-1%乙酸溶液(体积比10∶50∶40)为流动相,流速1.0 mL/min时,HQEE、对苯二酚及其他相关杂质得到良好分离,紫外光谱285 nm检测。方法简便、快捷,结果准确可靠,在工业生产中可有效地指导HQEE合成过程的质量控制。     

高效液相色谱法测定贵州铜仁地区优质矿泉水中16种多环芳烃

本文使用高效液相色谱仪对贵州铜仁地区优质矿泉水中16种多环芳烃进行分析测试,研究了测定优质矿泉水中多环芳烃的方法,并进行了方法验证和实际样品测试,对仪器柱温箱温度和萃取溶剂种类等条件进行优化,选出最适条件。建立的检测方法线性关系良好(R2均大于0. 999 0),检出限为0. 002 6 0. 009 8μg/L,16种多环芳烃的回收率为73. 87%116. 16%,替代物十氟联苯的回收率为70. 17%85. 61%,方法精密度(RSD)为0. 85%16. 77%。方法前处理过程简单,有利于实际样品快速分析,在贵州铜仁地区优质矿泉水资源调查项目中发挥重要作用。     

应力路径和干湿状态对堆石料颗粒破碎的影响研究

堆石料颗粒破碎是引起高土石坝变形的重要因素。在大坝填筑、蓄水期,堆石料的应力路径和干湿状态均是变化的。通过大型三轴试验,系统地研究了应力路径和干湿状态对堆石料颗粒破碎规律的影响。试验结果表明：（1）相同初始条件下,按不同应力路径达到同一轴向应变停机时测定的颗粒破碎率是不同的,等围压?3试验产生的颗粒破碎最大,等平均主应力p试验的次之,等最大主应力?1试验的最小,但不同应力路径下的颗粒级配演化规律是一致的。（2）相同初始条件下,湿样的颗粒破碎率明显高于干样,且二者的差距随着围压的增大而增大,不同干湿条件下的颗粒级配演化规律同样是一致的。（3）建立的考虑母岩强度的颗粒破碎率与塑性功的关系可以较好地统一描述不同应力路径及干湿状态下的颗粒破碎。该研究成果可为建立复杂应力路径及干湿变化条件下考虑颗粒破碎的堆石料弹塑性本构模型提供依据。     

3D打印技术在岩石物理力学试验中的应用

3D打印技术在岩土工程领域的应用还处于初步探索阶段,但其可重复制造含复杂内部结构的试样是常规室内试验无法实现的。现阶段制约3D打印技术在岩石物理力学试验中应用的主要因素在于3D打印试样强度偏低,延性较强。初步探讨了3D打印后干燥时间、打印胶水浓度对试样强度的影响,在此基础上提出了最优化打印方案,使打印试样在强度和脆性方面均有很大提升;通过改变打印方向模拟了天然层状节理岩石的各向异性特征。研究结果表明,随着打印倾斜角度的增加,3D打印试样的单轴抗压强度先减小后增大,呈"U"型变化趋势,抗拉强度也随打印方向的改变出现明显的各向异性特征,这与天然层状节理岩石相关研究成果相似。研究成果可为3D打印技术在岩土工程领域的推广和室内试验研究提供参考。     

Characterization of Continental Intercalaire aquifer (CI) in the Tinrhert-East Area-Illizi Basin on the Algerian-Libyan Border

This paper addresses the characterization of the Continental Intercalaire aquifer(CI) in the Tinrhert-East area of Illizi Basin on the Algerian-Libyan border, which belongs to the SASS1 system, one of the biggest transboundary aquifers in the world. This study concerns a superficies of 4 300 km~2. On the basis of Mud Logging borehole data conducted in this part of the aquifer, a realistic characterization of the aquifer was done. The thickness of the CI aquifer varies from 300 m in the south to 700 m in the north, and the depth ranges from 180 m to 320 m. The interpretation of the logs showed that the aquifer is characterized by a maximum net thickness in its southwestern part(more than 600 m), the porosity is very high, ranging from 30% in the west to 24% at the Libyan borders, the permeability is low to medium around 10~(-5) m/s, and the maximum transmissivity values of about 8× 10~(-3) m~2/s were recorded at the center of the study area. The depth of water varies from 235 m to 312 m, and the water flows from south to north, in accordance with the general direction observed in the CI aquifer in the Northern Sahara Aquifer System(SASS). The porosity values obtained from the interpretation of the sonic and density logs permit to estimate the water reserves of this aquifer considered fossil, at thresholds much higher than what was considered until now.     

按摩疗法加健康教育结合乳果糖口服液治疗便秘30 例疗效观察

目的：观察按摩疗法加健康教育结合乳果糖口服液治疗便秘的临床疗效。方法：将60 例便秘患者随机分为治疗组和对照组,每组各30 例。对照组给予乳果糖口服液治疗,治疗组在对照组基础上采用按摩疗法并结合健康教育。2组均以14 d为1个疗程,共治疗2个疗程。治疗结束后随访1个月,观察2组综合疗效、生活质量（PAC-QOL）评分及症状积分。结果：总有效率治疗组为93.33%（28/30）,高于对照组的76.67%（23/30）,差异有统计学意义（P<0.05）。2组治疗后PAC-QOL评分比较,差异有统计学意义（P<0.05）。治疗2周后,治疗组排便时间积分、症状总积分低于对照组（均P<0.05）;治疗4周后,治疗组排便困难、排便时间、排便感（下坠、不尽、胀感）、排便频度积分及症状总积分低于对照组（均P<0.05）;治疗结束后1个月,治疗组粪便性状、排便困难、排便时间、排便感（下坠、不尽、胀感）、排便频度积分及症状总积分低于对照组（均P<0.05）。结论：按摩疗法加健康教育结合乳果糖口服液治疗便秘效果优于单纯乳果糖口服液治疗,值得临床推广应用。     

Crack nucleation in saturated porous media

Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.     

Dynamic responses of unsaturated half‐space soil to a moving harmonic rectangular load

The problem of the dynamic responses of a semi‐infinite unsaturated poroelastic medium subjected to a moving rectangular load is investigated analytical/numerically. The dynamic governing equations are obtained with consideration of the compressibility of solid grain and pore fluid, inertial coupling, and viscous drag as well as capillary pressure in the unsaturated soil, and they can be easily degraded to the complete Biot's theory. Using the Fourier transform, the general solution for the equations is derived in the transformed domain, and then a corresponding boundary value problem is formulated. By introducing fast Fourier transform algorithm, the unsaturated soil vertical displacements, effective stresses, and pore pressures induced by moving load are computed, and some of the calculated results are compared with those for the degenerated solution of saturated soils and confirmed. The influences of the saturation, the load speed, and excitation frequency on the response of the unsaturated half‐space soil are investigated. The numerical results reveal that the effects of these parameters on the dynamic response of the unsaturated soil are significant.     

CLOUD RADIATIVE AND MICROPHYSICAL EFFECTS ON THE RELATION BETWEEN SPATIAL MEAN RAIN RATE, RAIN INTENSITY AND FRACTIONAL RAINFALL COVERAGE

Cloud radiative and microphysical effects on the relation between spatial mean rain rate, rain intensity and fractional rainfall coverage are investigated in this study by conducting and analyzing a series of two-dimensional cloud resolving model sensitivity experiments of pre-summer torrential rainfall in June 2008. The analysis of time-mean data shows that the exclusion of radiative effects of liquid clouds reduces domain mean rain rate by decreasing convective rain rate mainly through the reduced convective-rainfall area associated with the strengthened hydrometeor gain in the presence of radiative effects of ice clouds, whereas it increases domain mean rain rate by enhancing convective rain rate mainly via the intensified convective rain intensity associated with the enhanced net condensation in the absence of radiative effects of ice clouds. The removal of radiative effects of ice clouds decreases domain mean rain rate by reducing stratiform rain rate through the suppressed stratiform rain intensity related to the suppressed net condensation in the presence of radiative effects of liquid clouds, whereas it increases domain mean rain rate by strengthening convective rain rate mainly via the enhanced convective rain intensity in response to the enhanced net condensation in the absence of radiative effects of liquid clouds. The elimination of microphysical effects of ice clouds suppresses domain mean rain rate by reducing stratiform rain rate through the reduced stratiform-rainfall area associated with severely reduced hydrometeor loss.     

THREE-DIMENSIONAL CALCULATION OF PARTICLE-LIQUID TWO-PHASE TURBULENT FLOW IN A HYDRAULIC TURBINE RUNNER

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